System and method for vacuum deposition of thin films

• US 4,777,908 A
• Filed: 11/26/1986
• Issued: 10/18/1988
• Est. Priority Date: 11/26/1986
• Status: Expired due to Term

• Current Assignee: Viavi Solutions, Inc. (Lumentum Holdings Inc.)
• Original Assignee: Optical Coating Laboratory, Inc. (Lumentum Holdings Inc.)
• Inventors: Johnson, Kim L., Seddon, Richard I., Temple, Michael D.
• Primary Examiner(s): BUEKER, RICHARD R
• Application Number:
  US06/935,292
• Time in Patent Office: 692 Days
• Field of Search: 118/719, 118/723, 118/726, 204/192.31
• US Class Current: 118/719
• CPC Class Codes: C23C 14/32 by explosion; by evaporation and subsequent ionisation of the vapours , e.g. ion-platingC23C14/34 - C23C14/48 take precedence

Abstract

A substrate holder is mounted within the vacuum chamber for carrying at least one substrate; an electrically conductive crucible is positioned within said vacuum chamber and is electrically insulated therefrom but has a low electrical resistance connection therebetween. The crucible is adapted to contain a preselected material for evaporation onto a substrate on the substrate holder. A high voltage electron beam source is positioned within said vacuum chamber in the vicinity of said crucible and includes a high voltage electron gun and a deflection magnet system arranged for bending electrons from said gun into said crucible for evaporating the preselected material therein, the magnet system forms a magnet field of prearranged characteristics in the region above said crucible. A low voltage, high current plasma source, including a separate plasma generating chamber is positioned relative to said vacuum chamber to produce an intense first plasma of a selected activation gas species in said plasma generating chamber for injection into said vacuum chamber. The plasma source is positioned at any convenient location relative to the crucible and the electron beam source and is electrically interconnected with the crucible for current flow therebetween. The plasma source fills the vacuum chamber with a generally distributed plasma. The distributed plasma coacts with the magnetic field above said crucible and evaporant material leaving the crucible to form an intense second plasma in the region above said crucible, thereby activating the evaporant material passing through the region toward the substrate to produce a vacuum deposited thin film having improved thin film characteristics.

Claims

1. In a system for vacuum evaporation of material onto a substrate,

a vacuum chamber;

means for evacuating said vacuum chamber;

a substrate holder mounted within said vacuum chamber for carrying at least one substrate;

an electrically conductive crucible positioned within said vacuum chamber and electrically insulated therefrom but having a low electrical resistance connection therebetween, said crucible being adapted to contain a preselected material for evaporation onto a substrate on said substrate holder;

a high voltage electron beam source positioned within said vacuum chamber in the vicinity of said crucible and including a high voltage electron gun and a deflection magnet system arranged for bending electrons from said gun into said crucible for evaporating said preselected material therein, said magnet system forming a magnetic field of prearranged characteristics in the region above said crucible;

a low voltage, high current plasma source, including a separate plasma generating chamber, positioned relative to said vacuum chamber to produce an intense first plasma of a selected activation gas species in said plasma generating chamber for injection into said vacuum chamber, said plasma source being positioned at any convenient location relative to said crucible and said electron beam source and being electrically interconnected with said crucible for current flow therebetween;

said plasma source thereby filling said vacuum chamber with a generally distributed plasma, and said distributed plasma coacting with said magnetic field above said crucible and evaporant material leaving said crucible to form an intense second plasma in the region above said crucible, thereby activating said evaporant material passing through said region toward said substrate to produce a vacuum deposited thin film comprising said material and having improved thin film characteristics.

2. The system of claim 1, wherein said selected activation gas species is reactive with said evaporant material, and said thin film deposited on said substrate includes a chemical combination of said evaporant material and said activation gas species.

3. The system of claim 1, wherein said substrate holder is mounted in a top region of said chamber, said crucible and said high voltage electron gun are positioned in a bottom region of said chamber and said plasma source is located adjacent a bottom region of said chamber generally in a position on one side of said crucible opposite said electron gun.

4. The system of claim 1, wherein said electron beam source is a 270 degree deflection type source, said deflection magnet system comprises a pair of magnet pole pieces arranged on opposite sides of said electron gun and shaped to provide a more narrow pole gap and accompanying higher magnetic field strength in the region of said electron gun whereat electrons are emitted and a wider pole gap and accompanying lower magnetic field strength in the region adjacent and above said crucible to increase the number of electrons withdrawn from the second plasma to the crucible and thereby to increase the ionization efficiency in said second plasma region.

5. The system of claim 1, wherein said plasma source comprises

a first chamber including a top wall having a small aperture therein, a triangular arrangement of three separate filaments mounted within said chamber parallel to said top wall and centered on said small aperture, means for applying a direct current bias between said filaments and said top wall, means for supplying electrical current to said filaments to produce heating thereof, and means for communicating a noble gas to said first chamber for plasma activation by electrons from said heated filaments;

a second chamber serving as said plasma generating chamber and communicating with said first chamber through said small aperture for receiving electrons from said plasma in said first chamber and having a top wall with a large aperture therein communicating with said vacuum chamber, means for communicating said selected gas species into said second chamber, and electromagnet means surrounding said second chamber for creating a magnetic field therewithin, said electrons cooperating with said magnetic field to produce a plasma generating region within said second chamber, thereby producing an intense plasma of said selected gas species for communication into said vacuum chamber.

6. The system of claim 1, further comprising

a second electrically conductive crucible positioned within said vacuum chamber at a location substantially remote from said first crucible, said second crucible being electrically insulated from said chamber but having a low resistance electrical connection therebetween, said second crucible being adapted to contain a preselected second material for evaporation onto said substrate;

and

a second high voltage electron beam source positioned within said chamber in the vicinity of said second crucible and remote from said first electron beam source to avoid interaction therebetween, said second electron beam source including a high voltage electron gun and a deflection magnet system arranged for bending electrons from said gun into said crucible for evaporating said preselected material therein, said magnet system forming a magnetic field of prearranged characteristics in the region above said second crucible;

said second crucible being electrically connected to said low voltage, high current plasma source for current flow therebetween;

said plasma filling said chamber coacting with said magnetic field above said second crucible and evaporant material leaving said said second crucible to form an intense second plasma in the region above said second crucible, thereby activating said evaporant material passing through said region toward said substrate and depositing thereon.

7. The system of claim 6, wherein said first and second materials are chemically different materials, and said first and second electron beam sources are operated during separate first and second time periods such that said thin film deposited during said first time period comprises said first material and said thin film deposited during said second time period comprises said second material.

8. The system of claim 6, wherein said first and second materials are chemically different materials, and said first and second electron beam sources are operated during the same time period such that said thin film deposited on said substrate comprises both said first and second materials.

9. In a system for depositing thin film coatings,

a vacuum chamber,

substrate holder means mounted within said vacuum chamber for carrying at least one substrate thereon;

container means mounted within said vacuum chamber for holding a source of evaporant material with line of sight between said material and said substrate;

heating means associated with said container means for heating said source of evaporant material to evaporate said material onto said substrate;

plasma generating means for generating an intense plasma of a selected gas species in a separate plasma generating chamber and for communicating said plasma to said vacuum chamber to fill said vacuum chamber with a generally distributed plasma;

current conducting means associated with said container means and said plasma generating means for conducting electrical current therebetween;

magnet means associated with said container means for producing a magnetic field of prearranged characteristics in the region above said container means;

said magnet means, said generally distributed plasma, and said evaporant material passing through said magnetic field cooperating to produce an intense second plasma in the region above said container means accompanied by high current flow in said conducting means, whereby said evaporant material is activated in passing through said second plasma region and then deposited on said substrate to produce a vacuum deposited thin film comprising said material and having improved thin film characteristics.