Composition for the preservation of wood

• US 4,778,833 A
• Filed: 12/11/1986
• Issued: 10/18/1988
• Est. Priority Date: 02/03/1984
• Status: Expired due to Fees

• Current Assignee: Nederlandse Centrale Organisatie Voor Toegepast- Natuurweten- Schappelijk Onderzoek
• Original Assignee: Nederlandse Centrale Organisatie Voor Toegepast- Natuurweten- Schappelijk Onderzoek
• Inventors: Van der Drift, Jan W. P. T., La Brijn, Jan
• Primary Examiner(s): Lilling, Herbert J.
• Application Number:
  US06/941,538
• Time in Patent Office: 677 Days
• Field of Search: 523/177, 524/404, 524/405, 524/438, 524/516, 524/517, 524/503, 525/197, 525/198, 525/207
• US Class Current: 523/177
• CPC Class Codes: B27K 3/15 Impregnating involving polymerisation including use of polymer-containing impregnating agents macromolecular compounds derived from lignocellulosic materials C08H; compositions of lignin-containing materials C08L97/02
• CPC Class Codes: C08K 3/16 Halogen-containing compounds
• CPC Class Codes: C08K 3/38 Boron-containing compounds
• CPC Class Codes: C08L 23/0853 Vinylacetate
• CPC Class Codes: C08L 97/02 Lignocellulosic material, e.g. wood, straw or bagasse manufacture of articles made from lignocellulosic material by dry processes B27N

Abstract

Composition for the preservation of wood containing a wood preservative, such as a boron compound or a fluorine compound, in a polymer or polymer composition, which upon contact with water releases the wood preservative. Said composition is introduced into a hole in the wood or in a wood construction, whereafter the hole is sealed.

Claims

1. Composition for the preservation of wood comprising a mixture of a wood preservative with a polymer composition, wherein said wood preservative is not chemically bonded to said polymer composition, and wherein said polymer composition is a polymer alloy prepared from component (a) one or more high molecular polymers possessing anhydride groups and component (b) one or more high molecular polymers containing ester groups, in which the components (a) and (b) are bonded to one another via a hydrogen bridge through complete or total protolysis of component (a).

2. Composition according to claim 1, wherein the polymer alloy consists of (a) a copolymer of styrene and maleic anhydride and (b) polyvinylacetate or a copolymer of ethylene and vinyl acetate.

3. Composition according to claim 1, wherein the polymer or the polymer composition, containing the wood preservative, is coated with a water-permeable coating.

4. Composition according to claim 3, wherein the coating consists of a water-permeable polymer or a water-permeable polymer composition.

5. Composition according to claim 3, wherein the coating consists of a polymer or polymer composition which is water-soluble or water-swellable.

6. Composition according to claim 1, wherein the wood preservative contains one or more boron compounds.

7. Composition according to claim 6, the wood preservative is boric acid and/or borax.

8. Composition according to claim 7, wherein the wood preservative is a mixture of boric acid and borax.

9. Composition according to claim 1, wherein the wood preservative contains a fluorine compound.

10. Composition according to claim 9, wherein wood preservative is a mixture of potassium bifluoride and ammonium bifluoride.

11. Composition according to claim 1, wherein the composition contains both a boron compound and a fluorine compound as wood preservatives.

12. Composition according to claim 1, wherein the composition is in the form of a pellet, a pill or a cylinder.

13. A water activatable wood preserving composition comprising:

(a) a polymer alloy made up of at least one first high molecular weight polymer component having anhydride groups thereon and at least one second high molecular weight polymer component containing ester groups, said first and second components being bonded to each other by a hydrogen bridge; and

(b) a wood preservative;

wherein said wood preservative is mixed with but not bonded to said polymeric component.

14. The composition of claim 13 wherein said wood preservative comprise a boron fluorine or containing compound.

15. The composition of claim 13 further comprising a polymeric water permeable coating surrounding said wood preserving composition.

16. The composition of claim 15 wherein said coating is selected from the group of polymer alloys which may be used as the polymeric component of the wood preserving composition.

17. The composition of claim 13 wherein said polymer alloy consists of (a) a copolymer of styrene and maleic anhydride, and (b) polyvinylacetate.

18. The composition of claim 13 wherein said polymer alloy consists of (a) a copolymer of styrene and maleic anhydride, and (b) a copolymer of ethylene and vinyl acetate.

19. The composition of claim 15 wherein said coating comprises of a polymer alloy of (a) a copolymer of styrene and maleic anhydride, and (b) polyvinylacetate.

20. The composition of claim 15 wherein said coating conprises of a polymer alloy of (a) styrene and maleic anhydride, and (b) a copolymer of ethylene and vinyl acetate.

21. The composition of claim 19 wherein the coating comprises a polymer alloy of (a) from 10-70% by weight of a copolymer of styrene and maleic anhydride, and (b) 90-30% by weight polyvinylacetate.

22. The composition of claim 13 wherein said wood preservative is selected from the group consisting of borax, boric acid and mixtures thereof.

23. The composition of claim 14 wherein said wood preservative comprises KHF₂ and NH₄ HF₂.

24. A water activatable wood preserving composition comprising:

(a) a polymer alloy made up of at least one first high molecular weight polymer component having anhydride groups thereon and at least one second high molecular weight polymer component containing ester groups, said first and second components being bonded to each other by a hydrogen bridge; and

(b) a wood preservative selected from the group consisting essentially of boric acid, borax, fluorine compounds and mixtures thereof, wherein said wood preservative is mixed with but not bonded to said polymer alloy.

25. The composition of claim 24 wherein the polymer alloy consists essentially of

(i) a copolymer of styrene and maleic anhydride, and

(ii) polyvinylacetate.

26. The composition of claim 24 wherein said polymer alloy consists essentially of

(i) a copolymer of styrene and maleic anhydride, and

(ii) a copolymer of ethylene and vinylacetate.

27. The composition of claim 24 wherein the wood preservative is a mixture of boric acid and borax.

28. The composition of claim 24, wherein the wood preservative is a mixture of KHF₂ and NH₄ HF₂.

29. The composition of claim 24 further comprising a water permeable coating comprising a polymer alloy made up of at least one first high molecular weight polymer component having anhydride groups thereon and at least one second high molecular weight polymer component containing ester groups, said first and second components being bonded to each other by a hydrogen bridge.

30. The composition of claim 29 wherein said coating comprises a polymer alloy of

(i) a copolymer of styrene and maleic anhydride, and

(ii) polyvinyl acetate.

31. The composition of claim 29 wherein said coating comprises a polymer alloy of

(i) a copolymer of styrene and maleic anhydride;

and

(ii) a copolymer of ethylene and vinyl acetate.

32. The composition of claim 29 wherein said coating comprises a polymer alloy of

(i) from 10-70% by weight of a copolymer of styrene and maleic anhydride;

and

(ii) 90-30% by weight of polyvinyl acetate.

33. The composition of claim 24 further comprising a water permeable coating comprising a polymer selected from the group consisting of polyvinylpyrrolidone, polyvinylalcohol, polyethylene glycol, and polyacrylamide.

34. The composition of claim 33 wherein the coating comprises polyvinylalcohol.

35. A water activatable wood preserving composition comprising:

(a) a polymeric component consisting of

(i) a polymer selected from the group consisting of polyvinylpyrrolidone, polyvinylalcohol, polyethylene glycol, and polyacrylamide;

or

(ii) a polymer alloy made up of at lest one first high molecular weight polymer component having anhydride groups thereon and at least one second high molecular weight polymer component containing ester groups, said first and second components being bonded to each other by a hydrogen bridge; and

(b) a mixture of KHF₂ and NH₄ HF₂ as a wood preservative.

36. The composition of claim 35 further comprising a water permeable coating comprising a polymer alloy made up of at least one first high molecular weight polymer component having anhydride groups thereon and at least one second high molecular weight polymer component containing ester groups, said first and second components being bonded to each other by a hydrogen bridge.

37. The composition of claim 36 wherein said coating comprises a polymer alloy of

(i) a copolymer of styrene and maleic anhydride;

and

(ii) polyvinyl acetate.

38. The composition of claim 36 wherein said coating comprises a polymer alloy of

(i) a copolymer of styrene and maleic anhydride and

(ii) a copolymer of ethylene and vinyl acetate.

39. The composition of claim 36 wherein said coating comprises a polymer alloy of

(i) from 20-70% by weight of a copolymer of styrene and maleic anhydride, and

(ii) 90-30% by weight of polyvinyl acetate.

40. The composition of claim 35 further comprising a water permeable coating comprising a polymer selected from the group consisting of polyvinylpyrrolidone, polyvinylalcohol, polyethylene glycol and polyacrylamide.

41. The composition of claim 40 wherein the coating comprises polyvinylalcohol.