Hydraulic fracturing process using a polymer gel

• US 4,779,680 A
• Filed: 05/13/1987
• Issued: 10/25/1988
• Est. Priority Date: 05/13/1987
• Status: Expired due to Fees

• Current Assignee: Marathon Oil Company 539 South Main St Findlay Oh
• Original Assignee: Marathon Oil Company (Marathon Oil Corporation)
• Inventors: Sydansk, Robert D.
• Primary Examiner(s): Suchfield, George A.
• Application Number:
  US07/050,609
• Time in Patent Office: 531 Days
• Field of Search: 166/294, 166/295, 166/300, 166/308, 252/8.551
• US Class Current: 166/300
• CPC Class Codes: C09K 8/685 containing cross-linking agents
• CPC Class Codes: Y10S 507/902 Controlled release agent
• CPC Class Codes: Y10S 507/903 Crosslinked resin or polymer
• CPC Class Codes: Y10S 507/922 Fracture fluid

Abstract

A subterranean hydrocarbon-bearing formation is hydraulically fractured using a crosslinked polymer gel as a fracturing fluid. The gel comprises a high molecular weight, water-soluble, carboxylate-containing polymer and a chromic carboxylate complex crosslinking agent. The gel components are premixed at the surface and injected into a wellbore in fluid communication with the formation at a pressure sufficient to hydraulically fracture the formation.

Claims

1. A fracturing process applied to a subterranean hydrocarbon-bearing formation below an earthen surface in fluid communication with a wellbore comprising:

(a) premixing a fracturing fluid at the surface comprising a gel breaker and a gelation solution consisting essentially of an aqueous solvent, a water-soluble acrylamide polymer selected from the group consisting of polyacrylamide and partially hydrolyzed polyacrylamide, and a crosslinking agent formed of at least one chromium III species complexed with at least one carboxylate species selected from the group consisting of propionate, acetate, lactate, and mixtures thereof;

(b) at least partially gelling said gelation solution at the surface to form a gel; and

(c) injecting said fracturing fluid into said formation via said wellbore at a pressure sufficient to hydraulically fracture said formation.

2. The process of claim 1 wherein said gel is substantially completely gelled upon injection into said wellbore.

3. The process of claim 1 wherein said at least partially gelled gel is gelled to completion after injection into said wellbore.

4. The process of claim 1 wherein said at least one carboxylate species is acetate.

5. The process of claim 1 wherein the pH of said gelation solution is at least about 7.

6. The process of claim 5 wherein the molar ratio of said acetate to chromium III species in said complex is less than 4.0:

1.

7. The process of claim 1 wherein said fracturing fluid further comprises a solid proppant.

8. A fracturing process applied to a subterranean hydrocarbon-bearing formation below an earthen surface in fluid communication with a wellbore comprising:

(a) premixing a fracturing fluid at the surface comprising a gel breaker and a gelation solution consisting essentially of an aqueous solvent, a water-soluble acrylamide polymer selected from the group consisting of polyacrylamide and partially hydrolyzed polyacrylamide, and a crosslinking agent formed of at least one chromium III species complexed with at least one carboxylate species, selected from the group consisting of propionate, acetate, lactate, and mixtures thereof, and at least one species selected from the group consisting of electronegative oxygen species, electronegative hydroxide species, inorganic monovalent ions, inorganic divalent ions, water molecules, and mixtures thereof;

(b) at least partially gelling said gelation solution at the surface to form a gel; and

(c) injecting said fracturing fluid into said formation via said wellbore at a pressure sufficient to hydraulically fracture said formation.

9. The process of claim 8 wherein said gel is substantially completely gelled upon injection into said wellbore.

10. The process of claim 8 wherein said at least partially gelled gel is gelled to completion after injection into said wellbore.

11. The process of claim 8 wherein said at least one carboxylate-containing species is acetate.

12. The process of claim 8 wherein the pH of said gelation solution is at least about 7.

13. The process of claim 11 wherein the molar ratio of said acetate to chromium III species in said complex is less than 4.0:

1.

14. The process of claim 8 wherein said fracturing fluid further comprises a solid proppant.