Method of making polyimide foam structures of controlled density and increased rigidity

• US 4,780,167 A
• Filed: 10/23/1987
• Issued: 10/25/1988
• Est. Priority Date: 10/23/1987
• Status: Expired due to Fees

• Current Assignee: Sorrento Engineering Incorporated
• Original Assignee: Sorrento Engineering Incorporated
• Inventors: Hill, Francis V.
• Primary Examiner(s): Foelak, Morton
• Application Number:
  US07/111,851
• Time in Patent Office: 368 Days
• Field of Search: 156/245, 156/307.3, 156/331.1, 156/331.5, 264/137, 264/321
• US Class Current: 156/245
• CPC Class Codes: B32B 2260/046 Synthetic resin
• CPC Class Codes: B32B 2262/0269 Aromatic polyamide fibres
• CPC Class Codes: B32B 2262/101 Glass fibres
• CPC Class Codes: B32B 2262/105 Ceramic fibres
• CPC Class Codes: B32B 2262/106 Carbon fibres, e.g. graphite fibres
• CPC Class Codes: B32B 2266/0214 Materials belonging to B32B27/00
• CPC Class Codes: B32B 2305/022 Foam
• CPC Class Codes: B32B 2305/076 Prepregs
• CPC Class Codes: B32B 2305/72 Cured, e.g. vulcanised, cross-linked
• CPC Class Codes: B32B 2307/3065 Flame resistant or retardant, fire resistant or retardant
• CPC Class Codes: B32B 2597/00 Tubular articles, e.g. hoses, pipes
• CPC Class Codes: B32B 2605/12 Ships
• CPC Class Codes: B32B 2605/18 Aircraft blades, propellers B32B2603/00
• CPC Class Codes: B32B 27/34 comprising polyamides
• CPC Class Codes: B32B 38/08 Impregnating
• CPC Class Codes: B32B 38/16 Drying; Softening; Cleaning
• CPC Class Codes: B32B 5/18 characterised by features of a layer of foamed material
• CPC Class Codes: B32B 5/245 another layer next to it being a foam layer
• CPC Class Codes: Y10S 521/918 Physical aftertreatment of a cellular product
• CPC Class Codes: Y10T 428/249953 Composite having voids in a component [e.g., porous, cellular, etc.]
• CPC Class Codes: Y10T 428/249991 : Synthetic resin or natural rubbers
• CPC Class Codes: Y10T 428/31721 : Of polyimide
• CPC Class Codes: Y10T 442/335 : Plural fabric layers
• CPC Class Codes: Y10T 442/651 : Plural fabric layers

Abstract

A method of making structural panels having a controlled density polyimide core, generally with at least one face sheet. An open cell polyimide foam panel is impregnated with a liquid polyimide precursor, compressed to squeeze out all but a desired quantity of the polyimide precursor and dried. One or two face sheets are impregnated with the same liquid polyimide precursor and placed on one or both faces of the foam panel, with pre-drying of the face sheet if desired. This assembly is placed in a mold and subjected to slight compression. The assembly is heated to a moderate temperature for a suitable time to take on the mold configuration. Then the assembly is heated to the curing temperature of the polyimide precursor for a period sufficient to cause curing. The resulting structural panel has a selected density, which determines strength and rigidity, weight and other physical characteristics, controlled by the amount of precursor allowed to remain after the impregnation foam compression step.

Claims

1. The method of making a composite structure having a uniform polyimide foam component of controlled density, which comprises the steps of:

providing a substantially open-cell polyimide foam core having substantially uniform cell size and subtantially uniform density;

impregnating said foam core with a liquid polyimide precursor;

compressing said foam shape to squeeze out all but a desired quantity of liquid precursor;

bringing said face sheet into contact with said foam core;

heating the resulting assembly to a temperature sufficient to cure said polyimide precursor; and

whereby a strong, well bonded asesmbly having a uniform selected core density results.

2. The method according to claim 1 wherein said compressing of said foam core is accomplished by passing said foam core between at least one pair of spaced rollers, the space between said rollers being adjusted to squeeze out all but a selected quantity of said polyimide precursor from said foam core.

3. The method according to claim 1 wherein said foam core has thickness substantially less than its length and width and two face sheets are brought into contact with opposite major faces of said foam core.

4. The method according to claim 1 wherein said face sheets comprise fibers in woven cloth, matt or blanket form and the fibers are glass, aramid, graphite, ceramic or a mixture or combination thereof.

5. The method according to claim 1 wherein said liquid polyimide precursor impregnated foam core is dried after said compression step.

6. The method according to claim 1 wherein said liquid polyimide precursor impregnated face sheet is dried after said impregnation step.

7. The method according to claim 1 wherein said assembly is cured in a mold with at least two mold surfaces in contact with two opposite surfaces of said assembly.

8. The method according to claim 7 wherein the thickness of said assembly between said two opposite surfaces is slightly greater than the spacing between said two mold surfaces, whereby said foam core of said assembly is slightly compressed during molding.

9. The method according to claim 7 wherein said mold surfaces are configured to reshape said assembly.

10. The method according to claim 7 wherein said assembly is assembled and cured by:

placing a first liquid polyimide precursor impregnated face sheet on a first mold surface which has an other than flat configuration;

placing a liquid polyimide precursor impregnated foam core over said first face sheet;

placing a second liquid polyimide precursor impregnated face sheet over said foam core;

heating the resulting assembly to dry said liquid polyimide precursor;

placing the second mold surface over said assembly in slight pressure contact therewith; and

heating said assembly to a temperature sufficient to cure said precursor.

11. The method according to claim 7 wherein said assembly is assembled and cured by:

(a) placing a first liquid polyimide precursor impregnated face sheet on a first mold surface having an other than flat configuration;

(b) drying said polyimide precursor to shape retaining, dry, state;

(c) removing said face sheet from said mold surface;

(d) repeating steps (a) through (c) with a second face sheet;

(e) drying said impregnated foam core on a flat surface;

(f) replacing said first dry face sheet on said other than flat mold surface;

(g) placing said foam core over said first face sheet and trimming to fit;

(h) placing said second dry face sheet over said foam core;

(i) bringing a second mold surface into slight pressure contact with the resulting assembly;

(j) heating said assembly to a temperature sufficient to cure said precursor.

12. The method according to claim 11 including the further step of reducing the trimmings removed in said trimming step to small pieces and filling any gaps in said fitted foam core with said granules prior to installation of said second face sheet.

13. The method of making structural panels having a polyimide foam core bonded between face sheets which comprises the steps of:

providing a substantially open-cell polyimide foam core;

impregnating said foam core with a liquid polyimide precursor;

compressing said foam core to squeeze out all but the desired quantity of said polyimide precursor;

drying said foam core at a temperature below the cure temperature of said polyimide precursor;

impregnating two face sheets with said polyimide precursor;

drying said two face sheets at a temperature below the cure temperature of said polyimide precursor;

placing said face sheets on opposite sides of said foam core;

placing the resulting assembly between mold surfaces adjusted to slightly compress said foam assembly;

heating said assembly at a temperature below the curing temperature of said polyimide precursor for a period sufficient to allow said assembly to take the shape of the mold surfaces;

heating said assembly at a temperature sufficient to cure said polyimide precursor for a time period sufficient to produce complete cure; and

removing the resulting bonded composite structural panel from the mold.

14. The method according to claim 13 wherein said compressing of said foam core is accomplished by passing said foam core between at least one pair of spaced rollers, the space between said rollers being adjusted to squeeze out all but a selected quantity of said polyimide precursor from said foam core.

15. The method according to claim 13 wherein said face sheets comprise fibers in woven cloth, matt or blanket form and the fibers are glass, aramid, graphite, ceramic or a mixture or combination thereof.

16. The method according to claim 13 wherein said mold surfaces are configured to reshape said assembly.