Method and apparatus for subjecting gases to discharge treatment

• US 4,780,277 A
• Filed: 05/05/1986
• Issued: 10/25/1988
• Est. Priority Date: 05/10/1985
• Status: Expired due to Term

• Current Assignee: Shinryo Corporation (Mitsubishi Chemical Group Corp.)
• Original Assignee: Shinryo Corporation (Mitsubishi Chemical Group Corp.)
• Inventors: Nagashima, Yasuaki, Sumiya, Masato, Hosono, Shinji, Tanaka, Toshio
• Primary Examiner(s): Richman, Barry S.
• Assistant Examiner(s): Johnston, Jill
• Application Number:
  US06/859,344
• Time in Patent Office: 904 Days
• Field of Search: 422/121-123, 422/4, 422/22, 422/30, 422/169, 422/172, 422/177, 422/24, 423/212, 423/219, 204/176
• US Class Current: 422/4
• CPC Class Codes: A61L 9/015 using gaseous or vaporous substances, e.g. ozone A61L9/20 takes precedence ; evaporation in general B01B1/005
• CPC Class Codes: A61L 9/22 Ionisation
• CPC Class Codes: B01J 19/088 giving rise to electric discharges for heating purposes H05B7/00; for the production of ozone C01B13/11, H01T19/00
• CPC Class Codes: B01J 2219/0847 Glow discharge
• CPC Class Codes: B01J 2219/0849 Corona pulse discharge

Abstract

A waste gas in treated by the sequence of discharge treatment and catalytic oxidation. A microbe-containing gas is disinfected by first mixing it with ozone, then subjecting the gas to discharge treatment and catalytic reaction successively.

Claims

1. A sterilization method which comprises:

adding ozone to a gas containing microorganisms;

introducing the resulting ozone-containing gas into a discharge zone so as to produce plasma in the gas; and

supplying the resulting treated gas into a catalytic reaction zone at ordinary ambient temperature such that a gas which is substantially free from ozone and microorganisms is obtained.

2. A method according to claim 1 wherein said gas is air.

3. A method according to claim 1 wherein the ozone is added in an amount of 10 to 5,000 ppm.

4. A method according to claim 1 wherein a glow or corona discharge is produced in said discharge zone.

5. A method according to claim 1 wherein a catalyst selected from the group consisting of zeolite, a silica-alumina catalyst, activated carbon, and a lead-, zinc-, copper- or nickel-supporting catalyst is employed in said catalytic reaction zone.

6. A sterilization method which comprises:

performing surface sterilization in working space by supplying ozone thereinto;

after completion of the surface sterilization, drawing the ozone-containing gas from the working space and introducing it into a discharge zone so as to produce plasma in said gas;

supplying the resulting treated gas into a catalytic reaction zone at ordinary ambient temperature such that a gas which is substantially free from ozone is obtained; and

returning said ozone-free gas to said working space.

7. A method of treating a noxious component in a waste gas by oxidation which comprises first introducing the waste gas into a discharge zone to form a plasma-containing gas and then introducing said plasma-containing gas into a catalytic reaction zone so as to allow said noxious components to enter into a catalytic oxidation reaction.

8. A method according to claim 7 wherein said waste gas is at ordinary ambient temperature.

9. A method according to claim 7 wherein said waste gas has a temperature in the range of 40°

to 100°

C.

10. A method according to claim 7 wherein a glow or corona discharge is produced in said discharge zone.

11. A method according to claim 7 wherein a catalyst selected from the group consisting of zeolite, a silica-alumina catalyst, activated carbon, and a lead-, zinc-, copper- or nickel-supporting catalyst is employed in said catalytic reaction zone.

12. A method according to claim 7 wherein ozone is added to said waste gas prior to introducing the waste gas into the discharge zone.

13. A method according to claim 7 wherein said noxious component is a malodorous component.

14. A method according to claim 13 wherein said malodorous component is at least one member selected from the group consisting of mercaptan, hydrogen sulfide, ammonia and trimethylamine.

15. A method according to claim 7 wherein said noxious component is an organic solvent.

16. A method according to claim 15 wherein said organic solvent is at least one member selected form the group consisting of enzene, toluene, xylene, ethylene glycol monobutyl ether, methyl ethyl ketone, and methyl isobutyl ketone.

17. A method according to claim 7 wherein said noxious component is a gasous inorganic oxide.

18. A method according to claim 17 wherein said gaseous inorganic oxide is at least one member selected from the group consisting of NO_x, SO_x and CO.