Treatment of viscous crude oils

• US 4,781,819 A
• Filed: 07/21/1986
• Issued: 11/01/1988
• Est. Priority Date: 07/06/1983
• Status: Expired due to Fees

• Current Assignee: Intevep, S.A. (PDVSA Gas SA)
• Original Assignee: BP PLC, Intevep, S.A. (PDVSA Gas SA)
• Inventors: Stockwell, Alan, Layrisse, Ignacio, Chirinos, Maria L., Grosso, Jorge L.
• Primary Examiner(s): Davis, Curtis R.
• Assistant Examiner(s): Myers, Helane
• Application Number:
  US06/888,109
• Time in Patent Office: 834 Days
• Field of Search: 208/309, 208/370, 208/34, 208/45, 208/188, 210/708, 210/709, 210/729
• US Class Current: 208/309
• CPC Class Codes: C10G 21/003 Solvent de-asphalting
• CPC Class Codes: C10G 21/28 Recovery of used solvent

Abstract

Asphaltenes and/or wax and/or water are removed from crude oil by contacting the crude oil with an organic solvent to dissolve the crude oil and precipitate asphaltenes and/or wax and separate the oil and water. Solvent is then separated from the deasphalted and/or dewaxed and/or dehydrated crude oil.

Removing asphaltenes, wax and/or water reduces the viscosity of the crude oil and it can then be transported, e.g. by pumping through a pipeline, with less expenditure of energy.

Claims

1. A method for the treatment and transportation of a viscous crude oil produced in the form of an emulsion of fine droplets of formation water in oil, comprising the stages of dehydration, solvent deasphalting, solvent removal and transportation through a pipeline, said dehydration and solvent deasphalting capable of being carried out in a single zone or separate zones, said method comprising:

(a) adding a deasphalting/dewatering solvent to the emulsion of water in oil upstream of the dehydration and deasphalting stages,

(b) separating water from oil in a dehydration stage,

(c) withdrawing water from the dehydration stage,

(d) precipitating asphalt in a deasphalting stage by contacting the oil with the solvent at a temperature in the range of 40°

C. to 60°

C. and removing asphaltenes from the deasphalting stage,

(e) passing oil and solvent from the deasphalting stage to the solvent removal stage, and

(f) withdrawing the oil of reduced water and asphaltene content from the solvent removal stage and transporting said oil through a pipeline.

2. A method according to claim 1 wherein dehydration and deasphalting are effected simultaneously within the same stage.

3. A method according to claim 1 wherein the ratio of the volume of solvent to the volume of crude oil is in the range 1:

10 to 8;

1.

4. A method according to claim 1 wherein a chemical demulsifier is added to the crude oil or organic solvent upstream of the dehydration stage.

5. A method according to claim 1 wherein treatment is effected at a temperature in the range 40°

to 60°

C.

6. A method according to claim 1 wherein the crude oil has an API Gravity in the range 5°

to 15°

.

7. A method according to claim 1 wherein the water associated with the crude oil is salt water and the salt content of the crude oil is reduced.

8. A method according to claim 1 wherein the organic solvent is selected from the group consisting of pentane, hexane, heptane and naphtha.

9. A method for the treatment and transportation of a viscous crude oil produced in the form of an emulsion of fine droplets of formation water in oil, comprising the stages of dehydration, solvent deasphalting, solvent removal and transportation through a pipeline, said method comprising:

(a) adding a deasphalting/dewatering organic solvent to the emulsion of water in oil upstream of the dehydration stage,

(b) separating water from oil in a dehydration stage,

(c) withdrawing water from the dehydration stage,

(d) passing oil and solvent from the dehydration stage to the deasphalting stage,

(e) adding a further quantity of solvent to the oil and solvent between the dehydration and the deasphalting stages,

(f) precipitating asphalt in a deasphalting stage by contacting the oil with the solvent at a temperaturee in the range of 40°

-60°

C. and removing asphaltenes from the deasphalting stage,

(g) passing the oil and solvent from the deasphalting stage to the solvent removal stage, and

(h) withdrawing the treated oil of reduced water and asphaltene content from the solvent removal stage and transporting the oil through a pipeline.

10. A method according to claim 9 wherein (h) recovered solvent from the solvent removal stage is recycled to the dehydration and deasphalting stages.

11. A method according to claim 9 wherein the ratio of the volume of solvent added in Stage (a) to the volume of crude oil is in the range 1:

20 to 1;

2.

12. A method according to claim 11 wherein the ratio of the total volume of solvent added in Stages (a) and (d) to the volume of crude oil is in the range 1:

10 to 8;

1.

13. A method according to claim 9 wherein the solvent is selected from the group consisting of pentane, hexane, heptane and naphtha.