Antimicrobially active wet wiper

• US 4,781,974 A
• Filed: 03/09/1987
• Issued: 11/01/1988
• Est. Priority Date: 04/23/1986
• Status: Expired due to Term

• Current Assignee: James River Corporation (KOCH Industries Incorporated)
• Original Assignee: James River Corporation (KOCH Industries Incorporated)
• Inventors: Miller, Joseph H., Bouchette, Michael P.
• Primary Examiner(s): Bell, James J.
• Application Number:
  US07/023,228
• Time in Patent Office: 603 Days
• Field of Search: 428/288, 428/289, 428/290, 428/446, 428/452, 428/913, 15/104.93, 604/360, 427/389.9, 427/421, 427/439, 424/443, 424/414
• US Class Current: 442/327
• CPC Class Codes: A01N 25/34 Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
• CPC Class Codes: A47L 13/17 containing cleaning agents A47L13/19 takes precedence ; chemical compositions C11D17/049
• CPC Class Codes: D04H 1/587 characterised by the bonding agents used
• CPC Class Codes: D04H 1/64 the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
• CPC Class Codes: D06M 16/00 Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
• CPC Class Codes: D21H 21/36 Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture
• CPC Class Codes: Y10T 442/60 Nonwoven fabric [i.e., nonwoven strand or fiber material]

Abstract

An antimicrobially active wet wiper and a method of making the wiper. The wet wiper has an antimicrobially active non-woven web that includes: (i) bonded fibers; (ii) a binder in an amount effective to bind the fibers; and (iii) a first antimicrobial agent that is substantive to the fibers and to the binder when the web is either wet or dry. The web is maintained in a wet condition in a liquid containing a second antimicrobial agent until use.

Claims

1. An antimicrobially active wet wiper comprising:

(a) an antimicrobially active non-woven web comprising;

(i) bonded fibers;

(ii) a binder in an amount effective to bind the fibers;

(iii) a first antimicrobial agent being substantive to the fibers and to the binder when the web is either wet or dry; and

(b) a liquid containing a second antimicrobial agent, the web being maintained in a wet condition in the liquid until use.

2. The wet wiper of claim 1, wherein the second antimicrobial agent is an organic acid capable of exhibiting antimicrobial properties.

3. The wet wiper of claim 2, wherein the organic acids are naturally occurring.

4. The wet wiper of claim 2, wherein the organic acids are edible.

5. The wet wiper of claim 2, wherein the organic acid is selected from the group consisting of citric acid, sorbic acid, ethylenediaminetetraacetic acid, malic acid, and combinations thereof.

6. The wet wiper of claim 1, wherein the liquid is water.

7. The wet wiper of claim 1, wherein the second antimicrobial agent comprises a mixture of about 0.01% to about 0.20% weight sorbic acid and about 0.1% to about 0.5% weight citric acid, the weight percents being based upon the liquid.

8. The wet wiper of claim 1, wherein the fibers are selected from the group consisting of cellulosic fibers, synthetic fibers, and combinations thereof.

9. The wet wiper of claim 1, wherein the binder is a polymeric binder.

10. The wet wiper of claim 9, wherein the polymeric binder is a latex binder.

11. The wet wiper of claim 1, wherein the first antimicrobial agent is an organo-silicon quaternary ammonium salt.

12. The wet wiper of claim 1, wherein the first antimicrobial agent is selected from the group consisting of a 3-(trimethoxysilyl) propyldidecylmethyl ammonium salt and 3-(trimethoxysilyl) propyloctadecyldimethyl ammonium salt.

13. An antimicrobially active wet wiper comprising:

(a) an antimicrobially active non-woven web comprising;

(i) bonded cellulosic fibers;

(ii) a polymeric binder in an amount effective to bind the fibers;

(iii) a antimicrobial agent being substantive to the fibers and to the binder when the web is either wet or dry; and

(b) a liquid containing an antimicrobial organic acid, the web being maintained in a wet condition in the liquid until use.

14. The wet wiper of claim 13, wherein the organic acid is selected from the group consisting of citric acid, sorbic acid, ethylenediaminetetraacetic acid, malic acid, and combinations thereof.

15. The wet wiper of claim 14, wherein the antimicrobial agent is an organo-silicon quaternary ammonium salt.

16. The wet wiper of claim 15, wherein the organo-silicon quaternary ammonium salt is selected from the group consisting of 3-(trimethoxysilyl) propyldidecylmethyl ammonium salt and 3-(trimethoxylsilyl) propyloctadecyldimethyl ammonium salt.

17. The wet wiper of claim 13, wherein the organic acid is selected from the group consisting of sorbic acid, citric acid and combinations thereof.

18. The wet wiper of claim 17, wherein the liquid is water.

19. The wet wiper of claim 18, wherein the polymeric binder is a latex binder.

20. The wet wiper of claim 19, wherein the organic acid comprises a mixture of about 0.01% to about 0.20% weight sorbic acid and about 0.1% to about 0.5% weight citric acid, the weight percents being based upon the liquid.

21. The wet wiper of claim 20, wherein the sorbic acid is present in about 0.075% weight and the citric acid is present in about 0.375% weight.

22. The wet wiper of claim 13, wherein the antimicrobial agent is present in an amount in the range of about 0.25% to about 3% of the total web weight.

23. The wet wiper of claim 13, wherein the organic acid is present in the liquid in the range of about 0.3% to about 1.5% of the total liquid.

24. A method for preparing an antimicrobially active wet wiper comprising the steps of:

(a) forming an unbonded fibrous web;

(b) applying throughout the unbonded fibrous web an uncured binder and a first antimicrobial agent, the first antimicrobial agent being substantive to the fibers of the web and to the binder when the web is either wet or dry;

(c) curing the binder to bind the fibers together to form an antimicrobially active, non-woven web; and

(d) storing the web in a liquid containing a second antimicrobial agent to maintain the web in a wet condition until use.

25. The method of claim 24, wherein the second antimicrobial agent is a naturally occuring organic acid.

26. The method of claim 25 wherein the organic acid is selected from the group consisting of citric acid, sorbic acid, malic acid, and combinations thereof.

27. The method of claim 24 wherein the fibers are selected from the group consisting of cellulosic fibers, synthetic fibers, and combinations thereof.

28. The method of claim 24 wherein the first antimicrobial agent is an organo-silicon quaternary ammonium salt.

29. The method of claim 24, wherein the first antimicrobial agent is selected from the group consisting of 3-(trimethoxyiilyl) propyldidecylmethyl ammonium salt and 3-(trimethoxysilyl) propyloctadecyldimethyl ammonium salt.

30. The method of claim 24, wherein the amount of the first antimicrobial agent applied to the web is in the range of about 0.25% to about 3% of the total web weight.

31. The method of claim 24, wherein the amount of the binder applied to the web is in the range of about 5% to about 50% of the total web weight.

32. The method of claim 24, wherein the amount of the second antimicrobial agent present in the liquid is in the range of about 0.3% to about 1.5% of the total liquid.