Latex paint formulations and methods

• US 4,782,109 A
• Filed: 07/28/1987
• Issued: 11/01/1988
• Est. Priority Date: 06/26/1986
• Status: Expired due to Fees

• Current Assignee: Lindsay Finishes, Inc.
• Original Assignee: Lindsay Finishes, Inc.
• Inventors: Lindsay, Robert H., DuLaney, Donald C.
• Primary Examiner(s): Schofer, Joseph L.
• Assistant Examiner(s): Sarofim, N.
• Application Number:
  US07/078,835
• Time in Patent Office: 462 Days
• Field of Search: 524/501, 524/523, 524/524
• US Class Current: 524/501
• CPC Class Codes: C08L 25/14 with unsaturated esters
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 33/06 of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
• CPC Class Codes: C09D 125/08 Copolymers of styrene C09D129/08, C09D135/06, C09D155/02 take precedence
• CPC Class Codes: C09D 131/04 Homopolymers or copolymers of vinyl acetate
• CPC Class Codes: C09D 133/064 containing anhydride, COOH or COOM groups, with M being metal or onium-cation
• CPC Class Codes: C09D 5/02 Emulsion paints including aerosols

Abstract

A paint comprising a solution of an internal phase comprising pigment and latex resin and an external phase comprising an amine soluble resin dissolved in water is disclosed. The amine soluble resin has a molecular weight sufficiently high that it imparts desirable film properties while maintaining surface applicability of the paint. Upon evaporation of the water, the external phase forms a substantially continuous film encapsulating the internal phase. The invention also comprehends a novel method of paint formulation.

Claims

1. A paint solution substantially free of crosslinking consisting of:

an internal phase comprising pigment and latex resin; and

an external phase comprising an amine-soluble resin dissolved in water, said amine-soluble resin having a molecular weight sufficiently high that said amine soluble resin imparts an improvement in desirable film properties including hardness, flexibility, adhesion, water resistance and a high volume of solids to said paint while maintaining surface applicability of said paint, said external phase being effective in forming a substantially continuous film encapsulating said internal phase upon evaporation of said water at ambient temperature.

2. The paint of claim 1 wherein said amine soluble resin is a styrene acrylic resin.

3. The paint of claim 2 wherein said styrene acrylic resin has a molecular weight in the range of about 5,000-9,000.

4. The paint of claim 3 wherein said styrene acrylic resin has a molecular weight of about 7,000.

5. The paint of claim 1 wherein said latex resin comprises a resin selected from the group consisting of polyvinyl acetate copolymers, acrylic copolymers, styrene-acrylic copolymers and styrene-butadiene copolymers.

6. The paint of claim 1 wherein said amine soluble resin comprises about 10-50% of the total resin solids present in said solution.

7. The paint of claim 6 wherein said amine soluble resin comprises about 20-30% of the total solids in said solution.

8. The paint of claim 1 wherein said amine soluble resin comprises more than about 30% of the total solids present in said solution and said paint additionally includes a compatible plasticizer effective in minimizing embrittlement of the film formed upon evaporation of said water.

9. The paint of claim 1 wherein dissolution of said amine soluble resin in said water is enhanced by the presence of a solubilizing agent.

10. The paint of claim 9 wherein said solubilizing agent comprises ammonia.

11. The paint of claim 1 additionally including an additive effective in reducing sensitivity to cleaning agents.

12. The paint of claim 11 wherein said cleaning agents comprise a salt of a strong base and a weak acid.

13. The paint of claim 10 wherein said additive is selected from the group consisting of lime and calcium hydroxide.

14. A method of formulating a paint capable of being set without the use of a crosslinking agent or the addition of heat comprising the steps of:

dispersing an amine-soluble resin and pigment at high speed to form a mixture, said amine soluble resin having a molecular weight sufficiently high that said amine soluble resin imparts in improvement in desirable film properties including hardness, flexibility, adhesion, water resistance and a high volume of solids to said paint while maintaining surface applicability of said paint; and

mixing a latex resin with said mixture.

15. The method of claim 14 wherein said paint is an enamel and said high speed dispersing step is continued until said enamel attains a Hegman level of at least about 6.

16. The method of claim 14 wherein said paint is a primer and said high speed dispersion is continued until said primer attains a Hegman level of about 3-4.

17. The method of claim 14 wherein said paint is a flat paint and said high speed dispersion is continued until said flat paint attains a Hegman level of about 3.

18. The method of claim 14 wherein said amine soluble resin is a styrene acrylic resin.

19. The method of claim 18 wherein said styrene acrylic resin has a molecular weight in the range of about 5,000-9,000.

20. The method of claim 19 wherein said styrene acrylic resin has a molecular weight of about 7,000.

21. The method of claim 14 wherein said latex resin comprises a resin selected from the group consisting of polyvinyl acetate copolymers, acrylic copolymers, styrene-acrylic copolymers and styrene-butadiene copolymers.

22. The method of claim 14 wherein said amine soluble resin comprises about 10-50% of the total resin solids present in said solution.

23. The method of claim 22 wherein said amine soluble resin comprises about 20-30% of the total solids in said solution.

24. The method of claim 14 wherein said amine soluble resin comprises more than about 30% of the total solids present in said solution and said paint additionally comprises a compatible plasticizer effective in minimizing embrittlement of the film formed upon evaporation of said water.

25. The method of claim 14 wherein dissolution of said amine soluble resin in said water is enhanced by the presence of a solubilizing agent.

26. The method of claim 25 wherein said solubilizing agent comprises ammonia.

27. The method of claim 14 wherein said paint additionally includes an additive effective in reducing sensitivity to cleaning agents.

28. The method of claim 27 wherein said cleaning agents comprise a salt of a strong base and a weak acid.

29. The method of claim 28 wherein said additive is selected from the group consisting of lime and calcium hydroxide.