Magnetic recording medium

• US 4,784,907 A
• Filed: 12/22/1986
• Issued: 11/15/1988
• Est. Priority Date: 12/20/1985
• Status: Expired due to Term

• Current Assignee: Fuji Photo Film Co Limited (Fujifilm Holdings Corporation)
• Original Assignee: Fuji Photo Film Co Limited (Fujifilm Holdings Corporation)
• Inventors: Yamada, Yasuyuki, Matsufuji, Akihiro, Kasuga, Akira, Komine, Shigeo, Miyatsuka, Hajime
• Primary Examiner(s): Robinson, Ellis P.
• Application Number:
  US06/944,068
• Time in Patent Office: 694 Days
• Field of Search: 428/694, 428/695, 428/900, 428/522, 428/425.9, 428/328, 428/329, 427/128, 427/131, 252/62.54, 360/134-136
• US Class Current: 428/328
• CPC Class Codes: G11B 5/7023 containing polyesters, polyethers, silicones, polyvinyl resins, polyacrylresins or epoxy resins G11B5/7022 takes precedence
• CPC Class Codes: G11B 5/71 characterised by the lubricant
• CPC Class Codes: Y10S 428/90 Magnetic feature
• CPC Class Codes: Y10T 428/256 Heavy metal or aluminum or compound thereof
• CPC Class Codes: Y10T 428/257 Iron oxide or aluminum oxide
• CPC Class Codes: Y10T 428/31609 Particulate metal or metal compound-containing
• CPC Class Codes: Y10T 428/31935 Ester, halide or nitrile of addition polymer

Abstract

In a magnetic recording medium such as a video tape comprising a nonmagnetic support and a magnetic recording layer provided on the support, said magnetic recording layer comprising a binder and a ferromagnetic powder dispersed therein, the improvement in which:

the magnetic recording layer comprises a fatty acid ester lubricant and a lubricant other than the fatty acid ester lubricant;

the binder is composed of a resin component comprising a resin containing a repeating unit which has a polar group and having a glass transition point of not lower than 50° C., and a resin containing a repeating unit which has a polar group and having a glass transition point of lower than 50° C; and

at least one resin of the resins contains a repeating unit having a polar group such as --SO₃ M, --OSO₃ M or --PO(OM'"'"')₂, wherein M is hydrogen or an alkali metal atom, and M'"'"' is hydrogen, an alkali metal atom or a lower hydrocarbon group.

Claims

1. A magnetic recording medium comprising a non-magnetic support and a magnetic recording layer provided on the support, said magnetic recording layer comprising a binder and a ferromagnetic powder dispersed therein, which is characterized in that:

said magnetic recording layer comprises a fatty acid ester lubricant and a lubricant other than the fatty acid ester lubricant;

said binder is composed of a resin component comprising a vinyl chloride copolymer resin containing a repeating unit which has a polar group and having a glass transition point of not lower than 50°

C. and a polyurethane resin containing a repeating unit which has a polar group and having a glass transition point of lower than 50°

C., a ratio by weight of said vinyl chloride copolymer resin to said polyurethane resin being in the range of 70/30 to 30/70; and

at least one resin of said resins contains a repeating unit having at least one polar group selected from the group consisting of --SO₃ M, --OSO₃ M and --PO(OM'"'"')₂, wherein M is hydrogen or an alkali metal atom, and M'"'"' is hydrogen, an alkali metal atom or a lower hydrocarbon group.

2. The magnetic recording medium as claimed in claim 1, wherein said ferromagnetic powder is a ferromagnetic metal powder having a specific surface area of not less than 45 m² /g.

3. The magnetic recording medium as claimed in claim 1, wherein said vinyl chloride copolymer contains a repeating unit having --SO₃ Na in an amount ranging from 0.01 to 5 mol%.

4. The magnetic recording medium as claimed in claim 1, wherein said polyurethane resin contains a repeating unit having --SO₃ Na in an amount ranging from 0.01 to 5 mol%.

5. The magnetic recording medium as claimed in claim 1, wherein said fatty acid ester lubricant is an ester of a fatty acid having 12-22 carbon atoms and a fatty alcohol having 2-18 carbon atoms.

6. The magnetic recording medium as claimed in claim 1, wherein said lubricant other than the fatty acid ester lubricant is at least one lubricant selected from the group consisting of a fatty acid lubricant, a silicone lubricant and a fatty acid modified silicone lubricant.

7. The magnetic recording medium as claimed in claim 1, wherein a total amount of the fatty acid ester lubricant and the lubricant other than the fatty acid ester lubricant in the magnetic recording layer is in the range of 0.1 to 10 parts by weight based on 100 parts by weight of the ferromagnetic powder, and the ratio between the fatty acid ester lubricant and the lubricant other than the fatty acid ester lubricant is in the range of 1:

9 to 9;

1, by weight.