Composite conformable sheet electrodes

• US 4,786,837 A
• Filed: 05/05/1987
• Issued: 11/22/1988
• Est. Priority Date: 05/05/1987
• Status: Expired due to Fees

• Current Assignee: Hoechst Celanese Corporation (Sanofi )
• Original Assignee: Hoechst Celanese Corporation (Sanofi )
• Inventors: Breckenridge, George J. Jr., Kalnin, Ilmar L.
• Primary Examiner(s): Budd, Mark O.
• Application Number:
  US07/046,076
• Time in Patent Office: 567 Days
• Field of Search: 310/363-366, 310/330-332, 310/334, 310/336, 310/337, 310/357, 310/358, 310/800
• US Class Current: 310/364
• CPC Class Codes: B06B 1/0688 with foil-type piezoelectric elements, e.g. PVDF
• CPC Class Codes: H10N 30/87 Electrodes or interconnections, e.g. leads or terminals
• CPC Class Codes: H10N 30/878 the principal material being non-metallic, e.g. oxide or carbon based
• CPC Class Codes: Y10S 310/80 Piezoelectric polymers, e.g. PVDF

Abstract

A method is described for making an electroconductive composite sheet electrode which is conformable and in which a slit-and-expanded or perforated nickel screen is embedded by heat and pressure, so that electrical leads can be easily and strongly attached to the nickel screen before or after integrally bonding a electroconductive sheet electrode to each side of at least one adjacent piezoelectric ceramic/polymer composite sheet electrode which is non-conductive. After poling, the resultant transducer has an increased combined transverse stiffness which increases the hydrostatic voltage coefficient, g_h, as well as the overall hydrophone Figure of Merit. Because the nickel screen is formed from a continuous metal sheet by slitting and traction or by perforation, it possesses internal electrical continuity and is much more electroconductive than a conventional woven metal wire screen of the same dimensions, thereby enabling the conductive composite electrode to show higher electrical conductivity than a similar woven wire-reinforced one and also lowering the thermally generated electrical noise of the piezoelectric composite transducer formed therefrom.

Claims

1. A composite sheet electrode, comprising a conductive polymer sheet or film and a slit-and-expanded screen formed from a sheet of a selected metal, said conductive polymer in said polymer sheet being ethylene/propylene/diene elastomer (EPR) and said metal sheet being embedded into said polymer sheet and having exposed portions to which electrical leads can be soldered.

2. The composite electrode of claim 1, wherein said metal is nickel.

3. The electrode of claim 1, wherein said sheet or film comprises an electrically conductive but piezoelectrically inactive powder which is selected from the group consisting of carbon, nickel, and copper.

4. The electrode of claim 1, wherein said selected metal is nickel.

5. The electrode of claim 1, wherein said screen has approximately 25 to 2,600 diamond-shaped openings per square inch, each said opening being bounded by four strands having a width which is from one ot six times the thickness of said metal sheet.

6. The electrode of claim 5, wherein said screen has approximately 625 diamond-shaped openings per square inch and said sheet thickness is 0.002-0.12 inch before expansion of said sheet.

7. The elctrode of claim 1, wherein said screen is mechanically anisotropic in the transverse plane thereof, whereby several resonances can be generated in said composite sheet electrode or the resonance bandwidth thereof can be broadened.

8. The electrode of claim 5, wherein said openings are formed by expansion of said metal sheet from slits therein, said slits being 0.5 to 15 mm in length and 0.1 to 1.5 mm apart, without extending any slit closer than 3 mm to any edge of said metal sheet.

9. The electrode of claim 8, wherein said composite sheet electrode has a conductance that is:

A. higher than the conductance of a conventional conductive polymer electrode or a woven-wire reinforced electrode; and

B. adjustable to a desired magnitude by changing;

(1) the distance between said slits,

(2) the number of said slits per unit area in said metal sheet,

(3) said metal sheet thickness, and

(4) the extent of traction applied in the longitudinal and transverse directions of said metal sheet during said expansion thereof.

10. A piezoelectric transducer, having a substantially increased hydrostatic piezoelectric voltage coefficient and lowered thermally generated electrical noise, comprising:

A. A piezoelectric composite sheeet comprising a thermoplastic polymer and a piezo-ceramic powder having a particle size in the 1-20 μ

m range;

B. a conductive composite sheet electrode, containing a thermoplastic polymer and a continuous slit-and-expanded metal screen, said screen being embedded in said polymer and one of said composite sheet electrodes being bonded to each side of said piezoelectric composite sheet; and

C. electrical leads attached to exposed portions of said metal screen.

12. The transducer of claim 10, wherein said conductive composite sheet electrode comprises an electrically conductive but piezoelectrically inactive powder which is selected from the group consisting of carbon, nickel, and copper.

13. The transducer of claim 12, wherein said carbon is graphite.

14. The transducer of claim 10, wherein said piezo-ceramic powder is a solid solution of lead titanate and bismuth ferrite (PTBF).

15. The transducer of claim 10, wherein said continuous metal screen is a slit-and-expanded nickel screen.

16. The transducer of claim 15, wherein said screen has approximately 25 to 2,600 diamond-shaped openings per square inch, each said opening being bounded by four strands having a width which is from one to six times the thickness of said metal sheet, and the overall thickness of said screen being less than twice said strand width.

17. The transducer of claim 16, wherein said screen has approximately 625 diamond-shaped openings per square inch and said sheet thickness is b 0.002-0.12 inch before expansion thereof.

18. The transducer of claim 16, wherein said screen is mechanically anisotropic in the transverse plane thereof, whereby several resonances can be generated in said composite sheet electrode or the resonance bandwidth thereof can be broadened.

19. The transducer of claim 16, wherein said openings are formed by expansion of said metal sheet from slits therein, said slits being 0.5 to 15 mm in length and 0.1 to 1.5 mm apart, without extending any slit closer than 3 mm to any edge of said metal sheet.

20. The transducer of claim 19, wherein said composite sheet electrode has a conductance that is:

A. higher than the conductance of a conventional conductive polymer electrode or a woven-wire reinforced electrode; and

B. adjustable to a deisred magnitude by changing;

(1) the distance between said slits,

(2) the number of said slits per unit area in said metal sheet,

(3) said metal sheet thickness, and

(4) the extent of traction applied in the longitudinal and transverse directions of said metal sheet during said expansion thereof.

11. A piezoelectric transducer, having a substantially increased hydrostatic piezoelectric voltage coefficient and lowered thermally generated electrical noise, comprising:

A. a piezoelectric composite sheet comprising a thermoplastic polymer and a piezo-ceramic powder having a particle size in the 1-20 μ

m range;

B. a conductive composite sheet electrode, containing a thermoplastic polymer and a continuous metal screen, which is bonded to each side of said piezoelectric composite sheet; and

C. electrical leads attached to exposed portions of said metal screen, wherein said polymer, in both said piezoelectric composite sheet and in said composite sheet electrode, is an ethylene/propylene/diene elastomer (EPR).