Method of sintering by induction

• US 4,788,396 A
• Filed: 12/08/1987
• Issued: 11/29/1988
• Est. Priority Date: 12/11/1986
• Status: Expired due to Fees

• Current Assignee: Societe Anonyme DBA
• Original Assignee: Centre National De La Recherche Scientifique
• Inventors: Ernst, Roland, Maugein, Christian
• Primary Examiner(s): Leung, Philip H.
• Application Number:
  US07/130,221
• Time in Patent Office: 357 Days
• Field of Search: 219/10.41, 219/10.43, 219/10.57, 219/10.61 R, 219/10.71, 219/10.79, 148/150, 148/154, 266/129
• US Class Current: 219/645
• CPC Class Codes: B22F 2998/00 Supplementary information concerning processes or compositions relating to powder metallurgy
• CPC Class Codes: B22F 3/105 by using electric current other than for infrared radiant energy, laser radiation or plasma B22F3/11 takes precedence; by ultrasonic bonding B22F3/115 takes precedence
• CPC Class Codes: B22F 7/002 of porous nature
• CPC Class Codes: H01M 4/04 Processes of manufacture in general
• CPC Class Codes: H01M 4/0404 by coating on electrode collectors
• CPC Class Codes: H01M 4/043 involving compressing or compaction
• CPC Class Codes: H01M 4/0471 involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
• CPC Class Codes: H05B 6/104 metal pieces being elongated like wires or bands
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

An electrode composed of a mixture of electrochemically active particles and metal powder compressed onto a metal foil strip can be inductively sintered without localized overheating by passing the coated strip through a hairpin-shaped inductor provided with widened portions facing the edge regions of the strip, so as to locally increase the cross section of the hairpin in the portions of the hairpin that are opposed to the edge regions of the electrode strip. This arrangement counteracts the tendency of the edge regions to overheat and thermally damage the active material.

Claims

1. A method of sintering by induction an electrode for an electrochemical cell, said electrode being constituted by a metal strip having a mixture of metal powder and of active material powder previously compressed onto the faces thereof, the method comprising displacing said strip longitudinally through an inductor having a high frequency current flowing therein, said inductor being generally in the form of a hairpin having two branches situated on opposite sides of said strip and extending perpendicularly to its direction of displacement, wherein the improvement comprises:

providing each branch of said hairpin with widened portions extending parallel to the strip in the zones facing the edges of the strip so as to serve to locally increase the cross-section through which the inducing current passes in such a way that the whole electrode remains at a uniform temperature suitable to sintering said metal powder without damage to said active material powder.

2. A sintering method according to claim 1, wherein said metal strip is constituted by a perforated metal foil having a linear non-perforated zone running substantially along the middle thereof, with additional widened portions being provided on the branches of said hairpin inductor where they face said linear zone.

3. A sintering method according to claim 1, wherein the displacement speed of said strip lies between 1 meter per minute and 10 meters per minute, and the temperature rise time in the heated zone lies between 0.1 seconds and 1.5 seconds.

4. In an apparatus of sintering by induction an electrode for an electromechanical cell, said electrode being constituted by a metal strip having a mixture of metal powder and of active material powder previously compressed on the faces thereof, an inductor being generally in the form of a hairpin having two branches situated on opposite sides of said strip and extending perpendicularly to the edges of the strip, wherein each of the branches has at least one widened portion extending orthogonally to the plane formed by said branches, in the vicinity of the edges of the electrode strip.

5. The apparatus according to claim 4, wherein said widened portions of said inductor are constituted by metal plates added to said branches of said inductor.

6. The apparatus according to claim 4, wherein said branches of said inductor are machined in solid material so as to have said widened portions of said inductor.