Electrodes for the combined measurement of oxygen and carbon dioxide

• US 4,789,453 A
• Filed: 01/25/1988
• Issued: 12/06/1988
• Est. Priority Date: 06/06/1986
• Status: Expired due to Fees

• Current Assignee: Kontron Instruments Holding, N.V.
• Original Assignee: Kontron Holding AG (Roche Holding AG)
• Inventors: Mindt, Wolfgang, Eberhard, Patrick, Palma, Jean-Pierre
• Primary Examiner(s): Kaplan, G. L.
• Application Number:
  US07/147,632
• Time in Patent Office: 316 Days
• Field of Search: 204/412, 204/403, 204/415, 204/1 P, 204/1 K, 128/635
• US Class Current: 204/403.13
• CPC Class Codes: G01N 27/404 Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid , e.g. Clark-type oxygen sensors
• CPC Class Codes: G01N 27/4045 for gases other than oxygen

Abstract

A combined sensor for sensing partial O₂ pressure and partial CO₂ pressure and comprising measuring electrodes, a reference electrode, a diaphragm covering the electrodes and an electrolyte layer between the electrodes and the diaphragm wherein the reference electrode has disposed around it a screening of gold which is at the same potential as the reference electrode and the electrolyte contains a defined concentration of a soluble silver compound or of a silver complex.

Claims

1. An electrode arrangement for the combined measurement of the partial O₂ and CO₂ pressures of a medium, the arrangement comprising measuring electrodes, one of which applies for PO₂ and the other applies for PCO₂, a reference electrode, a diaphragm covering the electrodes and an electrolyte layer between the electrodes and the diaphragm, the reference electrode has disposed thereon a layer of gold which is at the same potential as the reference electrode and the electrolyte contains a predetermined concentration of a soluble silver compound or of a silver complex.

2. The electrode arrangement of claim 1, wherein the reference electrode has a circular surface with a diameter of at least about one-tenth and at most about one-third of the diameter of the total measuring area of the electrode.

3. The electrode arrangement of claim 1, wherein the soluble silver compound is selected from the group consisting of AgCl, AgCN, and AgNO₃.

4. The electrode arrangement of claim 1, wherein the silver complex is formed by complexing silver with a complexing agent selected from the group consisting of EDTA and DTPA.

5. The electrode arrangement of claim 1, wherein the electrolyte contains about 10 to about 100×

10^-6 mol/l of silver.