Inhibiting voltage suppression in lithium/fluorinated carbon batteries

• US 4,791,038 A
• Filed: 10/09/1986
• Issued: 12/13/1988
• Est. Priority Date: 10/09/1986
• Status: Expired due to Fees

• Current Assignee: Alliedsignal Inc. (Honeywell International Inc.)
• Original Assignee: Alliedsignal Inc. (Honeywell International Inc.)
• Inventors: Pyszczek, Michael F., Nalewajek, David, Shia, George A.
• Primary Examiner(s): Niebling, John F.
• Assistant Examiner(s): MARQUIS, STEVEN
• Application Number:
  US06/917,455
• Time in Patent Office: 796 Days
• Field of Search: 429/218, 429/212, 423/439, 423/489
• US Class Current: 429/212
• CPC Class Codes: H01M 4/583 Carbonaceous material, e.g. graphite-intercalation compounds or CFx
• CPC Class Codes: H01M 4/5835 Comprising fluorine or fluoride salts
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

Voltage suppression is an important problem in the Li/CF_x battery system. The voltage that a Li/CF_x battery will deliver just after the circuit has been closed can be as low as the voltage near the end of battery life. Electronic circuitry powered by Li/CF_x batteries are complicated by the need to design around this problem.

The processing of fluorinated carbon (CF_x) to lower the initial voltage suppression is disclosed wherein fluorinated carbon is treated with a Group IA metal-alkyl or -aryl compound. The reaction between these compounds (e.g., n-butyl lithium) and the fluorinated carbon produces a battery grade product which undergoes reduced to almost no suppression of the initial closed circuit voltage.

Claims

1. A lithium/fluorinated carbon battery having a reduced initial voltage suppression which comprises the incorporation in the battery cathode of fluorinated carbon which has been reacted with a compound selected from the group consisting of a Group IA metal-alkyl compound and a Group IA metal-aryl compound, which Group IA metal-aryl compound has at least 10 carbon atoms, until surface fluorine on the fluorinated carbon has been stripped and alkyl or aryl groups from the Group IA metal-alkyl compound or Group IA metal-aryl compound are substituted for surface fluorine atoms.

2. The battery of claim 1 in which surface fluorine on the fluorinated carbon has been substantially stripped.

3. The battery of claim 1 in which from about 5-10% of the surface fluorine on the fluorinated carbon has been stripped.

4. The battery of claim 3 wherein the Group IA metal compound is a Group IA metal-alkyl compound.

5. The battery of claim 4 wherein the Group IA metal compound contains from 1-4 carbon atoms.

6. The battery of claim 5 wherein the Group IA metal compound is selected from the group consisting of methyl lithium, ethyl lithium, n-propyl lithium and n-butyl lithium.

7. The battery of claim 6 wherein the Group IA metal compound is n-butyl lithium.

8. The battery of claim 3 wherein the Group IA metal compound is a Group IA metal-aryl compound.

9. The battery of claim 8 wherein the aryl compound is selected from the group consisting of naphthalene, anthracene and pyrene.

10. The battery of claim 9 wherein the Group IA metal is selected from lithium, sodium and potassium.

11. The battery of claim 10 in which the Group IA metal is lithium.

12. The battery of claim 10 wherein the Group IA metal-aryl compound is sodium naphthalide.