High oxygen barrier coextruded film

• US 4,792,488 A
• Filed: 12/18/1987
• Issued: 12/20/1988
• Est. Priority Date: 10/11/1985
• Status: Expired due to Term

• Current Assignee: Cryovac Incorporated (Sealed Air)
• Original Assignee: WR Grace & Company
• Inventors: Schirmer, Henry G.
• Primary Examiner(s): Buffalow, Edith
• Application Number:
  US07/136,175
• Time in Patent Office: 368 Days
• Field of Search: 428/349, 428/518, 428/516, 428/520
• US Class Current: 428/349
• CPC Class Codes: B29C 48/08 flexible, e.g. films
• CPC Class Codes: B29C 48/185 comprising six or more components, i.e. each component being counted once for each time it is present, e.g. in a layer
• CPC Class Codes: B32B 2307/7244 Oxygen barrier
• CPC Class Codes: B32B 2309/02 Temperature
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/30 comprising vinyl (co)polymers; comprising acrylic (co)polymers
• CPC Class Codes: B32B 27/304 comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
• CPC Class Codes: B32B 27/306 comprising vinyl acetate or vinyl alcohol (co)polymers
• CPC Class Codes: B32B 7/12 using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: Y10T 428/2826 Synthetic resin or polymer
• CPC Class Codes: Y10T 428/31913 Monoolefin polymer
• CPC Class Codes: Y10T 428/3192 Next to vinyl or vinylidene chloride polymer
• CPC Class Codes: Y10T 428/31928 Ester, halide or nitrile of addition polymer

Abstract

A coextruded multilayer film includes a layer of a vinylidene chloride copolymer, and a layer of ethylene vinyl alcohol copolymer. The coextruded film has high oxygen barrier properties under both high and low humidity conditions.

Claims

1. A coextruded multi-layer thermoplastic film comprising:

(a) a layer comprising vinylidene chloride copolymer;

(b) a layer comprising ethylene vinyl alcohol copolymer;

(c) an intermediate layer disposed between said vinylidene chloride copolymer and ethylene vinyl alcohol copolymer layers and comprising an adhesive polymeric material;

(d) fourth and fifth layers disposed on the respective surfaces of the vinylidene chloride copolymer and ethylene vinyl alcohol copolymer layers opposite said intermediate layer, either of said fourth and fifth layers comprising an adhesive polymeric material, and the other of said fourth or fifth layers comprising a copolymer of ethylene; and

(e) sixth and seventh layers disposed on the outside of said fourth and fifth layers, said sixth and seventh layers selected from the group consisting of polyolefins and copolymers of ethylene.

2. The film according to claim 1 wherein the vinylidene chloride copolymer comprises vinylidene chloride vinyl chloride copolymer.

3. The film according to claim 1 wherein the intermediate layer, and either of the fourth and fifth layers comprises an acid- or acid anhydride-modified polymeric material.

4. The film according to claim 3 wherein the acid- or acid anhydride-modified polymeric material comprises an acid- or acid anhydride-modified ethylene vinyl acetate copolymer.

5. The film according to claim 1 wherein the copolymer of ethylene comprises an ethylene vinyl acetate copolymer.

6. A coextruded multi-layer thermoplastic film comprising

(a) a first layer comprising a copolymer of ethylene;

(b) a second layer comprising a copolymer of ethylene;

(c) a third or barrier layer comprising vinylidene chloride copolymer;

(d) a fourth layer comprising an adhesive polymeric material;

(e) a fifth or barrier layer comprising ethylene vinyl alcohol copolymer;

(f) a sixth layer comprising an adhesive polymeric material; and

(g) a seventh layer comprising a copolymer of ethylene.

7. The film according to claim 6 wherein the first layer comprises ethylene vinyl acetate copolymer.

8. The film according to claim 7 wherein the first layer of ethylene vinyl acetate has a vinyl acetate content of between about 2% and 8% by weight.

9. The film according to claim 7 wherein the first layer of ethylene vinyl acetate copolymer has a vinyl acetate content of between about 2% and 5% by weight.

10. The film according to claim 7 wherein the ethylene vinyl acetate copolymer has a vinyl acetate content of about 4.5% by weight.

11. The film according to claim 6 wherein the second layer comprises ethylene vinyl acetate copolymer.

12. The film according to claim 11 wherein the ethylene vinyl acetate copolymer has a vinyl acetate content of between about 10% and about 30% by weight.

13. The film according to claim 11 wherein the ethylene vinyl acetate copolymer has a vinyl acetate content of between about 17% and 18% by weight.

14. The film according to claim 6 wherein the third or barrier layer comprises vinylidene chloride vinyl chloride copolymer.

15. The film according to claim 6 wherein the fourth and sixth layers comprise an acid- or acid anhydride-modified polymeric material.

16. The film according to claim 15 wherein the acid- or acid anhydride-modified polymeric material comprises an acid- or acid anhydride-modified ethylene vinyl acetate copolymer.

17. The film according to claim 6 wherein the seventh layer comprises ethylene vinyl acetate copolymer.

18. The film according to claim 17 wherein the ethylene vinyl acetate copolymer has a vinyl acetate content of between about 20% and 40% by weight.

19. The film according to claim 17 wherein the ethylene vinyl acetate copolymer has a vinyl acetate content of about 28% by weight.

20. The film according to claim 6 wherein said film is a lay-flat tubular film having its interior lay-flat surfaces welded together.