Evaporation inhibitor compositions

• US 4,793,850 A
• Filed: 11/14/1985
• Issued: 12/27/1988
• Est. Priority Date: 03/02/1985
• Status: Expired due to Term

• Current Assignee: Cognis Deutschland GmbH & Co. KG (BASF SE)
• Original Assignee: Henkel KGaA (Henkel AG & Co KGaA), Hoechst Aktiengesellschaft (Sanofi )
• Inventors: Schmid, Karl, Koester, Josef, Albrecht, Konrad, Bittner, Paul, Keim, Fritz
• Primary Examiner(s): Mills, Catherine L.
• Application Number:
  US06/798,210
• Time in Patent Office: 1,139 Days
• Field of Search: 71/DIG. 1, 71/79, 47/DIG. 11, 106/271, 514/772
• US Class Current: 504/363
• CPC Class Codes: A01N 25/02 containing liquids as carriers, diluents or solvents
• CPC Class Codes: A01N 25/04 Dispersions, emulsions, suspoemulsions, suspension concentrates or gels foams A01N25/16
• CPC Class Codes: Y10S 47/11 The application of protective coatings to plants

Abstract

An evaporation inhibitor composition which consists essentially of:

A. from about 15 to about 50% by weight of a wax mixture containing at least about 5% by weight, based on the wax mixture, of a wax component having an acid number of from about 10 to about 95 mg KOH/g wax;

B. from about 4 to about 20% by weight of at least one nonionic and/or anionic emulsifier;

C. from about 19.5 to about 81% by weight of water and/or at least one organic solvent selected from the group consisting of hydrocarbons, esters, and ketones having a boiling point of from about 70° to about 280° C.

Claims

1. An evaporation inhibitor composition consisting of:

A. from about 15 to about 50% by weight of a wax mixture containing at least about 5% by weight, based on the wax mixture, of a wax component having an acid number of from about 10 to about 95 mg KOH/g wax;

said wax mixture being selected from one of the following;

a. from about 60 to about 95% by weight of paraffin wax and/or microcrystalline paraffin wax having a setting point of from about 40°

to about 70°

C., and from about 5 to about 40% by weight of oxidized polyethylene wax having a dropping point of from about 95°

to about 140°

C. and an acid number of from about 10 to about 95 mg KOH/g wax;

b. from about 60 to about 95% by weight of paraffin wax and/or microcrystalline paraffin wax having a setting point of from about 40°

to about 70°

C., and from about 5 to about 40% by weight of wax containing ester bonds and having a dropping point of from about 75°

to about 100°

C. and an acid number of from about 10 to about 95 mg KOH/g wax; and

c. from about 20 to about 50% by weight of paraffin wax having a setting point of from about 30°

to about 50°

C., and from about 50 to about 80% by weight of oxidized paraffin wax having a setting point of from about 60°

to about 90°

C. and an acid number of from about 10 to about 95 mg KOH/g wax;

B. from about 4 to about 20% by weight of at least one nonionic and/or anionic emulsifier; and

C. from about 19.5 to about 81% by weight of water and/or at least one organic solvent selected from the group consisting of hydrocarbons, esters, and ketones having a boiling point of from about 70°

to about 280°

C.

2. A composition in accordance with claim 1 wherein up to 5% by weight of an amine or an alkali metal hydroxide is also present therein.

3. A composition in accordance with claim 1 wherein up to 5.5% by weight of one or more of a dye, a viscosity regulator, a foam regulator, a preservative, an inorganic salt, and a hydrotrope is also present therein.

4. A composition in accordance with claim 2 wherein up to 5.5% by weight of one or more of a dye, a viscosity regulator, a foam regulator, a preservative, an inorganic salt, and a hydrotrope is also present therein.

5. A composition in accordance with claim 1 wherein the composition consists essentially of:

A. from about 15 to about 40% by weight of a., b., or c.;

B. an emulsifier which is

a. from about 4 to about 20% by weight of at least one nonionic emulsifier, and

b. from 0 to about 10% by weight of at least one anionic emulsifier, wherein the nonionic emulsifier makes up at least 50% by weight of component B;

C. from about 29.5 to about 81% by weight of water and from 0 to about 10% by weight of the at least one organic solvent;

D. from 0 to about 5% by weight of at least one hydrotrope;

E. from 0 to about 0.5% by weight of at least one inorganic salt; and

F. from 0 to about 5.0% by weight of an amine or an alkali metal hydroxide.

7. A composition in accordance with claim 5 wherein component B.a. is present in from about 4 to about 14% by weight and component B.b. is present in from about 1 to about 7% by weight.

8. A composition in accordance with claim 1 wherein the at least one nonionic emulsifier of component B is at least one of a sorbitan ester of a higher fatty acid or a long-chain alkyl glycoside, and an alkylene oxide adduct with a higher, C₁₀ -C₂₄ linear monofunctional or polyfunctional alcohol, an alkylphenol, a long-chain carboxylic acid, a carboxylic acid amide, a hydroxy fatty acid, or a fatty acid glycerol, or sorbitan ester or a long-chain alkyl glycoside.

9. A composition in accordance with claim 8 wherein the at least one nonionic emulsifier is at least one of an adduct of from 2 to 50 moles of ethylene oxide with a C₁₂ -C₁₈ long-chain primary alcohol or fatty acid.

10. A composition in accordance with claim 1 wherein at least one nonionic emulsifier in component B. is a mixture of ethylene oxide adducts with C₁₂ -C₁₈ fatty alcohols or an alkylphenol having

from about 10 to about 40% by weight of adducts containing from 1 to 4 moles of ethylene oxide,

from about 25 to about 70% by weight of adducts containing from 4 to 10 moles of ethylene oxide, and

from about 5 to about 35% by weight of adducts containing from 10 to 50 moles of ethylene oxide.

11. A composition in accordance with claim 1 wherein the anionic emulsifier in component B is at least one of a salt of a sulfuric acid semiester, a phosphoric acid partial ester of a linear alcohol or an alkylphenol containing from 12 to 18 carbon atoms or a polyglycol monoalkylether containing from 12 to 18 carbon atoms in the alkyl group, an olefin sulfonate, an ester sulfonate, and an alkane sulfonate wherein such sulfonates contain from 12 to 20 carbon atoms, an alkylbenzene sulfonate containing from 6 to 16 carbon atoms in the alkyl group, a sulfonate of a polyglycol monoalkylether, and a salt of a polyglycol monoalkylether carboxylic acid containing from 12 to 18 carbon atoms in the alkyl chain.

12. A composition in accordance with claim 11 wherein the anionic emulsifier is one or more of an alkylbenzene sulfonate containing from 6 to 16 carbon atoms in the alkyl group, and an alkane sulfonate containing from 12 to 20 carbon atoms.

13. A composition in accordance with claim 1 wherein component B. is present in from about 4 to about 14% by weight.

14. An aqueous agricultural spray composition comprising at least one agriculturally active ingredient and from about 1 to about 15% by weight of an evaporation inhibitor composition of claim 1.

15. An aqueous spray composition in accordance with claim 14 wherein from about 5 to about 10% by weight of an evaporation inhibitor composition of claim 1 is present therein.

6. A composition in accordance with claim 6 wherein component B.b. is present in from about 1 to about 7% by weight.

16. A method for reducing the evaporation of water from an aqueous spray mixture containing at least one agricultural chemical comprising mixing therewith an evaporation inhibitor composition consisting essentially of:

A. from about 15 to about 50% by weight of a wax mixture containing at least about 5% by weight, based on the wax mixture, of a wax component having an acid number of from about 10 to about 95 mg KOH/g wax;

said wax mixture being selected from one of the following;

a. from about 60 to about 95% by weight of paraffin wax and/or microcrystalline paraffin wax having a setting point of from about 40°

to about 70°

C., and from about 5 to about 40% by weight of oxidized polyethylene wax having a dropping point of from about 95°

to about 140°

C. and an acid number of from about 10 to about 95 mg KOH/g wax;

b. from about 60 to about 95% by weight of paraffin wax and/or microcrystalline paraffin wax having a setting point of from about 40°

to about 70°

C., and from about 5 to about 40% by weight of wax containing ester bonds and having a dropping point of from about 75°

to about 100°

C. and an acid number of from about 10 to about 95 mg KOH/g wax; and

c. from about 20 to about 50% by weight of paraffin wax having a setting point of from about 30°

to about 50°

C., and from about 50 to about 80% by weight of oxidized paraffin wax having a setting point of from about 60°

to about 90°

C. and an acid number of from about 10 to about 95 mg KOH/g wax;

B. from about 4 to about 20% by weight of at least one nonionic and/or anionic emulsifier;

C. from about 19.5 to about 81% by weight of water and/or at least one organic solvent selected from the group consisting of hydrocarbons, esters, and ketones having a boiling point of from about 70°

to about 280°

C., and spraying said aqueous mixture onto agricultural crops by the Low-Volume method in a quantity of from about 5 to about 50 liters/hectare.

17. A method in accordance with claim 16 wherein from about 1 to about 15% by weight of said evaporation inhibitor composition is present in said aqueous spray mixture.

18. An evaporation inhibitor composition consisting of:

A. from about 15 to about 50% by weight of a wax mixture containing at least about 5% by weight, based on the wax mixture, of a wax component having an acid number of from about 10 to about 95 mg KOH/g wax;

said wax mixture being selected from one of the following;

a. from about 60 to about 95% by weight of paraffin wax and/or microcrystalline paraffin wax having a setting point of from about 40°

to about 70°

C., and from about 5 to about 40% by weight of oxidized polyethylene wax having a dropping point of from about 95°

to about 140°

C. and an acid number of from about 10 to about 95 mg KOH/g wax;

b. from about 60 to about 95% by weight of paraffin wax and/or microcrystalline paraffin wax having a setting point of from about 40°

to about 70°

C., and from about 5 to about 40% dropping point of from about 75°

to about 100°

C. and an acid number of from about 10 to about 95 mg KOH/g wax; and

c. from about 20 to about 50% by weight of paraffin wax having a setting point of from about 30°

to about 50°

C., and from about 50 to about 80% by weight of oxidized paraffin wax having a setting point of from about 60°

to about 90°

C. and an acid number of from about 10 to about 95 mg KOH/g wax;

B. an emulsifier which is

a. from about 40 to about 20% by weight of at least one nonionic emulsifier, and

b. from 0 to about 10% by weight of at least one anionic emulsifier, wherein the nonionic emulsifier makes up at least 50% by weight of component B;

said anionic emulsifier in component B is at least one of a salt of a sulfuric acid semiester, a phosphoric acid partial ester of a linear alcohol or an alkylphenol containing from 12 to 18 carbon atoms or a polyglycol monoalkylether containing from 12 to 18 carbon atoms in the alkyl group, an olefin sulfonate, and ester sulfonate, or an alkane sulfonate wherein such sulfonates contain from 12 to 20 carbon atoms, an alkylbenzene sulfonate containing from 6 to 16 carbon atoms in the alkyl groups, a sulfonate of a polyglycol monoalkylether, and a salt of a polyglycol monoalkylether carboxylic acid containing from 12 to 18 carbon atoms in the alkyl chain, and

C. frmm about 19.5 to about 81% by weight of water and/or at least one organic solvent selected from the group consisting of hydrocarbons, esters, and ketones having a boiling point of from about 70°

to about 280°

C.

19. An evaporation inhibitor composition consisting of:

A. from about 15 to about 50% by weight of a wax mixture containing at least about 5% by weight, based on the wax mixture, of a wax component having an acid number of from about 10 to about 95 mg KOH/g wax;

said wax mixture being selected from one of the following;

a. from about 60 to about 95% by weight of paraffin wax and/or microcrystalline paraffin wax having a setting point of from about 40°

to about 70°

C., and from about 5 to about 40% by weight of oxidized polyethylene wax having a dropping point of from about 95°

to about 140°

C. and an acid number of from about 10 to about 95 mg KOH/g wax;

b. from about 60 to about 95% by weight of paraffin wax and/or microcrystalline paraffin wax having a setting point of from about 40°

to about 70°

C., and from about 5 to about 40% by weight of wax containing ester bonds and having a dropping point of from about 75°

to about 100°

C. and an acid number of from about 10 to about 95 mg KOH/g wax; and

c. from about 20 to about 50% by weight of paraffin wax having a setting point of from about 30°

to about 50°

C., and from about 50 to about 80% by weight of oxidized paraffin wax having a setting point of from about 60°

to about 90°

C. and an acid number of from about 10 to about 95 mg KOH/g wax;

B. from about 4 to about 20% by weight of at least one nonionic and/or anionic emulsifier;

wherein said nonionic emulsifier is a mixture of ethylene oxide adducts with C₁₂ -C₁₈ fatty alcohols or an alkylphenol having from about 10 to about 40% by weight of adducts containing from 1 to 4 moles of ethylene oxide, from about 25 to about 70% by weight of adducts containing from 4 to 10 moles of ethylene oxide, and from about 5 to about 35% by weight of adducts containing from 10 to 50 moles of ethylene oxide, and

C. from about 19.5 to about 81% by weight of water and/or at least one organic solvent selected from the group consisting of hydrocarbons, esters, and ketones having a boiling point of from about 70°

to about 280°

C.