Method for permanganate bleaching of fabric and garments

• US 4,795,476 A
• Filed: 01/27/1988
• Issued: 01/03/1989
• Est. Priority Date: 01/27/1988
• Status: Expired due to Term

• Current Assignee: General Chemical Corporation (Gentek Incorporated)
• Original Assignee: General Chemical Corporation (Gentek Incorporated)
• Inventors: Monopoli, Peter A., Bean, Samuel L., Dulik, Mark D.
• Primary Examiner(s): Lieberman, Paul
• Assistant Examiner(s): McNally, John F.
• Application Number:
  US07/149,217
• Time in Patent Office: 342 Days
• Field of Search: 8/107, 8/102, 8/111.1, 252/186.33, 252/186.2, 252/188.21, 252/188.22
• US Class Current: 8/107
• CPC Class Codes: D06L 4/30 using reducing agents
• CPC Class Codes: D06P 5/153 with oxidants
• CPC Class Codes: D06P 5/155 with reductants

Abstract

Permanganate based fabric bleaching processes, such as stone-washing processes, are substantially improved by utilizing a reducing composition comprising a metabisulfite and a sulfite in the washing step. The relative amounts of metabisulfite and sulfite in the reducing composition are selected so as to substantially eliminate the odor of sulfur dioxide during the washing step at the particular temperature selected. For washing temperatures of 100°-140 ° F. the preferred weight ratio of sodium metabisulfite to sodium sulfite is 7:3, which produces a reducing composition having a pH of 6.2 (in a 5% by weight solution). Such a composition not only allows operation at elevated temperatures without an odor of SO₂, it also allows a reduction in the washing time and in the amount of reducing composition used.

Claims

1. In a process for preparing bleached fabrics wherein the fabric is treated with a permanganate oxidizing agent which is subsequently reduced, the improvement comprising reducing the permanganate with a reducing composition comprising sodium metabisulfite and sodium sulfite in amounts wherein the metabisulfite and sulfite are present in a mole ratio of between about 0.6 and about 3.2 such that substantially no sulfur dioxide odor is detectable during the reduction step.

2. The improvement of claim 1, wherein the mole ratio is between about 1.1 and about 1.8.

3. The improvement of claim 1, wherein the reduction of permanganate is carried out at a temperature of 100°

-140°

F.

4. The improvement of claim 1, wherein a mixture of sodium metabisulfite and sodium sulfite is introduced during the reduction step.

5. The improvement of claim 1, wherein a mixture of a metabisulfite and a base is introduced during the reduction step such that the reducing composition is generated upon reaction with water.