Impact resistant blends of thermoplastic polyamides, functionalized polyolefins and functionalized elastomers

• US 4,795,782 A
• Filed: 09/25/1986
• Issued: 01/03/1989
• Est. Priority Date: 09/25/1986
• Status: Expired due to Term

• Current Assignee: Shell Oil Company (Shell Plc)
• Original Assignee: Shell Oil Company (Shell Plc)
• Inventors: Lutz, Robert G., Gelles, Richard, Gergen, William P.
• Primary Examiner(s): Bleutge, John C.
• Assistant Examiner(s): WOODWARD, ANA LUCRECIA
• Application Number:
  US06/911,555
• Time in Patent Office: 831 Days
• Field of Search: 525/92, 525/66
• US Class Current: 525/66
• CPC Class Codes: C08L 23/00 Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 23/02 not modified by chemical after-treatment
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/20 Macromolecular compounds having nitrogen in the main chain according to C08L75/00 - C08L79/00; Derivatives thereof
• CPC Class Codes: C08L 2666/24 Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
• CPC Class Codes: C08L 51/00 Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds for ABS polymers C08L55/02; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 51/06 grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
• CPC Class Codes: C08L 53/00 Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 77/00 Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 77/06 Polyamides derived from polyamines and polycarboxylic acids C08L77/10 takes precedence

Abstract

The present invention relates to an impact resistant polymeric composition comprising a polyamide, a functionalized polyolefin and a functionalized elastomer.

Claims

1. Impact resistant polymeric compositions comprising

(a) from 1 to 95 percent by weight of a polyamide having a number average molecular weight of at least 5000;

and

(b) from 1 to 95 percent by weight of a poly-α

-olefin to which has been grafted an unsaturated monocarboxylic or polycarboxylic acid compound or its derivative;

(c) from 1-50 percent by weight of a selectively hydrogenated block copolymer of conjugated dienes and vinyl aromatic hydrocarbons to which has been grafted an unsaturated monocarboxylic or polycarboxylic acid compound or its derivative.

2. Impact resistant polymeric compositions of claim 1 wherein the selectively hydrogenated block copolymer is of the formula B_n (AB)_o A_p where n=0 or 1, o=1 to 100, p=0 or 1 to which has been grafted an acid compound or its derivative wherein,

(1) each A is predominantly a polymerized monoalkenyl aromatic hydrocarbon block having an average molecular weight of about 2,000 to 115,000;

(2) each B prior to hydrogenation is predominantly a polymerized conjugated diene hydrocarbon block having an average molecular weight of about 20,000 to 450,000;

(3) the blocks A constituting 5-95 weight percent of the copolymer;

(4) the unsaturation of the block B is less than 10% of the original unsaturation.

3. The composition of claim 2 wherein the selectively hydrogenated block copolymer has at least 1 B mid block and at least two A end blocks wherein

the unsaturation of the A blocks is above 50% of the original unsaturation.

4. The composition of claim 2 wherein the block copolymer is a styrene-butadiene-styrene block copolymer.

5. The composition of claim 2 wherein prior to hydrogenation, the polymeric blocks A are polymer blocks of a monoalkenyl aromatic hydrocarbon.

6. The composition of claim 2 wherein the unsaturation of block B is reduced to less than 5% of its original value and the average unsaturation of the hydrogenated block copolymer is reduced to less than 20% of its original value.

7. The composition of claim 2 wherein A is a polymerized styrene block having an average molecular weight of between about 4,000 and 60,000.

8. The composition of claim 2 wherein B is a polymerized butadiene block having an average molecular weight of between about 35,000 and 150,000, 35%-50% of the condensed butadiene units having 1,2-configuration.

9. The composition according to claim 3 wherein an average of less than about 10% of the monoalkenyl aromatic hydrocarbon units are hydrogenated.

10. The composition according to claim 3 wherein an average of more than about 25% of the monoalkenyl aromatic hydrocarbon units are hydrogenated.

11. The composition of claim 1 wherein the acid compound is maleic acid.

12. The composition of claim 1 wherein the polyolefin is functionalized polypropylene.

13. The composition of claim 1 wherein the polyolefin is functionalized polybutylene.

14. The composition of claim 1 wherein the polyolefin is functionalized high density polyethylene.

15. The composition of claim 1 wherein the polyolefin is functionalized low density polyethylene.

16. The composition of claim 1 wherein the polyamide is present at between about 10 and about 70 percent by weight.

17. The composition of claim 1 wherein the polyamide is present at between about 15 and about 45 percent by weight.

18. The composition of claim 1 wherein the polyamide is nylon 6,6.

19. A composition of claim 1 wherein the polyamide resin is selected from the group consisting of polyhexamethylene adipamide, polyhexamethylene sebacamide, polycaprolactam, polyhexamethylene isophthalamide, polyhexamethylene tere-co-isophthalamide and mixtures and copolymers of the above.

20. The composition of claim 1 wherein the block copolymer is present at between about 15 and 35 percent by weight.

21. The composition of claim 1 wherein the block copolymer is present at between about 10 and 25 percent by weight.

22. The composition of claim 1 wherein the polyolefin is present between about 10 and 70 percent by weight.

23. The composition of claim 1 wherein the polyolefin is present between about 15 and 45 percent by weight.

24. The composition of claim 1, wherein the poly-α

-olefin is functionalized with from about 1 to about 10 percent by weight of the acid compound.

25. The composition of claim 24, wherein the block copolymer is functionalized with from about 0.2 to about 20 percent by weight of the acid compound.