Method for producing an at least partly amorphous alloy piece

• US 4,797,166 A
• Filed: 05/11/1987
• Issued: 01/10/1989
• Est. Priority Date: 05/29/1986
• Status: Expired due to Fees

• Current Assignee: Cendres-Metaux SA
• Original Assignee: Cendres-Metaux SA
• Inventors: Blatter, Andreas, Von Allmen, Martin
• Primary Examiner(s): Andrews, Melvyn J.
• Assistant Examiner(s): KASTLER, SCOTT R
• Application Number:
  US07/047,481
• Time in Patent Office: 610 Days
• Field of Search: 148/4, 148/403, 148/304, 148/13, 420/422
• US Class Current: 148/561
• CPC Class Codes: B22F 3/007 by diffusion starting from non-amorphous articles prepared by powder metallurgy
• CPC Class Codes: C22C 45/10 with molybdenum, tungsten, niobium, tantalum, titanium, or zirconium or Hf as the major constituent

Abstract

An alloy, e.g. a Cr-Ti alloy, is transformed to a metastable crystal modification, e.g., by heating in an electric arc and quenching in water. The metastable crystal modification is annealed at a temperature which is below the glass temperature, e.g. at 600° C. during 48 hours, causing it to vitrify completely.

The inventive method provided the production of large pieces of hard and non-porous amorphous alloy with thicknesses in the centimeter range.

Claims

1. A method for producing an at least partly amorphous alloy piece, comprising the steps of

preparing an alloy composition of at least two elements of appreciably different atomic radius,

at least one of said elements being elected from the group consisting of Si, Al, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Zr, Nb, Mo, Pd, Ag, Hf, Ta, W, Pt or Au,

the composition being chosen such that a high -temperature solution crystal or high-temperature compound crystal exists for said composition,

heating the composition to an elevated temperature with respect to the glass temperature, so that the composition becomes a high-temperature solution crystal or high-temperature compound crystal,

quenching the composition to a temperature below the glass temperature at such a cooling rate, that the high-temperature solution crystal or high-temperature compound crystal is preserved as a metastable crystal phase in at least a part of the composition,

annealing the composition under a vacuum or in an inert gas environment at an annealing temperature, which is below the glass temperature by a tolerance of at least a few degrees in order to vitrify the metastable crystal phase.

2. A method according to claim 1, wherein the composition is generated to a temperature below said annealing temperature and reheated to said annealing temperature.

3. A method according to claim 1, wherein the high-temperature solution crystal or high-temperature compound crystal has at temperatures below the glass temperature a lower free energy than the glass phase.