Method for the detection of noxious gases

• US 4,797,180 A
• Filed: 06/04/1987
• Issued: 01/10/1989
• Est. Priority Date: 07/29/1985
• Status: Expired due to Fees

• Current Assignee: Mine Safety Appliances Company (MSA Safety, Inc.)
• Original Assignee: Mine Safety Appliances Company (MSA Safety, Inc.)
• Inventors: Price, John F., Jolson, Joseph D., Schneider, Alan A., Auel, RaeAnn M., Stewart, David A.
• Primary Examiner(s): Tung, T.
• Application Number:
  US07/058,134
• Time in Patent Office: 586 Days
• Field of Search: 204/1 P, 204/1 K, 204/1 T, 204/412, 204/415, 204/432, 204/435
• US Class Current: 205/783
• CPC Class Codes: G01N 27/4045 for gases other than oxygen

Abstract

The present invention is for an electrochemical cell and method for quantitatively detecting noxious gas which comprises a first working electrode comprising a gas diffusion membrane having bonded thereto a catalytic portion electrochemically reactive with the noxious gas; a second working electrode having electrochemical activity with the oxidation/reduction products produced at the first working electrode; a counter electrode; a reference electrode; an electrolyte; means for containing said electrolyte and said electrodes; means for maintaining a fixed potential on said first working electrode relative to said reference electrode of from about 1.0 to 1.8 volts with respect to the potential of the reversible hydrogen couple of the electrolyte of the cell; and means for maintaining a fixed potential on said second working electrode relative to said reference electrode of from about 1.0 to 2.2 volts with respect to the potential of the reversible hydrogen couple of the electrolyte of the cell, the fixed potential on said working electrode being maintained at a voltage higher than the fixed potential being maintained on said first working electrode.

Claims

1. A method for quantitatively detecting a noxious gas in air in an electrochemical cell comprising a first working electrode, a second working electrode, a counter electrode and a reference electrode, said first working electrode comprising a gas diffusion membrane having bonded thereto a catalytic portion electrochemically reactive with the noxious gas and said second working electrode having electrochemical activity with oxidation/reduction products produced at the first working electrode;

an electrolyte in contact with the catalytic portion of the first working electrode and in contact with second working electrode, the counter electrode and the reference electrode; and

means for containing the electrolyte and said electrodes;

said method comprising;

(a) feeding an air sample containing the noxious gas to be detected to the first working electrode of said cell;

(b) maintaining the first working electrode by means of a potentiostat at a fixed potential relative to the reference electrode of from about 1.0 to 1.8 volts with respect to the potential of the reversible hydrogen couple in the electrolyte of said cell to oxidize the noxious gas;

(c) maintaining the second working electrode by means of a potentiostat at a fixed potential relative to the reference electrode of from above 1.0 to about 2.2 volts with respect to the potential of the reversible hydrogen couple in the electrolyte of said cell to further oxidize/reduce the oxidation/reduction products of the noxious gas to minimize the contamination of the electrolyte and the counter electrode, the fixed potential on said second working electrode being maintained at a voltage higher than the fixed potential being maintained on said first working electrode; and

(d) measuring the current flowing between said first working electrode and said counter electrode to quantitatively determine the amount of the noxious gas in said air, said measured current being a measure of the concentration of the noxious gas in said air sample being detected.

2. The method of claim 1 wherein the catalytic portion of the first working electrode is selected from the group consisting of palladium, platinum, iridium, ruthenium, rhodium, osmium and alloys and mixtures thereof with gold.

3. The method of claim 1 wherein the catalytic portion of the first working electrode is iridium black.

4. The method of claim 1 wherein the membrane of the first working electrode is a porous fluorocarbon material.

5. The method of claim 1 wherein the second working electrode is a gas diffusion membrane having bonded thereto a catalytic portion selected from the group consisting of palladium, platinum, iridium, ruthenium, rhodium, osmium and alloys and mixtures thereof with gold.

6. The method of claim 1 wherein the counter electrode is a gas diffusion membrane having bonded thereto a catalytic portion selected from the group consisting of palladium, platinum, iridium, gold, ruthenium, rhodium, osmium and alloys and mixtures thereof.

7. The method of claim 1 wherein the electrolyte is selected from the group consisting of aqueous electrolytes, non-aqueous electrolytes and solid electrolytes that remain stable and inert during operation of the cell.

8. The method of claim 7 wherein the electrolyte is an aqueous solution of sulfuric acid.

9. The method of claim 1 wherein the reference electrode is selected from the group consisting of a normal hydrogen electrode, a saturated calomel electrode, a silver/silver chloride electrode, a glass or pH electrode, a mercury/mercury sulfate electrode, and a quinhydrone electrode.

10. The method of claim 1 wherein the reference electrode is coated with an ionically conductive medium.

11. The method of claim 10 wherein the reference electrode is coated with an ionically conductive medium formed by intimately mixing an ionic salt with a plastic material.

12. The method of claim 1 wherein the reference electrode is a chloranil/graphite electrode coated with an intimate mixture of polycarbonate or synthetic rubber and sodium sulfate.

13. The method of claim 1 wherein the noxious gas is selected from the group consisting of ethylene oxide, ethylene glycol, acetaldehyde, acetone, ethanol, isopropanol, propylene oxide and other two to four carbon chain gases.

14. The method of claim 1 wherein the noxious gas is ethylene oxide.

15. The method of claim 1 wherein the counter and reference electrodes are a single electrode.