Ionic semiconductor materials and applications thereof

• US 4,797,190 A
• Filed: 10/06/1986
• Issued: 01/10/1989
• Est. Priority Date: 10/06/1986
• Status: Expired due to Term

• Current Assignee: T and G Corporation
• Original Assignee: T and G Corporation
• Inventors: Peck, Robert L.
• Primary Examiner(s): Niebling, John F.
• Assistant Examiner(s): GORGOS, KATHRYN L
• Application Number:
  US06/915,994
• Time in Patent Office: 827 Days
• Field of Search: 204/296, 204/290 R, 204/283, 429/33, 429/190, 429/192
• US Class Current: 204/296
• CPC Class Codes: G01N 27/40 Semi-permeable membranes or partitions
• CPC Class Codes: H01M 10/36 Accumulators not provided for in groups H01M10/05-H01M10/34
• CPC Class Codes: H01M 12/06 with one metallic and one gaseous electrode
• CPC Class Codes: H01M 4/02 Electrodes composed of, or comprising, active material
• CPC Class Codes: H01M 4/62 Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
• CPC Class Codes: H01M 50/414 Synthetic resins, e.g. thermoplastics or thermosetting resins
• CPC Class Codes: H01M 50/429 Natural polymers
• CPC Class Codes: H01M 50/489 Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
• CPC Class Codes: H01M 8/08 Fuel cells with aqueous electrolytes
• CPC Class Codes: H01M 8/188 by recharging of redox couples containing fluids; Redox flow type batteries
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

An ion transport membrane includes 10 to approximately 50 percent by weight of a hydrogel which is dispersed within an inert nonporous matrix material to form a composite wherein the quantity of water that can be absorbed by the composite does not substantially exceed the weight of the composite. The membranes may be used in electrochemical cells, for water purification, as solid polymeric electrolytes, in breathable waterproof coatings, and in numerous other applications for controlled moisture or ion transfer.

Claims

1. An ionic semiconductor having an ion transport rate which is temperature dependent, said semiconductor comprising an inert man-made polymeric matrix material and a hydrogel, the molecules of the hydrogel being substantially uniformly dispersed within said matrix material to form a composite structure wherein contact between hydrogel molecules is minimized by the matrix and the formation of channels is thereby limited, the composite allowing the transfer of ions and preventing the passage of un-ionized matter, the hydrogel comprising 10 to approximately 50% by weight of the dry composite, there being sufficient bonding between the hydrogel molecules and the matrix material to prevent substantial leach-out of hydrogel molecules from the composite.

2. The material of claim 1 wherein the current attributable to copper ion diffusion does not exceed 16% of the equilibrium current when the composite separates H₂ SO₄ and CuSO₄ electrolytes and a potential difference is established across the composite.

3. The material of claim 1 wherein the hydrogel is a synthetic material selected form the group consisting of polyethylene oxide, polyacrylic acid and polyacrylamide.

4. The material of claim 1 wherein the hydrogel is devised from natural materials selected from the group consisting of hydroxyethy cellulose, gelatin, pectin, cellulose and starch.

5. The material of claim 1 wherein the matrix is selected from the group consisting of polyvinylidene chloride, polyvinyl chloride, polyvinylidene fluoride, polyethylene, polypropylene, urethane, and phenol formaldehyde.

6. The material of claim 1 further comprising a coupling agent to facilitate the bonding between the hydrogel and the matrix.

7. The material of claim 6 wherein the coupling agent is selected from the group consisting of polyacrylic acid, phenolic resin, cellulosic titanate, carbon, lignin and silica.

8. The material of claim 5 wherein the hydrogel is a synthetic material selected from the group consisting of pclyethylene oxide, polyacrylic acid and polyacrylamide.

9. The material of claim 5 wherein the hydrogel is devised from natural materials selected from the group consisting of hydroxyethyl cellulose, gelatin, pectin, cellulose and starch.

10. The material of claim 8 further comprising a coupling agent to facilitate the bonding between the hydrogel and the matrix.

11. The material of claim 10 wherein the coupling agent is selected from the group consisting of polyacrylic acid, phenolic resin, cellulose titanate, carbon, lignin and silica.

12. The material of claim 9 further comprising a coupling agent to facilitate the bonding between the hydrogel and the matrix.

13. The material of claim 12 wherein the coupling agent is selected from the group consisting of polyacrylic acid, phenolic resin, cellulosic titanate, carbon, lignin and silica.

14. The material of claim 8 wherein the current attributable to copper ion diffusion does not exceed 16% of the equilibrium current when the composite separates H₂ SO₄ and CuSO₄ electrolytes and a potential difference is established across the composite.

15. The material of claim 9 wherein the current attributable to copper ion diffusion does not exceed 16% of the equilibrium current when the composite separates H₂ SO₄ and CuSO₄ and a potential difference is established across the composite.

16. The material of claim 1 wherein the hydrogel and the matrix material and their respective proportions in the composite are selected such that the quantity of water absorbed by the composite will be limited to less than the weight of the composite prior to water absorption.

17. The material of claim 3 wherein the hydrogel and the matrix material and their respective proportions in the composite are selected such that the quantity of water absorbed by the composite will be limited to less than the weight of the composite prior to water absorption.

18. The material of claim 5 wherein the hydrogel and the matrix material and their respective proportions in the composite are selected such that the quantity of water absorbed by the composite will be limited to less than the weight of the composite prior to water absorption.