Impact resistant blends of thermoplastic polyesters and modified block copolymers

• US 4,797,447 A
• Filed: 08/16/1985
• Issued: 01/10/1989
• Est. Priority Date: 08/16/1985
• Status: Expired due to Term

• Current Assignee: Shell Elastomers LLC (DL Holdings Co., Ltd.)
• Original Assignee: Shell Oil Company (Shell Plc)
• Inventors: Lutz, Robert G., Gergen, William P.
• Primary Examiner(s): Briggs, Sr., Wilbert J.
• Application Number:
  US06/766,216
• Time in Patent Office: 1,243 Days
• Field of Search: 525/92, 525/366, 525/250, 525/271, 525/314
• US Class Current: 525/64
• CPC Class Codes: C08F 287/00 Macromolecular compounds obtained by polymerising monomers on to block polymers
• CPC Class Codes: C08F 8/04 Reduction, e.g. hydrogenation
• CPC Class Codes: C08L 2666/14 Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
• CPC Class Codes: C08L 53/025 modified

Abstract

The present invention relates to an impact resistant polymeric composition comprising a polyester and a thermally stable modified selectively hydrogenated high 1,2 content block copolymer wherein at least one graftable functional molecule is grafted to the block copolymer in the vinylarene block.

Claims

1. Impact resistant polymeric composition comprising:

(a) from 50 to 97 percent by weight of a thermoplastic polyester; and

(b) from 3 to 50 percent by weight of a functionalized selectively hydrogenated block copolymer of the formula B_n (AB)_o A_p where n=0 or 1, o≧

1, p=0 or 1, each A is predominantly a polymerized vinyl aromatic hydrocarbon block and, each B prior to hydrogenation is predominantly a polymerized conjugated diene hydrocarbon block, to which has been grafted at least one graftable functional molecule selected from the group consisting of an electrophilic graftable molecule containing a functional group and an electrophile, wherein substantially all of said electrophilic graftable molecules or electrophiles are grafted to the block copolymer in the vinyl aromatic hydrocarbon block.

2. The composition of claim 1 containing said block copolymer wherein:

(1) each A is predominantly a polymerized vinyl aromatic hydrocarbon block having an average molecular weight of about 500 to 115,000;

(2) each B prior to hydrogenation is predominantly a polymerized conjugated diene hydrocarbon block having an average molecular weight of about 20,000 to 450,000;

(3) the blocks A constituting 1-95 weight percent of the copolymer;

(4) the unsaturation of the block B is less than 10% of the original unsaturation; and

(5) the unsaturation of the A blocks is above 50% of the original unsaturation.

3. The composition of claim 1 wherein the block copolymer is a styrene-ethylene/butylene-styrene block copolymer.

4. The composition of claim 1 wherein the blocks A comprise 1-40 percent by weight of the copolymer, the unsaturation of block B is reduced to less than 5% of its original value and the average unsaturation of the hydrogenated block copolymer is reduced to less than 20% of its original value.

5. The composition of claim 4 wherein A is a polymerized styrene block having an average molecular weight of between about 500 and 60,000

6. The composition of claim 1 wherein B is a polymerized butadiene block having an average molecular weight of between about 35,000 and 150,000, 35%-50% of the condensed butadiene units having 1,2-configuration.

7. The composition of claim 6 wherein the unsaturation of block B has been reduced by hydrogenation to less than 10% of its original value.

8. The composition of claim 1 wherein an average of less than about 10% of the vinyl aromatic hydrocarbon units are hydrogenated.

9. The composition of claim 1 wherein an average of more than about 25% of the vinyl aromatic hydrocarbon units are hydrogenated.

10. The composition of claim 1 wherein said graftable functional molecule is an electrophile and said electrophile is carbon dioxide.

11. The composition of claim 1 wherein said graftable functional molecule is an electrophile and said electrophile is ethylene oxide.

12. The composition of claim 1 wherein said graftable functional molecule is an electrophile and said electrophile is selected from the group consisting of aldehydes, ketones and acid salts and esters.

13. The composition of claim 1 wherein said graftable functional molecule is an electrophile and said electrophile is an epoxide.

14. The composition of claim 1 wherein said graftable functional molecule is an electrophile and said electrophile is sulphur.

15. The composition of claim 1 wherein said graftable functional molecule is an electrophile and said electrophile is a boron alkoxide.

16. The composition of claim 1 wherein said graftable functional molecule is an electrophile and said electrophile is an isocyanate.

17. The composition of claim 1 wherein said graftable functional molecule is an electrophile and said electrophile is a molecule containing silicon.

18. The composition of claim 1 wherein said graftable functional molecule is an electrophile and said electrophile is a sulfonate.

19. The composition of claim 1 wherein the functional groups are carboxylic acids, their salts and esters.

20. The composition of claim 1 wherein the functional groups are ketones.

21. The composition of claim 1 wherein the functional groups are alcohols and alkoxides.

22. The composition of claim 1 wherein the functional groups are amines.

23. The composition of claim 1 wherein the functional groups are functional groups containing a silicon atom.

24. The composition of claim 1 wherein the functional groups are thiols.

25. The composition of claim 1 wherein the functional groups are borates.

26. The composition of claim 1 wherein the functional groups are amides.

27. The composition of claim 1 wherein the grafted molecule or its derivative is present in the functionalized block copolymer at between about 0.02-20 weight percent.

28. The composition of claim 1 wherein the grafted molecule or its derivative is present in the functionalized block copolymer at between about 0.1-10 weight percent.

29. The composition of claim 1 wherein the grafted molecule or its derivative is present in the functionalized block copolymer at between about 0.2-5 weight percent.

30. The composition of claim 1 wherein the polyester is present at between about 70 and about 95 percent by weight.

31. The composition of claim 1 wherein the polyester is present at between about 75 and about 90 percent by weight.

32. The composition of claim 1 wherein the polyester is polybutylene terephthalate.

33. The composition of claim 1 wherein the polyester is polyethylene terephthalate.

34. The composition of claim 1 wherein the polyester is present at between 60 and 90 percent by weight and the block copolymer is present at between 10 and 40 percent by weight.