Method of manufacturing an electrochemical device

• US 4,798,693 A
• Filed: 08/03/1987
• Issued: 01/17/1989
• Est. Priority Date: 04/26/1984
• Status: Expired due to Term

• Current Assignee: NGK Insulators Limited
• Original Assignee: NGK Insulators Limited
• Inventors: Mase, Syunzo, Soejima, Shigeo
• Primary Examiner(s): Tung, T.
• Application Number:
  US07/081,631
• Time in Patent Office: 533 Days
• Field of Search: 204/1 S, 204/421-429, 264/61, 264/44, 65/59.22
• US Class Current: 264/44
• CPC Class Codes: G01N 27/4071 using sensor elements of laminated structure
• CPC Class Codes: G01N 27/417 using cells , i.e. more than one cell and probes with solid electrolytes

Abstract

A method of manufacturing an electrochemical device having an electrochemical cell including a planar solid electrolyte body and at least two electrodes disposed in contact with the solid electrolyte body. The method comprising: forming a first unfired ceramic layer on one side of an unfired structure of the electrochemical cell, the first unfired ceramic layer being given a porous structure by firing thereof; forming a second unfired ceramic layer on the other side of the unfired structure of the electrochemical cell, the second unfired ceramic layer having substantially the same property of firing shrinkage as the first unfired ceramic layer; and co-firing the unfired structure of the electrochemical cell, the first and second unfired ceramic layers. The two unfired ceramic layers may be formed on opposite sides of an unfired structure of an electrochemical cell assembly which includes plural cells, for example, an oxygen pumping cell and an oxygen sensing cell. In this case, another unfired ceramic layer may be formed between the unfired structures of the two cells. The electrochemical device manufactured by the method does not have a unfavorable warpage that would arise due to difference in firing shrinkage between the layers.

Claims

1. A method of manufacturing an electrochemical device which has a planar electrochemical cell structure including a planar solid electrolyte body and at least two electrodes disposed in contact with the solid electrolyte body, the device also including a heating element, comprising the steps of:

forming a first unfired ceramic layer on a first side of an unfired electrochemical cell structure, said first unfired ceramic layer being given a porous structure by firing thereof;

forming a second unfired ceramic layer on a second side of said unfired electrochemical cell structure, such that said second unfired ceramic layer does not contact either of said at least two electrodes, said second unfired ceramic layer being made of an electrically insulating material and being given a porous structure by firing thereof, said second unfired ceramic layer cooperating with said first unfired ceramic layer to prevent warpage of the planar electrochemical cell during co-firing of the unfired structure and unfired layers of the electrochemical cell;

forming an unfired heater layer for the heating element, said unfired heater layer being embedded in said second unfired ceramic layer;

forming a gas-tight unfired ceramic layer on one of the opposite sides of the second unfired ceramic layer which is remote from said first unfired ceramic layer, said gas-tight layer protecting the heater layer from exposure to a gas to be analyzed using said device; and

co-firing said unfired electrochemical cell structure, said first unfired ceramic layer, said second unfired ceramic layer, said unfired heater layer, and said gas-tight unfired ceramic layer to form said electrochemical device.

2. A method as set forth in claim 1, wherein said first unfired ceramic layer is fired into a porous structure having a porosity within a range of 5-30%.

3. A method as set forth in claim 1, wherein the porous structure obtained by firing of said second unfired ceramic layer has a porosity within a range of 5-30%.

4. A method as set forth in claim 1, wherein said electrochemical cell structure includes a pumping cell and a sensing cell, said first unfired ceramic layer being formed so as to cover one side of an unfired structure of said pumping cell, said second unfired ceramic layer being formed so as to cover one side of an unfired structure of said sensing cell remote from the unfired structure of said pumping cell.

5. A method as set forth in claim 4, further comprising a step of forming a third unfired ceramic layer between said unfired structures of the pumping and sensing cells.

6. A method of manufacturing an electrochemical device which has a planar electrochemical cell structure including a planar solid electrolyte body and at least two electrodes disposed in contact with the solid electrolyte body, the device also including a heating element, comprising the steps of:

forming a first unfired ceramic layer on one side of an unfired electrochemical cell structure, said first unfired ceramic layer being given a porous structure by firing thereof;

forming a second unfired ceramic layer on the other side of said unfired electrochemical cell structure, such that said second unfired ceramic layer does not contact either of said at least two electrodes, said second unfired ceramic layer being made of an electrically insulating material and being given a porous structure by firing thereof;

forming an unfired heater layer for the heating element, said unfired heater layer being embedded in said second unfired ceramic layer;

forming a gas-tight unfired ceramic layer on one of the opposite sides of the second unfired ceramic layer which is remote from said first unfired ceramic layer, said gas-tight layer protecting the heater layer from exposure to a gas to be analyzed using said device; and

co-firing said unfired electrochemical cell structure, said first unfired ceramic layer, said second unfired ceramic layer, said unfired heater layer, and said gas-tight unfired ceramic layer to form said electrochemical device.

7. A method as set forth in claim 6, wherein said first unfired ceramic layer is fired into a porous structure having a porosity within a range of 5-30%.

8. A method as set forth in claim 6, wherein the porous structure obtained by firing of said second unfired ceramic layer has a porosity within a range of 5-30%.

9. A method as set forth in claim 6, wherein said electrochemical cell structure includes a pumping cell and a sensing cell, said first unfired ceramic layer being formed so as to cover one side of an unfired structure of said pumping cell, said second unfired ceramic layer being formed so as to cover one side of an unfired structure of said sensing cell remote from the unfired structure of said pumping cell.

10. A method as set forth in claim 9, further comprising a step of forming a third unfired ceramic layer between said unfired structures of the pumping and sensing cells .