Method for treating liquid used for absorbing gaseous sulfur dioxide in the process for desulfurization of combustion exhaust gas

• US 4,802,966 A
• Filed: 04/16/1987
• Issued: 02/07/1989
• Est. Priority Date: 04/17/1986
• Status: Expired due to Fees

• Current Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
• Original Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
• Inventors: Kudo, Yoshihiko, Aoki, Haruo
• Primary Examiner(s): CINTINS, IVARS C
• Application Number:
  US07/039,478
• Time in Patent Office: 663 Days
• Field of Search: 204/182.4, 210/638, 210/651, 210/685, 210/243, 423/242 A
• US Class Current: 204/526
• CPC Class Codes: A62D 3/00 Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances consuming noxious gases by combustion F23G7/06
• CPC Class Codes: B01D 53/501 by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
• CPC Class Codes: B01D 61/44 Ion-selective electrodialysis
• CPC Class Codes: C01F 11/46 Sulfates dehydration of gypsum for the production of calcium sulfate cements C04B11/02
• CPC Class Codes: C01F 5/30 Chlorides

Abstract

Disclosed herein is a method for treating a liquid used for absorbing gaseous sulfur dioxide in the wet process for desulfurization of a combustion exhaust gas of the gypsum-by-producing type, which method comprises the steps of, after subjecting a liquid, which has been saturated with gypsum, has dissolved at least magnesium sulfate and magnesium chloride and is used as the above-mentioned liquid for absorbing gaseous sulfur dioxide, to clarifying treatment, passing the liquid saturated with gypsum through an electrodialyzer having three dialyzing chambers comprising one sheet of cation-exchange membrane and two sheets of membrane selectively permeable to monovalent anions as one unit, thereby selectively separating and removing the chloride ion in the above-mentioned liquid as an aqueous solution of magnesium chloride of a high concentration.

Claims

1. A method for treating a liquid used for absorbing gaseous sulfur dioxide in the wet process for desulfurization of a combustion exhaust gas of the gypsum-by-producing type so as to remove chloride ions from said liquid wherein said liquid has been saturated with gypsum, has dissolved at least magneisium sulfate and magneisium chloride and has been used for absorbing gaseous sulfur dioxide, the method comprising the steps of conducting a clarification treatment and afterward passing said liquid through an electrodialyzer having three dialyzing chambers which comprise one sheet of cation-exchange membrane and two sheets of membrane selectively permeable to monovalent anions as one unit, and thereby selectively separating and removing chloride ions fom said liquid as an aqueous solution of magnesium chloride of a high concentration.

2. A method according to claim 1, wherein each unit of said three dialyzing chambers comprises (1) an intermediate chamber located between said two sheets of membrane (A₁ and A₂) selectively permeable to monovalent anions, (2) a concentrating chamber located between said membrane (A₂) selectively permeable to monovalent anions and said cation-exchange membrane and (3) a desalting chamber located beween said cation-exchange membrane and a sheet of membran (A₁) selectively permeable to monovalent anions of the neighboring unit of three dialyzing chambers, said method comprising the steps of passing said liquid, which has been saturated with gypsum and has been clarified, through said desalting chamber, thereby desalting said liquid and at the same time, removing an aqueous solution of magneisium chloride of a high concentration, which is formed in said concentrating chamber, therefrom.

3. A method according to claim 2, wherein said intermediate chamber is supplied with an aqueous solution containing chloride ions, thereby retaining the concentration of sulfate ions (equivalent/liter) so as to be not over the concentration of chloride ions (equivalent/liter) in said intermediate chamber.

4. A method according to claim 3, wherein said supply aqueous solution is a liquid which has been prepared by diluting the concentrated liquid of magnesium chloride discharged from said concentrating chamber with water.

5. A method according to claim 4, wherein from 3 to 8% by weight of said concentrated liquid of magnesium chloride discharged from said concentrating chamber is used for said supply aqueous solution.

6. A method according to claim 2, wherein the liquid which has been subjected to desalting treatment in said desalting chamber is recycled to the system of said process for desulfurization.

7. A method according to claim 2, wherein a liquid discharged from said intermediate chamber is introduced into said desalting chamber.

8. A method according to claim 1, wherein said liquid saturated with gypsum contains a magnesium salt of a carboxylic acid.

9. A method according to claim 8, wherein said carboxylic acid is sulfosuccinic acid or adipic acid.