Electrically conductive textile materials and method for making same

• US 4,803,096 A
• Filed: 08/03/1987
• Issued: 02/07/1989
• Est. Priority Date: 08/03/1987
• Status: Expired due to Term

• Current Assignee: Milliken & Company
• Original Assignee: Milliken Research Corporation
• Inventors: Kimbrell, William C. Jr., Kuhn, Hans H.
• Primary Examiner(s): Morganstern, Norman
• Assistant Examiner(s): Padgett, Marianne L.
• Application Number:
  US07/081,069
• Time in Patent Office: 554 Days
• Field of Search: 427/121, 252/500
• US Class Current: 427/121
• CPC Class Codes: D06M 11/28 Halides of elements of Groups 8, 9, 10 or 18 of the Periodic Table
• CPC Class Codes: D06M 11/50 with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
• CPC Class Codes: D06M 15/37 Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: D06M 15/687 containing atoms other than phosphorus, silicon, sulfur, nitrogen, oxygen or carbon in the main chain
• CPC Class Codes: H01B 1/127 comprising five-membered aromatic rings in the main chain, e.g. polypyrroles, polythiophenes
• CPC Class Codes: H01B 1/128 comprising six-membered aromatic rings in the main chain, e.g. polyanilines, polyphenylenes

Abstract

Fabrics are made electrically conductive by contacting the fabric under agitation conditions with an aqueous solution of a pyrrole or aniline compound, and an oxidizing agent and a doping agent or counter ion; and then epitaxially depositing onto the surface of the individual fibers of said fabric the in status nascendi forming polymer of the pyrrole or aniline compound so as to uniformly and coherently cover the fibers with an ordered conductive film of the polymerized pyrrole or aniline compound. Individual fibers and yarns can be similarly treated and then formed into fabrics. Products made by the process are also described.

Claims

1. A method for imparting electrical conductivity to a textile material, which comprises contacting the textile material with an aqueous solution of an oxidatively polymerizable compound, selected from a pyrrole compound and an aniline compound, and an oxidizing agent capable of oxidizing said compound to a polymer, said contacting being carried out in the presence of a counter ion which imparts electrical conductivity to said polymer when fully formed, said contacting being under conditions at which the compound and the oxidizing agent react with each other to form a prepolymer in said aqueous solution before either the compound or the oxidizing agent are adsorbed by, or deposited on or in, the textile material, but without forming a conductive polymer, per se, in said aqueous solution;

adsorbing onto the surface of said textile material the prepolymer and allowing the adsorbed prepolymer to polymerize while adsorbed on said textile material so as to uniformly and coherently cover the textile material with a conductive film of said polymer.

2. The method of claim 1 wherein said oxidatively polymerizable compound is pyrrole which is present in said solution in an amount from 0.01 to 5 grams per liter.

3. The method of claim 1 wherein said oxidatively polymerizable compound is aniline which is present in said solution in an amount from 0.02 to 10 grams per liter.

4. The method of claim 1 wherein said textile material comprises a knitted, woven, or non-woven fibrous textile fabric.

5. The method of claim 4 wherein the fibers of said fabric are uniformly and coherently covered with said conductive film to a thickness of from about 0.05 to about 2 microns.

6. The process of claim 5 wherein said textile fabric is selected from woven or knitted fabrics.

7. The process of claim 6 wherein said textile fabric is constructed of continuous filament yarns.

8. The process of claim 7 wherein said textile fabric comprises synthetic fibers selected from the group consisting of polyester, nylon and acrylic fibers.

9. The process of claim 7 wherein said textile fabric comprises high modulus fibers selected from aromatic polyester, aromatic polyamide and polybenzimidazole fibers.

10. The process of claim 7 wherein said textile material comprises high modulus inorganic fibers selected from glass and ceramic fibers.

11. The process of claim 4 wherein said treated textile fabric has a resistivity from about 50 to about 500,000 ohms per square.

12. The process of claim 1 wherein said textile material is or is comprised of basic dyeable polyester fibers.

13. The process of claim 1 wherein said textile material comprises a wound yarn, filament or fiber.

14. The process of claim 2 wherein said pyrrole compound is a pyrrole monomer selected from the group consisting of pyrrole, a 3- and 3,4-alkyl or aryl substituted pyrrole, N-alkyl pyrrole and N-aryl pyrrole.

15. The process of claim 1 wherein said pyrrole compound is pyrrole, N-methylpyrrole or a mixture of pyrrole and N-methylpyrrole.

16. A process of claim 3 where the aniline compound is a chloro-, bromo-, alkyl- or aryl-substituted aniline.

17. The process of claim 1 wherein said oxidant is Fe₊₃.

18. The process of claim 1 wherein said oxidant is a peroxide, persulfate, perborate, permanganate, peracid or chromate.

19. The process of claim 18 wherein said oxidant is persulfate.

20. The process of claim 19 wherein said counter ion is an anionic counter ion selected from the group consisting of chloride, perchlorate, sulfate, bisulfate, sulfonate, sulfonic acid, fluoroborate, PF₆ -, A₅ F₆ - and SbF₆ -.

21. The process of claim 19 wherein said counter ion is derived from a benzenesulfonic acid or a naphthalenesulfonic acid or a water-soluble salt thereof.

22. An electrically conductive textile material which is the product of the process of claim 1, having a resistivity in the range of from about 50 to about 10⁶ ohms per square.

23. The electrically conductive material of claim 22 which is a fabric comprised of fibers, filaments or yarns of polyester or polyamide.

24. The electrically conductive material of claim 22 wherein the pyrrole compound is pyrrole and the polypyrrole film has a thickness of less than about 1 micron.