Multiple layer packaging films and packages formed therefrom

• US 4,803,102 A
• Filed: 10/27/1987
• Issued: 02/07/1989
• Est. Priority Date: 11/29/1985
• Status: Expired due to Term

• Current Assignee: Pechiney Plastic Packaging Incorporated (Rio Tinto Limited)
• Original Assignee: American National Can Company (Ball Corporation), Kendall Mcgraw Laboratories Incorporated
• Inventors: Smith, Steven L., Gehrke, Russell P., Johnson, Richard E. Jr., Raniere, Jean E.
• Primary Examiner(s): Buffalow, Edith
• Application Number:
  US07/113,415
• Time in Patent Office: 469 Days
• Field of Search: 428/412, 428/476.3, 428/467.1, 428/349, 428/35, 428/500, 428/483
• US Class Current: 428/35.2
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: C08L 2666/24 Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
• CPC Class Codes: C09J 123/10 Homopolymers or copolymers of propene
• CPC Class Codes: Y10T 428/1334 Nonself-supporting tubular film or bag [e.g., pouch, envelope, packet, etc.]
• CPC Class Codes: Y10T 428/2826 Synthetic resin or polymer
• CPC Class Codes: Y10T 428/31507 Of polycarbonate
• CPC Class Codes: Y10T 428/31746 Polymer of monoethylenically unsaturated hydrocarbon
• CPC Class Codes: Y10T 428/3175 Next to addition polymer from unsaturated monomer[s]
• CPC Class Codes: Y10T 428/31797 Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31855 Of addition polymer from unsaturated monomers

Abstract

The invention discloses a multiple layer film useful in packaging, and the packages made therefrom. A first layer of the film is a material containing an ester group, a polycarbonate or a polyether block amide copolymer. A second layer of the film is a sealant, preferably polypropylene polymer blended with an elastomeric styrene ethylene butylene styrene copolymer. A third functionally adhesive layer is between the first and second layers. The composition of the third adhesive layer is typically either a polypropylene modified with a carboxy group such as an organic acid or anhydride or a styrene ethylene butylene styrene copolymer.

Claims

1. A multiple layer film, comprising:

(a) a first layer, the composition of said first layer being selected form the group consisting of polyesters, copolyesters, polycarbonates, and polyether block amide copolymers;

(b) a second sealant layer, the composition of said second layer comprising a composition of polypropylene polymer and a styrene ethylene butylene styrene copolymer; and

(c) a third adhesive layer adhering said first layer to said second layer with good adhesion, said third layer being positioned between said first and second layers, the composition of said third adhesive layer being styrene ethylene butylene styrene copolymer.

2. A multiple layer film as in claim 1 wherein said first layer is a polyester or copolyester polymer.

3. A multiple layer film as in claim 1 wherein said first layer is a polyether block amide copolymer.

4. A multiple layer film as in claim 1 wherein said first layer is a glycol modified cyclohexanedimethanolcyclohexanendicarboxylate.

5. A multiple layer film as in claim 1 wherein the composition of said second sealant layer comprises a blend of about 40% by weight to about 90% by weight of said polypropylene and about 60% by weight to about 10% by weight of said styrene ethylene butylene styrene copolymer.

6. A package made from a multiple layer film of claim 1.

7. A package made from a multiple layer film of claim 2.

8. A package made from a multiple layer film of claim 3.

9. A package made from a multiple layer film of claim 4.

10. A package made from a multiple layer film of claim 4.

11. A package as in claim 6, said package having been subjected to processing conditions of about 250°

F. for a period of at least about 10 minutes.

12. A package as in claim 7, said package having been subjected to processing conditions of about 250°

F. for a period of at least about 10 minutes.

13. A package as in claim 8, said package having been subjected to processing conditions of about 250°

F. for a period of at least about 10 minutes.

14. A package as in claim 9, said package having been subjected to processing conditions of about 250°

F. for a period of at least about 10 minutes.

15. A package as in claim 10, said package having been subjected to processing conditions of about 250°

F. for a period of at least about 10 minutes.

16. The package as in any one of claims 6, 7, 10, 11, and 12, 15 wherein said package is adapted to contain medical products including liquids and powders.

17. A multiple layer film as in any one of claims 1 or 2, 5, said third adhesive layer being in surface-to-surface contact with said first and second layers.

18. A package made from a multiple layer film of claim 17.

19. A package as in claim 18, said package having been subjected to processing conditions of about 250°

F. for a period of at least about 10 minutes.

20. A package as in claim 19 wherein said package is adapted to contain medical products including liquids and powders.