Method and apparatus for determining phase transition temperature using laser attenuation

• US 4,804,274 A
• Filed: 12/30/1986
• Issued: 02/14/1989
• Est. Priority Date: 12/30/1986
• Status: Expired due to Fees

• Current Assignee: Mobil Oil Corporation (Exxon Mobil Corporation)
• Original Assignee: Mobil Oil Corporation (Exxon Mobil Corporation)
• Inventors: Green, Gary J.
• Primary Examiner(s): Cuchlinski, Jr., William A.
• Assistant Examiner(s): Will, Thomas B.
• Application Number:
  US06/947,927
• Time in Patent Office: 777 Days
• Field of Search: 374/16, 374/17, 374/25, 356/436, 250/573
• US Class Current: 374/17
• CPC Class Codes: G01N 25/04 of melting point; of freezing point; of softening point
• CPC Class Codes: G01N 33/2811 by measuring cloud point or pour point of oils

Abstract

Disclosed are methods and apparatus for determining phase transition temperatures and, more particularly, for determining cloud, fluidity, freezing, and haze points of hydrocarbon fuels and hydrocarbon/oxygenate fuel blends. The attenuation of laser light as it passes through the sample, then through a laser line filter, and then into a photodetector is used to determine the transition temperature.

Claims

1. An apparatus operable in a plurality of ambient lighting conditions for determining the phase transition temperature of a liquid hydrocarbon fuel sample, said apparatus comprising:

(a) a container for holding the sample and for providing an optical pathway therethrough;

(b) a light source for projecting a highly parallel beam of monochromatic light along said optical pathway, said light having a wavelength in the visible spectrum;

(c) means for detecting the intensity of said light exiting said optical pathway, including a detecting cell and means for allowing the passage of substantially only that light having a wavelength substantially equal to the wavelength of light from said light source; and

(d) means for measuring the temperature of said sample as said sample passes through said transition temperature.

2. The apparatus of claim 1 further comprising means for recording the intensity of said detected light and said measured temperature.

3. The apparatus of claim 2 wherein said detecting cell comprises a photodiode and said recording means comprises a strip chart recorder connected to said photodiode and said temperature measuring means.

4. The apparatus of claim 1 wherein said light beam is a laser beam and said allowing means comprises a laser line filter.

5. The apparatus of claim 4 wherein said projecting light source is a helium-neon laser.

6. The apparatus of claim 1 further comprising means for maintaining a substantially uniform sample temperature.

7. The apparatus of claim 6 wherein said temperature measuring means comprises a thermocouple and said maintaining means comprises a jacketed sample holder equipped with a magnet stirring means.

8. The apparatus of claim 7 further comprising means for controlling the temperature of said sample to pass through said transition temperature.

9. The apparatus of claim 8 wherein said light intensity detecting means and said temperature measuring means produce signals representative of said light and said temperature.

10. The apparatus of claim 9 further comprising means for generating data pairs representative of said signals.

11. The apparatus of claim 10 wherein said means for generating data pairs comprises a dual-pen strip chart recorder.

12. The apparatus of claim 10 wherein said generating means comprises an electronic circuit means.

13. The apparatus of claim 10 further comprising means for analyzing said data pairs to determine said transition temperature.

14. The apparatus of claim 13 wherein said analyzing means comprises a microprocessor.

15. The apparatus of claim 1 further comprising means for controlling the temperature of said sample to pass through said transition temperature.

16. A method for determining the phase transition temperature of a liquid hydrocarbon sample comprising simultaneously:

(a) projecting a highly parallel beam of monochromatic visible light from a light source along an optical pathway in said liquid hydrocarbon sample;

(b) measuring the temperature of the liquid hydrocarbon sample;

(c) controlling the temperature of said liquid hydrocarbon sample to pass through the phase transition temperature of said sample;

(d) substantially only that light having a wavelength substantially equal to the light from said source to exit said pathway;

(e) detecting the intensity of the light exiting said optical pathway; and

(f) analyzing the intensity of said detected light to determine the temperature at which the phase transition of the liquid hydrocarbon occurs.

17. The method of claim 16 further comprising the step of recording the intensity of said detected light.

18. The method of claim 16 wherein said projecting step comprises projecting a laser beam.

19. The method of claim 18 wherein said allowing step comprises interposing a laser line filter between said light source and said detecting means.

20. The method of claim 18 wherein said laser beam is generated by a helium-neon laser.

21. The method of claim 16 wherein said allowing step comprises filtering the light exiting said optical pathway.

22. The method of claim 16 further comprising the step of maintaining a uniform sample temperature.

23. The method of claim 22 wherein said maintaining step comprises magnetically stirring said sample in a jacketed sampled holder.

24. The method of claim 16 wherein said phase transition is selected from the group consisting of cloud point, fluidity point, freeze point, haze point, or water tolerance.