Metallization of support members

• US 4,804,430 A
• Filed: 05/21/1984
• Issued: 02/14/1989
• Est. Priority Date: 05/21/1984
• Status: Expired due to Term

• Current Assignee: Vacumet Corp. (Nissha Co., Ltd.)
• Original Assignee: Dennison Manufacturing Company (Avery Dennison Corporation)
• Inventors: McDermott, John F., Clough, Philip J., Hubbard, Roswell E., Miekka, Richard G.
• Primary Examiner(s): HOAG, WILLARD
• Application Number:
  US06/612,167
• Time in Patent Office: 1,730 Days
• Field of Search: 156/233, 156/289, 428/914
• US Class Current: 156/233
• CPC Class Codes: B44C 1/14 Metallic leaves or foils, e.g. gold leaf
• CPC Class Codes: C23C 14/20 on organic substrates
• CPC Class Codes: D21H 19/04 applied as foil
• CPC Class Codes: D21H 27/30 Multi-ply for surface covering D21H27/18; making on paper-making machines D21F9/00, D21F11/00
• CPC Class Codes: H05K 3/025 by transfer of thin metal foil formed on a temporary carrier, e.g. peel-apart copper

Abstract

Method and apparatus for the metallization of support members, such as paper sheeting and other cellulosic products. A metallic film is transferred to a preheated paper support from a plastic sheet carrier and adhered to the paper by a thermoplastic material. The carrier is typically of stabilized plastic with a releasably adhered film of metal. Separate metallic films may be transferred simultaneously from opposite sides of a preheated plastic sheet carrier to separate, preheated paper supports. Pressure is applied to the composite which is cooled, desirably by chilling, and the carrier stripped away to leave the desired metallic layer on the receiving surface of the paper support.

This transfer procedure overcomes the objections associated with metal foil laminates and is particularly suitable for metallizing support members, like paper, which are difficult to metallize directly because they release significant amounts of vapor during conventional vacuum metallization. The results are also superior to what is realized using an adhesive with dispersed metal particles, and the need for curing the adhesive is eliminated.

Claims

1. The method of metallizing a support member which comprises:

(a) forming a heated composite of a support member to be metallized and a metallized sheet, with a thermoplastic layer therebetween, said metallized sheet having a metal layer to be transferred and a carrier sheet;

(b) heating the composite sufficiently to soften the thermoplastic and then immediately pressing and cooling the composite from both sides by calendering the composite between chilled calender rolls; and

(c) thereafter separating the carrier from the metallized sheet.

2. The method of claim 1 wherein said heated composite is calendered and cooled simultaneously.

3. The method of claim 1 wherein said thermoplastic layer is applied to said metallized sheet before said composite is formed.

4. The method of claim 1 wherein said sheet is of plastic and is metallized on opposite surfaces thereof, and said composite includes a second support member with a second thermoplastic layer facing the opposite surface of the metallized sheet.

5. The method of claim 1 wherein the plastic sheet is remetallized and reused for the metallization of other support members.

6. The method of claim 5 wherein the number of resuses of said plastic sheet is proportional to the thickness thereof.

7. The method of claim 6 wherein a reuse of said plastic sheet is made for each 0.1 mil thickness thereof.

8. The method of claim 1 wherein said release layer is selected from the class of natural waxes consisting of Ouricury, Carnauba, Condelilla, Esparto, Sugar Cane, Montan, Ozocerite, synthetic waxes made by purifying Montan wax and synthetic paraffin wax, microwax characterized by a microcrystalline structure and wax-like materials consisting of metalin salts of fatty acids of at least eleven carbon atoms, consisting of stearates, oleates or linoleates of zinc, calcium, barium, magnesium, aluminum and zirconium.

9. The method of claim 1 wherein said support member and said metallized sheet are heated before calendering.

10. The method of claim 1 wherein said support member and said metallized sheet are heated separately before calendering.

11. The method of claim 1 wherein either the metallized sheet or the support member is heated before calendering.

12. The method of claim 1 wherein said heating is by radiant energy.

13. The method of claim 1 wherein said thermoplastic adhesive layer is heated before the calendering of said composite.

14. The method of claim 1 wherein said support member is pre-heated.

15. The method of claim 1 wherein said metallized sheet is pre-heated before step (a).

16. The method of claim 1 wherein said pre-heating is by radiant heating.