Electrolytic cell

• US 4,804,449 A
• Filed: 08/27/1987
• Issued: 02/14/1989
• Est. Priority Date: 02/25/1986
• Status: Expired due to Term

• Current Assignee: Pureline Treatment Systems, LLC
• Original Assignee: Charles T. Sweeney
• Inventors: Sweeney, Charles T.
• Primary Examiner(s): Valentine, Donald R.
• Application Number:
  US07/090,404
• Time in Patent Office: 537 Days
• Field of Search: 204/254-258, 204/296, 204/128, 204/98, 204/95, 204/284, 204/151
• US Class Current: 204/256
• CPC Class Codes: C02F 1/46109 Electrodes
• CPC Class Codes: C02F 1/4674 with halogen or compound of halogens, e.g. chlorine, bromine
• CPC Class Codes: C02F 2001/46128 Bipolar electrodes
• CPC Class Codes: C02F 2001/46152 characterised by the shape or form electrodes in particulate form or with conductive or non-conductive particles between them C02F1/46114
• CPC Class Codes: C02F 2103/42 from bathing facilities, e.g. swimming pools
• CPC Class Codes: C25B 1/26 Chlorine; Compounds thereof by simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine C25B1/34
• CPC Class Codes: C25B 13/08 based on organic materials

Abstract

An electrolytic cell is disclosed comprising two or more compartments containing an anode, cathode, and one or more electrically neutral bi-polar electrodes. These cells can be utilized as batch or flowing cells. Increased capacity and lower maintenance is obtained using a diaphragm separating the compartments. This diaphragm is a special, finely woven synthetic non-ionic fabric having a low permeability. The preferred diaphragm is of Kanecaron modacrylic fiber. The bi-polar electrodes may be any of several configurations and act as a charged electrical component in a solution. When bi-polar electrodes are used in an anode compartment of a chlorine electrolytic cell, oxygen species are produced which blend with the chlorine species of a standard anode reaction to produce Cl₂, ClO₂ and oxygen species. When used in a cathode compartment, bi-polar electrode configurations serve to cool the caustic due to the agitation occuring on the bi-polars as well as increase buildup of caustic concentration. The diaphragm material is superior to NAFION in maintaining separation between two electrolytes of different viscosities and less back migration has been observed.

Claims

1. A chlorine, chlorine dioxide, oxygen species generator comprising;

a hollow container having a wall dividing the same into a first and second compartment,

said wall having an opening therein closed by a woven non-ionic modacrylic fiber diaphragm with a porosity sufficiently small to substantially prevent back migration of sodium ions during operation of the generator,

an anode positioned in said first compartment,

a cathode positioned in said second compartment,

a bipolar electrode positioned in one of said compartments having a configuration permitting flow of electrolyte around said electrode,

openings for introduction of electrolyte into said container,

openings for discharge of electrolytic reaction products from each of said compartments, and

said generator being adapted when filled with sodium chloride solution in said anode compartment and water or sodium hydroxide solution in said cathode compartment and energized to produce a chloride species from said anode compartment and hydrogen from said cathode compartment.

2. An electrolytic gas generator according to claim 1 in which

at least one bipolar electrode is positioned in said anode compartment and is configured to contact electrolyte on at least two sides thereof.

3. An electrolytic gas generator according to claim 1 in which

at least one bipolar electrode is positioned in said anode compartment and is configured to contact electrolyte on three sides thereof.

4. An electrolytic gas generator according to claim 1 in which

at least one bipolar electrode is positioned in said cathode compartment and is configured to contact electrolyte on at least two sides thereof.

5. An electrolytic gas generator according to claim 1 in which

at least one bipolar electrode is positioned in said cathode compartment and is configured to contact electrolyte on at three sides thereof.

6. An electrolytic gas generator according to claim 1 in which

at least one bipolar electrode is positioned in said cathode compartment and none in said anode compartment.

7. An electrolytic gas generator according to claim 1 in which

said container has openings for connection to sources of electrolyte for continuous flow therethrough.

13. An electrolytic gas generator according to claim 1 in which

said bipolar electrode has a plurality of holes for circulation of electrolyte therethrough.

8. A chlorine, chlorine dioxide, oxygen species generator comprising

a hollow container having two walls dividing the same into first, second and third compartments,

each wall having an opening therein closed by a woven non-ionic modacrylic fiber diaphragm with a porosity sufficiently small to substantially prevent back migration of sodium ions during operation of the generator,

an anode positioned in said first compartment,

a cathode positioned in said third compartment,

a bipolar electrode positioned in said second compartment having a configuration permitting flow of electrolyte around said electrode,

openings for introduction of electrolyte into said container in a batch or continuous manner,

openings for discharge of electrolytic reaction products from each of said compartments, and

said generator being adapted when filled with sodium chloride solution in said anode and bipolar electrode compartments and water or sodium hydroxide solution in said cathode compartment and energized to produce a chlorine species from said anode and bipolar electrode compartments and hydrogen from said cathode compartment.

9. An electrolytic gas generator according to claim 8 in which

at least one bipolar electrode is positioned in said cathode compartment and none in said anode compartment, and said bipolar electrode contacts cathode electrolyte on two sides.

10. An electrolytic gas generator according to claim 8 in which

at least one bipolar electrode is positioned in said cathode compartment and none in said anode compartment, and said bipolar electrode contacts cathode electrolyte on three sides.

11. An electrolytic gas generator according to claim 8 in which

at least one bipolar electrode is positioned in said anode compartment and none in said cathode compartment, and said bipolar electrode contacts anode electrolyte on two sides.

12. An electrolytic gas generator according to claim 8 in which

at least one bipolar electrode is positioned in said anode compartment and none in said cathode compartment, and said bipolar electrode contacts anode electrolyte on three sides.

14. An electrolytic gas generator according to claim 8 in which

said bipolar electrode has a plurality of holes for circulation of electrolyte therethrough.