Gas generating material

• US 4,806,180 A
• Filed: 05/12/1988
• Issued: 02/21/1989
• Est. Priority Date: 12/10/1987
• Status: Expired due to Fees

• Current Assignee: TRW Vehicle Safety Systems Incorporated Lyndhurst Cuyahoga Ohio
• Original Assignee: TRW Vehicle Safety Systems Incorporated (Zeppelin - Stiftung der Stadt Friedrichshafen)
• Inventors: Hamilton, Brian K., Goetz, George W.
• Primary Examiner(s): Lechert, Jr., Stephen J.
• Application Number:
  US07/193,361
• Time in Patent Office: 285 Days
• Field of Search: 149/2, 149/21, 149/5, 149/35, 149/61, 149/110, 280/741
• US Class Current: 149/5
• CPC Class Codes: C06B 45/16 the layer or zone containing at least one inorganic component from the group of azide, fulminate, phosphorus and phosphide
• CPC Class Codes: C06D 5/06 by reaction of two or more solids
• CPC Class Codes: Y10S 149/11 Particle size of a component

Abstract

Structure for generating nitrogen gas for inflating an air bag vehicle occupant resistant comprises a grain made of an azide based material which generates gas upon combustion. The grain has an ignition enhancing coating thereon consisting essentially of 30 to 50% by weight of an alkali metal azide, 40 to 60% by weight of sodium nitrate or potassium perchlorate, 5 to 15% by weight of boron, and 1 to 15% by weight of sodium silicate. The coating may also include 1 to 6% by weight of graphite fibers as a roughening agent.

Claims

1. Structure for generating gas, said structure comprising:

a grain made of an azide based material which generates gas upon combustion;

said grain having an ignition enhancing coating thereon comprising;

30 to 50% by weight of an alkali metal azide, 40 to 60% by weight of an inorganic oxidizer, 5 to 15% by weight of boron, and 1 to 15% by weight of a metal silicate.

2. The structure defined in claim 1 wherein said alkali metal azide is sodium azide and said inorganic oxidizer is sodium nitrate or potassium perchlorate and said metal silicate is sodium silicate.

3. The structure defined in claim 2 wherein the sodium silicate is Na₂ O (SiO₂)_n +where n=about 2 to 5.

4. The structure defined in claim 2 further including 1-6% by weight of graphite fibers or blends of graphite with a reinforcing fiber.

5. The structure defined in claim 1 wherein said coating weight comprises from about 2 to about 6 percent of the weight of the uncoated grain.

6. The structure as defined in claim 1 wherein said grain has opposite axial ends and passages which extend axially through the grain and intersect said opposite axial ends.

7. The structure as defined in claim 1 wherein said grain comprises a gas generating material which contains from about 2 to about 6% by weight of graphite fibers, said graphite fibers having a diameter of 3-15 microns and an average length of 40 to 125 thousandths of an inch.

8. The structure as defined in claim 6 wherein said azide based material comprises:

61-68% by weight of sodium azide,

0-5% by weight of sodium nitrate,

0-5% by weight of bentonite,

23-28% by weight of iron oxide, and

1-2% by weight of fumed metal oxide.

9. The structure as defined in claim 8 further comprising 2 to 6 percent by weight of graphite fibers or a blend of graphite with a reinforcing fiber and wherein said fumed metal oxide is selected from the group consisting of silica, alumina and titania.

10. The structure of claim 9 where the said reinforcing fiber is a potassium titanate fiber.