Method of making low emissivity film for high temperature processing

• US 4,806,220 A
• Filed: 12/29/1986
• Issued: 02/21/1989
• Est. Priority Date: 12/29/1986
• Status: Expired due to Term

• Current Assignee: PPG Industries Incorporated (Nouryon BV)
• Original Assignee: PPG Industries Incorporated (Nouryon BV)
• Inventors: Finley, James J.
• Primary Examiner(s): Niebling, John F.
• Assistant Examiner(s): Nguyen, Nam X.
• Application Number:
  US06/947,799
• Time in Patent Office: 785 Days
• Field of Search: 204/192.15, 204/192.22, 204/192.26, 204/192.27, 204/192.28, 204/192.29
• US Class Current: 204/192.27
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3618 Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
• CPC Class Codes: C03C 17/3644 the metal being silver
• CPC Class Codes: C03C 17/3652 the coating stack containing at least one sacrificial layer to protect the metal from oxidation
• CPC Class Codes: C03C 17/366 Low-emissivity or solar control coatings
• CPC Class Codes: C03C 17/3681 the multilayer coating being used in glazing, e.g. windows or windscreens
• CPC Class Codes: C03C 17/3689 one oxide layer being obtained by oxidation of a metallic layer

Abstract

A multiple-layer, high transmittance, low emissivity coated article which can be subjected to high temperature processing such as bending, annealing, tempering, laminating or glass welding as a result of titanium-containing primer layers is disclosed.

Claims

1. A method for making a high transmittance, high-temperature resistant film comprising the steps of:

a. sputtering a metal cathode target in a reactive atmosphere comprising oxygen thereby depositing a first metal oxide film on a surface of a substrate;

b. sputtering a metal-containing primer layer over said metal oxide layer;

c. sputtering a reflective metallic film over said metal-containing primer layer;

d. sputtering a second metal-containing primer layer over said reflective metallic film;

e. sputtering a second metal oxide film over said second primer layer thereby producing a coated article with a visible transmittance lower than the desired visible transmittance of the final product; and

f. heating said coated article to a sufficient temperature for a sufficient time to increase the visible transmittance of said high-temperature resistant film.

2. A method according to claim 1, wherein said primer layer comprises titanium.

3. A method according to claim 2, wherein said substrate is glass.

4. A method according to claim 3, wherein said metal oxide film comprises an oxide reaction product of an alloy comprising zinc and tin.

5. A method according to claim 1, further comprising the step of depositing a protective metal-containing overcoat over said second metal oxide film.

6. A method for making a multiple layer low emissivity coated product comprising the steps of:

a. placing a transparent, nonmetallic substrate in a sputtering chamber;

b. sputtering a cathode target comprising zinc and tin in a reactive atmosphere comprising oxygen to deposit a first transparent zinc/tin oxide film on a surface of said substrate;

c. sputtering a titanium target to deposit a primer layer on said oxide film;

d. sputtering a silver cathode target in an inert atmosphere to deposit a transparent silver film on said primer layer;

e. sputtering a titanium target to deposit a second primer layer on said silver film;

f. sputtering a cathode target comprising zinc and tin in a reactive atmosphere comprising oxygen to deposit a second zinc/tin oxide film on said second primer layer;

thereby producing a coated article with a visible transmittance lower than the desired visible transmittance of the coated article; and

g. heating said coated article at a sufficient temperature for a sufficient time to increase the visible transmittance of said low emissivity coated product.

7. The method according to claim 6, wherein the substrate is glass.

8. The method according to claim 7, further comprising the step of depositing a metal-containing protective coating over said second metal alloy oxide film.

9. The method according to claim 6, wherein the step of heating the coated article at a sufficient temperature for a sufficient time whereby the transmittance of the coated article increases is further carried out at a sufficient temperature for a sufficient time such that the emissivity decreases.