Polyarylamine compounds and systems utilizing polyarylamine compounds

• US 4,806,443 A
• Filed: 06/10/1987
• Issued: 02/21/1989
• Est. Priority Date: 06/10/1987
• Status: Expired due to Term

• Current Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Original Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Inventors: Yanus, John F., Renfer, Dale S., Limburg, William W., Spiewak, John W.
• Primary Examiner(s): Goodrow, John L.
• Application Number:
  US07/061,248
• Time in Patent Office: 622 Days
• Field of Search: 430/57, 430/72, 430/59, 430/73, 430/58, 430/96, 430/66
• US Class Current: 430/56
• CPC Class Codes: C08G 64/1641 containing nitrogen
• CPC Class Codes: G03G 5/047 characterised by the charge-generation layers or charge transport layers G03G5/0433 and G03G5/0436 take precedence
• CPC Class Codes: G03G 5/0764 triarylamine
• CPC Class Codes: G03G 5/0766 benzidine
• CPC Class Codes: G03G 5/142 Inert intermediate layers

Abstract

An electrostatographic imaging member and an electrophotographic imaging process for using the imaging member are disclosed in which the imaging member comprises a substrate and an electroconductive layer, the imaging member comprising a polymeric acrylamine compound represented by the formula: ##STR1## wherein n is between 5 and about 5,000,

m is 0 or 1,

y is 1, 2 or 3,

Z is selected from certain specified aromatic and fused ring groups,

Ar is selected from certain specified aromatic groups,

Ar'"'"' is selected from certain specified aromatic groups, and

X'"'"' is alkylene radical selected from the group consisting of alkylene and isoalkylene groups containing 2 to 10 carbon atoms.

The imaging member may comprise a substrate, charge generation layer and a charge transport layer.

Claims

1. An electrostatographic imaging member comprising a support layer and at least one electrophotoconductive layer, said imaging member comprising an arylamine compound represented by the formula:

##STR16## wherein;

n is between about 5 and about 5,000,

m is 0 or 1,

y is 1, 2 or 3

Z is selected from the group consisting of;

##STR17## n is 0 or 1, Ar is selected from the group consisting of;

##STR18## R is an alkylene radical selected from the group consisting of alkylene and iso-alkylene groups containing 2 to 10 carbon atoms,

Ar'"'"' is selected from the group consisting of;

##STR19## X is selected from the group consisting of;

##STR20## s is 0, 1 or 2, and X'"'"' is alkylene radical selected from the group consisting of alkylene and isoalkylene groups containing 2 to 10 carbon atoms.

2. An electrostatographic imaging member according to claim 1 wherein said imaging member comprises a charge generating layer and a charge transpot layer.

3. An electrostatographic imaging member according to claim 1 wherein said charge transport layer comprises said arylamine compound, said charge transport layer being substantially transparent to radiation in the region in which said imaging member is exposed during electrosatographic imaging and capable of supporting the injection of photo-generated holes from said charge generating layer and transporting these holes through said charge transport layer to selectively discharge a surface charge.

4. An electrostatographic imaging member according to claim 2 wherein said charge generating layer comprises a photogenerating compound and a binder comprising said arylamine compound.

5. An electrostatographic imaging member according to claim 1 wherein said imaging member comprises a protective overcoating comprising said arylamine compound.

6. An electrophotographic imaging process comprising forming an electrostatic latent image on the imaging surface of an electrostatographic imaging member comprising a support layer and at least one electrophotoconductive layer, said imaging member comprising an arylamine compound represented by the formula:

##STR21## wherein;

n is between about 5 and about 5,000,

m is 0 or 1,

y is 1, 2 or 3

Z is selected from the group consisting of;

##STR22## n is 0 or 1, Ar is selected from the group consisting of;

##STR23## R is an alkylene radical selected from the group consisting of alkylene and iso-alkylene groups containing 2 to 10 carbon atoms,

Ar'"'"' is selected from the group consisting of;

##STR24## X is selected from the group consisting of;

##STR25## s is 0, 1 or 2 X'"'"' is an alkylene radical selected from the group consisting of alkylene and iso-alkylene groups containing 2 to 10 carbon atoms,

and contacting said imaging surface with a developer comprising electrostatically attractable marking particles whereby said electrostatically attractable marking particles deposit on said imaging surface in conformance with said electrostatic latent image to form a marking particle image.

7. An electrophotographic imaging process according to claim 6 wherein said developer is a liquid developer.

8. An electrophotograhic imaging process according to claim 6 wherein said liquid developer comprises an organic carrier fluid.

9. An electrophotographic imaging process according to claim 8 including transfering said marking particle image to a receiving member.

10. An electrophotographic imaging process according to claim 9 including repeating said forming, contacting and transfering steps at least once.

11. An electrophotograhic imaging process according to claim 10 wherein said imaging member comprises a charge generating layer and a charge transport layer comprising said arylamine compound, said charge transport layer being substantially transparent to radiation in the region in which said imaging member is exposed during electrophotographic imaging and capable of supporting the injection of photo-generated holes from said charge generating layer and transporting said holes through said charge transport layer to selectively discharge an electrostatic charge on said imaging surface to form said electrostatic latent image.