Flat transparent top coat for retroreflective sheeting

• US 4,808,471 A
• Filed: 01/04/1988
• Issued: 02/28/1989
• Est. Priority Date: 03/01/1985
• Status: Expired due to Term

• Current Assignee: Minnesota Mining and Manufacturing Co (3M Company)
• Original Assignee: Minnesota Mining and Manufacturing Co (3M Company)
• Inventors: Grunzinger, Raymond E.
• Primary Examiner(s): NOT, DEFINED
• Application Number:
  US07/142,326
• Time in Patent Office: 421 Days
• Field of Search: 428/325, 428/327, 428/423.1, 428/423.3, 428/913, 528/60, 528/66, 528/65
• US Class Current: 428/325
• CPC Class Codes: C08G 18/6229 Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
• CPC Class Codes: C08G 18/75 cycloaliphatic
• CPC Class Codes: C08G 18/765 alpha, alpha, alpha', alpha', -tetraalkylxylylene diisocyanate or homologues substituted on the aromatic ring
• CPC Class Codes: C08G 18/7831 containing biuret groups
• CPC Class Codes: C08G 18/792 formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
• CPC Class Codes: C08G 18/8061 masked with compounds having only one group containing active hydrogen
• CPC Class Codes: G02B 5/128 transparent spheres being embedded in matrix
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture
• CPC Class Codes: Y10T 428/252 Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]
• CPC Class Codes: Y10T 428/254 Polymeric or resinous material
• CPC Class Codes: Y10T 428/31551 Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
• CPC Class Codes: Y10T 428/31554 Next to second layer of polyamidoester

Abstract

The novel retroreflective sheeting has a flat transparent top coat which is as tough and as resistant to solvents and abrasion as are alkyd resins, and as weather resistant as are acrylic polyesters. That top coat is made from a mixture of hydroxy-functional acrylic polyol and a curing agent which is an aliphatic polyfunctional isocyanate such as the biuret of 1,6-hexamethylene diisocyanate. The retroreflective sheeting may have a dual-layer top coat, the outer layer being relatively hard to provide good resistance to solvents, abrasion and weathering, and the inner layer being softer to make the sheeting more conformable.

Claims

1. Retroreflective sheeting have a flat, transparent, tough, solvent-resistant, abrasion-resistant and weather-resistant top coat made form a mixture of hydroxy-functional acrylic polyol and aliphatic polyfunctional isocyanate which serves as curing agent for the polyol, said top coat having a toughness index, defined as the multiplication product of the elongation and tensile strength of the top coat in, respectively, percent and kilograms per square centimeter, of at least 6175.

2. Retroreflective sheeting as defined in claim 1 wherein the isocyanate is used in an amount from 0.5 to 1.5 equivalents per equivalent of the polyol.

3. Retroreflective sheeting as defined in claim 2 wherein the effective T_g of the polyol is from -20°

to 30°

C.

4. Retroreflective sheeting as defined in claim 3 wherein the effective equivalent weight of the polyol is from 350 to 2500.

5. Retroreflective sheeting as defined in claim 4 wherein the isocyanate has been converted to a biuret.

6. Retroreflective sheeting as defined in claim 5 wherein the biuret is the biuret of 1,6-hexamethylene diisocyanate.

7. Retroreflective sheeting as defined in claim 6 wherein the equivalent weight of the biuret when mixed with the polyol is less than 260.

8. Retroreflective sheeting as defined in claim 4 wherein the isocyanate has been converted to isocyanurate trimers.

9. Retroreflective sheeting as defined in claim 4 wherein the aliphatic polyfunctional isocyanate has an aromatic ring which is bonded to a hydrogen-free carbon atom.

10. Retroreflective sheeting wherein the top coat is dual layer, the outer layer being made from a mixture as defined in claim 1.

11. Retroreflective sheeting as defined in claim 10 wherein the outer of said two layers provides good resistance to solvents, abrasion and weathering, and the inner is softer to make the sheeting more conformable.

12. Retroreflective sheeting as defined in claim 11 wherein said inner layer is made from a mixture of hydroxy-functional acrylic polyol and aliphatic polyfunctional isocyanate.

13. Retroreflective sheeting as defined in claim 12, wherein the hydroxy-functional acrylic polyol used in making the outer layer has a T_g from about 0°

to 30°

C., and that used in making the inner layer, a T_g from about -20°

to 0°

C.

14. Retroreflective sheeting defined in claim 1 wherein styrene accounts for no more than 10 molar percent of the monomers from which the polyol is formed.