Polyether-polycarbonate diols and processes for their production and use

• US 4,808,691 A
• Filed: 05/11/1988
• Issued: 02/28/1989
• Est. Priority Date: 05/21/1987
• Status: Expired due to Term

• Current Assignee: Bayer AG
• Original Assignee: Bayer AG
• Inventors: Konig, Klaus, Barnes, James M.
• Primary Examiner(s): Welsh, Maurice J.
• Application Number:
  US07/193,303
• Time in Patent Office: 293 Days
• Field of Search: 528/76, 528/367, 528/370, 528/372, 558/266
• US Class Current: 528/76
• CPC Class Codes: C08G 18/44 Polycarbonates
• CPC Class Codes: C08G 2110/0033 having integral skins
• CPC Class Codes: C08G 64/183 containing polyether sequences

Abstract

Polyether polycarbonate diols based on 1,6-hexanediol and having a molecular weight of from 500 to 12,000 are made by etherifying 50-100 mole % 1,6-hexane-diol in the presence of 0-50 mole % of specified diols and reacting the resultant polyether with a compound selected from diarylcarbonates, dialkyl carbonates, dioxolanones, hexanediol bischlorocarbonic acid esters, phosgene and urea. These diols are particularly useful in the production of polyurethanes having improved physical properties.

Claims

1. A hydroxyl-terminated polyether polycarbonate having a molecular weight of from 500 to 12,000 containing hexamethylene groups as ether groups in which the ratio of ether groups to carbonate groups is from 1 to 1:

5.

2. The composition of claim 1 in which up to mole % of the ether groups are pentamethylene, heptamethylene, octamethylene nonamethylene or decamethylene groups.

3. The composition of claim 1 in which the only ether groups present are hexamethylene groups.

4. The composition of claim 3 in which the ratio of ether groups to carbonate groups is from 3:

1 to 1;

3.

5. The composition of claim 2 in which the ratio of ether groups to carbonate groups is from 3:

1 to 1;

3.

6. The composition of claim 1 in which the ratio of ether groups to carbonate groups is from 3:

1 to 1;

3.

7. A process for the production of the hydroxyl-terminated polyether polycarbonate of claim 1 comprising

(a) preparing a polyether having a molecular weight of from 150 to 500 by etherifying 50-100 mole % 1,6-hexanediol and 0-50 mole % of a second diol selected from 1,7-heptanediol, 1,8-octanediol and 1,9-nonanediol and

(b) reacting the polyether prepared in (a) with a compound selected from diarylcarbonates, dialkyl carbonates, dioxolanones, hexanediol bischlorocarbonic acid esters, phosgene and urea to form a hydroxyl terminated polyether polycarbonate having a molecular weight of from 500 to 12,000.

8. The process of claim 7 in which step (a) comprises reacting a base with the α

,Ω

-diol, α

,Ω

-halogen alcohol or α

,Ω

-dihalogen alkane corresponding to the desired ether groups.

9. The process of claim 7 in which a diol selected from 1,5-pentanediol, 1,6-hexanediol, 1,7-heptanediol, 1,8-octanediol, 1,9-nonanediol and 1,10decanediol is added to the materials being reacted in (b).

10. The process of claim 9 in which the total of diols other than 1,6-hexanediol present during (a) and (b) is no more than 50 mole % of the total diol used.

11. A process for the production of a polyurethane comprising reacting the composition of claim 1 with a di- and/or polyisocyanate.

12. The process of claim 11 in which 0-50 wt. % of a relatively high molecular weight material containing at least two hydroxyl groups other than the composition of claim 1 is included in the reaction mixture.

13. The process of claim 12 in which at least one material selected from chain extending agents, blowing agents, inert solvents, catalysts surface active additives, reaction retarders, stabilizers, flame proofing agents, plasticizers, dyes, fillers, fungistatic and bacteriostatic substances and combinations thereof.