Electrochromic device and method of making an electrochromic layer therefor

• US 4,810,067 A
• Filed: 12/24/1987
• Issued: 03/07/1989
• Est. Priority Date: 12/24/1987
• Status: Expired due to Fees

• Current Assignee: Ford Motor Company
• Original Assignee: Ford Motor Company
• Inventors: Demiryont, Hulya
• Primary Examiner(s): LaRoche, Eugene R.
• Assistant Examiner(s): NOT, DEFINED
• Application Number:
  US07/137,631
• Time in Patent Office: 439 Days
• Field of Search: 350/357, 350/355, 350/356, 350/353
• US Class Current: 359/265
• CPC Class Codes: B29C 67/0007 Manufacturing coloured articles not otherwise provided for, e.g. by colour change
• CPC Class Codes: G02F 1/1523 comprising inorganic material

Abstract

This invention teaches an electrochromic device in which an electrochromic layer is positioned between two electrodes. The electrochromic layer comprises an organic based bulk material which has been polymerized and condensed supporting electrochromic particles and ion producing particles in fixed but generally distributed positions therewithin. The bulk material permits migration of ions produced by the ion producing particles to and from the electrochromic particles upon change in voltage between the first and second electrodes. The bulk material also prohibits the passage of electrons therethrough when a voltage is applied between the first electrode and the second electrode, whereby an electric field is built up between the first and second electrodes which causes migration of the ions. Also my invention is a method of making a material which can form an electrochromic layer. The method has the following steps. A gel producing organic material is dissolved in a solvent to produce a solution. The gel producing material is one which permits migration of ions therethrough but prohibits passage of electrons therethrough. A finely divided ion producing material is added to the solution. A finely divided electrochromic material is also added to the solution. The solution is thoroughly mixed. The solution is then polymerized and condensed to obtain a gelled material. The gelled material supports the finely divided ion producing material and the finely divided electrochromic material in fixed but generally distributed position therewithin.

Claims

1. An electrochromic device which comprises:

a first electrode;

a second electrode;

an electrochromic layer between said first and said second electrodes comprising;

an organic based bulk material which has been polymerized and condensed supporting electrochromic particles and ion producing particles in fixed but generally distributed positions therewithin, said bulk material permitting migration of ions produced by said ion producing particles to and from said electrochromic particles upon change in voltage between said first and second electrodes, said bulk material also prohibiting the passage of electrons therethrough when a voltage is applied between said first electrode and said second electrode, whereby an electric field is built up between said first and second electrodes which causes migration of said ions.

2. The electrochromic device of claim 1 wherein:

one of said first or second electrodes is a transparent electrode.

3. The electrochromic device of claim 1 wherein:

both said first and said second electrodes are transparent electrodes.

4. The electrochromic device of claim 3 wherein:

said organic based bulk material is gelled polyvinylbutyral.

5. The electrochromic device of claim 1 wherein:

said electrochromic particles are anodic electrochromic particles.

6. The electrochromic device of claim 5 wherein:

said anodic electrochromic particles are all the same.

7. The electrochromic device of claim 1 wherein:

said electrochromic particles are cathodic electrochromic particles.

8. The electrochromic device of claim 7 wherein:

said cathodic electrochromic particles are all the same.

9. The electrochromic device of claim 1 wherein:

said electrochromic particles are a mixture of both anodic and cathodic electrochromic particles.

10. The electrochromic device of claim 9 wherein:

said anodic electrochromic particles are all the same and said cathodic electrochromic particles are all the same.

11. A method of making a material which can form an electrochromic layer which comprises the steps of:

dissolving a gel producing organic material in a solvent therefor to produce a solution, said gel producing organic material permitting migration of ions therethrough but prohibiting passage of electrons therethrough;

adding a finely divided ion producing material to said solution;

adding a finely divided electrochromic material to said solution;

mixing said solution thoroughly; and

polymerizing and condensing said solution to obtain a gelled material, said gelled material supporting said finely divided ion producing material and said finely divided electrochromic material in fixed but generally distributed positions therewithin.

12. The method of claim 11 wherein:

said finely divided electrochromic material is an anodic electrochromic material.

13. The method of claim 12 wherein:

said finely divided anodic electrochromic material is all the same.

14. The method of claim 11 wherein:

said finely divided electrochromic material is a cathodic electrochromic material.

15. The method of claim 14 wherein:

said finely divided cathodic electrochromic material is all the same.

16. The method of claim 11 wherein:

said finely divided electrochromic material is a mixture of both anodic electrochromic material and cathodic electrochromic material.

17. The method of claim 16 wherein:

said finely divided anodic electrochromic material is all the same and said finely divided cathodic electrochromic material is all the same.

18. The method of claim 11 wherein:

said organic based bulk material is gelled polyvinylbutyral.