Apparatus and method to distinguish between oil and gas combustion by remote observation using an infrared spectrometer

• US 4,810,884 A
• Filed: 09/25/1987
• Issued: 03/07/1989
• Est. Priority Date: 09/25/1987
• Status: Expired due to Fees

• Current Assignee: Perkinelmer Incorporated
• Original Assignee: Perkinelmer Incorporated
• Inventors: Carlson, Ronald C.
• Primary Examiner(s): Howell, Janice A.
• Assistant Examiner(s): NOT, DEFINED
• Application Number:
  US07/100,854
• Time in Patent Office: 529 Days
• Field of Search: 250/339, 250/338 GA, 250/343
• US Class Current: 250/338.5
• CPC Class Codes: G01N 21/72 using flame burners

Abstract

An apparatus and method for detecting and analyzing the emissions or effluents from gas or oil combustion so as to discriminate between them. A spectrometer detects the spectra of a combustion effluent or exhaust. Identifying features of carbon dioxide and water vapor are selected at predetermined wavenumbers. The ratio of the relative intensities of the identifying features of carbon dioxide and water vapor is then computed, which results in the discrimination between oil and gas effluents.

Claims

1. A device for passively and remotely distinguishing between effluents from the combustion of oil or gas comprising:

spectra detecting means for detecting the infrared spectral radiation emitted by the combustion effluents;

carbon dioxide identifying means for identifying a feature characteristic of carbon dioxide from the detected spectral radiation emitted by the combustion effluents;

water vapor identifying means for identifying a feature characteristic of water vapor from the detected spectral radiation emitted by the combustion effluents;

measuring means for relativistically measuring the intensity of the feature characteristic of carbon dioxide;

measuring means for relativistically measuring the intensity of the feature characteristic of water vapor;

calculating means for calculating the ratio of the measured intensities of the features characteristic of carbon dioxide and water vapor; and

output means for displaying the results of the calculating means whereby the effluents can be determined to have been generated by the combustion of gas or oil.

2. A device for remotely distinguishing between effluents from the combustion of oil or gas as in claim 1 further comprising:

background suppression means for suppressing time varying background radiation.

3. A device for remotely distinguishing between effluents from the combustion of oil or gas as in claim 1 further comprising:

a telescope directing the infrared spectral radiation to said spectra detecting means.

4. A device for remotely distinguishing effluents from the combustion of oil or gas as in claim 1 wherein:

said spectrum detecting means comprises an infrared spectrometer.

5. A device for remotely distinguishing effluents from the combustion of oil or gas as in claim 1 wherein:

said carbon dioxide identifying means identifies the spectral emission characteristic of carbon dioxide over a relatively narrow portion of the spectral emissions; and

said water vapor identifying means identifies the spectral emissions characteristic of water vapor over a relatively narrow portion of the spectral emissions.

6. A device as in claim 5 wherein:

the relatively narrow portion of identifying spectral emissions characteristic of carbon dioxide is between the wavenumbers 625 and 725 cm^-1 ; and

the relatively narrow portion of identifying spectral emissions characteristic of water vapor is between the wavenumbers 1300 and 1400 cm^-1.

7. A device as in claim 5 wherein:

the relatively narrow portion of identifying spectral emissions characteristic of carbon dioxide is located near the wavenumber 719 cm^-1 ; and

the relatively narrow portion of identifying spectral emissions characteristic of water vapor is located near the wavenumber 1314.5 cm^-1.

8. A method for passively and remotely distinguishing effluents from the combustion of oil or gas comprising the steps of:

detecting the infrared spectral radiation emitted by the exhaust;

identifying a portion of the spectral emissions characteristic of carbon dioxide;

relativistically measuring the spectral emissions characteristic of carbon dioxide over a relatively narrow band;

identifying a portion of the spectral emissions characteristic of water vapor;

relativistically measuring the spectral emissions characteristic of water vapor over a relatively narrow band;

calculating the ratio of the relativistically measured values of the spectral emissions characteristic of carbon dioxide and water vapor;

indicating the combustion of oil or gas depending on said ratio.

9. The method as in claim 8 further comprising the step of:

suppressing the background radiation after said step of detecting the infrared spectral radiation emitted by the exhaust.

10. The method as in claim 8 wherein:

the portion of spectral emissions characteristic of carbon dioxide identified is between the wavenumbers 625 to 725 cm^-1 ; and

the portion of spectral emissions characteristic of water vapor identified is between the wavenumbers 1300 and 1400 cm^-1.

11. The method as in claim 10 wherein:

the portion of spectral emissions characteristic of carbon dioxide identified is located near the wavenumber 719 cm^-1 ; and

the portion of spectral emissions characteristic of water vapor identified is located near the wavenumber 1314.5 cm^-1.

12. A method for passively and remotely distinguishing between effluents from the combustion of oil or gas comprising the steps of:

detecting the infrared spectral radiation emitted by a forced plume of effluent emanating from a stack;

suppressing background spectra using factor analysis and rank annihilation techniques to obtain a residual spectrum;

relativistically measuring a portion of the residual spectrum characteristic of carbon dioxide located substantially at wavenumber 719 cm^-1 ;

relativistically measuring a portion of the residual spectrum characteristic of water vapor located substantially at wavenumber 1314.5 cm^-1 ;

calculating the ratio of the relativistically measured values of said spectral characteristic of carbon dioxide and water vapor;

comparing said ratio to a predetermined value for determining whether the combustion of oil or gas has occurred; and

displaying the results of said comparing step.