Heat-meltable polymer for use as adhesive agent, method for manufacturing the same and application thereof for the gluing of substrate materials

• US 4,814,413 A
• Filed: 02/18/1988
• Issued: 03/21/1989
• Est. Priority Date: 03/13/1987
• Status: Expired due to Term

• Current Assignee: Swift Adhesifs SA Avenue Robert Schuman - 41000 Blois
• Original Assignee: Eschem Incorporated
• Inventors: Thibaut, Jean-Pierre, Vittan, Iancu, Tezenas, Philippe
• Primary Examiner(s): WELSH JR, MAURICE
• Application Number:
  US07/157,495
• Time in Patent Office: 397 Days
• Field of Search: 528/80
• US Class Current: 528/80
• CPC Class Codes: C08G 18/4202 Two or more polyesters of different physical or chemical nature C08G18/44 takes precedence
• CPC Class Codes: C08G 2170/20 Compositions for hot melt adhesives
• CPC Class Codes: C08K 5/12 of cyclic polycarboxylic acids
• CPC Class Codes: C08L 75/06 from polyesters
• CPC Class Codes: C09J 175/06 from polyesters

Abstract

A heat-meltable polymer, adapted for use as an adhesive agent, which contains a block prepolymer comprising polyurethane and polycaprolactore sequences and a free NCO group rate comprised between 1% and 5%.

Claims

1. A heat-meltable polymer, adapted for use as an adhesive agent, formed of a block prepolymer having polycaprolactone and polyurethane sequences and comprising:

(a) a polycaprolactone-based resin having from about 0.7 to 1.5 percent free OH groups per mole of the heat-meltable polymer;

(b) a low melting point polyol; and

(c) a diisocyannate having a function rate from about 1.1 to 4 and having from about 1 to 5 percent free NCO groups per mole of the heat-meltable polymer.

2. A polymer according to claim 1, wherein the weight proportion of the --NC--CO.O--urethane sequences and the --(C₆ H₁₀ O₂)_n -polycaprolactone sequences ranges from about 1.1% to 2.1% and from 10% to 40% respectively.

3. A polymer according to claim 1, wherein the polycaprolatone-based resin is a polyester resin having an average molecular weight of 30,000 to 40,000, a melting point of 60°

C. and a vitreous transition temperature of -60°

C.

4. A polymer according to claim 3, wherein said resin comprises polyesters having the caprolactone structure, added to a slightly crystalline linear polyurethane derived from a polyester and from a polyisocyanate, or added to a copolyester formed by polycondensation of adipic acid, isophthalic acid and hexanediol.

5. A polymer according to claim 1, wherein the polyol is an aliphatic homopolyester having a melting point lower than 100°

C. and comprising hydroxyl end groups, the molecular weight of the homopolyester being comprised between 2,000 and 6,000, the hydroxyl index being comprised between 20 and 100 and the melting point ranging from about 50°

C. to 90°

C.

6. A polymer according to claim 5, wherein the polyol is either a condensation polymer of adipic acid and of hexanediol or a crystalline polyester issued from the polycondensation reaction of linear diacid and linear diol.

7. A polymer according to claim 1, wherein the diisocyanate is selected from the group comprising pure 4,4'"'"' diphenylmethane diisocyanate, mixtures of 2,4'"'"' and 4,4'"'"' isomers of diphenylmethane diisocyanate, diisocyanate adducts, isophorone diisocyanate and hexamethylene diisocyanate.

8. Polymer according to claim 1, wherein the weight proportion of the components are respectively comprised between 10 and 40 for the caprolactone prepolymer, between 40 and 80 for the polyol and between 10 and 30 for the diisocyanate.

9. A polymer according to claim 1, which is formed of:

1. polycaprolactone having from about 0.7 to 1.5 percent free OH groups per mole of the heat-meltable polymer;

2. adipic acid and hexanediol homopolyester of which the hydroxyl index is between 20 and 110; and

3. 4,4'"'"' diphenylmethane diisocyanate.

10. A polymer according to claim 9 wherein the respective weight proportions of the components are 25/60/15.

11. A polymer according to claim 10, which contains from 1.5 to 2% free isocyanate groups.

12. A polymer according to claim 11, which contains 2% free isocyanate groups.

13. A polymer according to claim 12, which has a viscosity of between 5,000 and 100,000 mPa.s at 150°

C.

14. A polymer according to claim 13, which is in the solid state at temperatures lower than 40°

C.

15. A heat-meltable polymer, adapted for use as an adhesive agent, formed of a block prepolymer having polycaprolactone and polyurethane sequences and comprising:

(a) from about 10 to 40 percent by weight of a polycaprolactone-based polyester resin having form about 0.7 to 1.5 percent free OH groups per mole of the heat-meltable polymer, an average molecular weight of 30,000 to 40,000, a melting point of about 60° and

a vitreous transition temperature of about -60°

;

(b) from about 40 to 80 percent by weight of a low melting aliphatic homopolyester polyol having hydroxyl end groups, a molecular weight of from about 2,000 to 6,000, and a hydroxyl index between about 20 and 100; and

(c) from about 10 to 30 percent by weight of a diisocyanate having a function rate from about 1.1 to 4 and having from about 1 to 5 percent free NCO groups per mole of the heat-meltable polymer.

16. A polymer according to claim 15 wherein the resin is added to a slightly crystalline linear polyurethane derived from a polyester and from a polyisocyanate, or added to a copolyester formed by polycondensation of adipic acid, isophthalic acid and hexandediol.

17. A polymer acording to claim 15, wherein the weight proportion of the --NC--CO.O-- urethane sequences and the --(C₆ H₁₀ OO₂)_n - polycaprolactone sequences ranges from about 1.1% to 2.1% and from 10% to 40% respectively.

18. A polymer according to claim 15, wherein the polyol is either a condensation polymer of adipic acid and of hexanediol or a crystalline polyester issued from the polycondensation reaction of linear diacid and linear diol.

19. A polymer according to claim 15, wherein the diisocyanate is selected from the group comprising pure 4,4'"'"' diphenylmethane diisocyanate, mixtures of 2,4'"'"' and 4,4'"'"' isomers of diphenylmethane diisocyanate, diisocyanate adducts, isophorone diisocyanate and hexamethylene diisocyanate.