Chemically stabilized film

• US 4,816,343 A
• Filed: 09/17/1987
• Issued: 03/28/1989
• Est. Priority Date: 08/26/1986
• Status: Expired due to Term

• Current Assignee: Cryovac Incorporated (Sealed Air)
• Original Assignee: WR Grace & Company
• Inventors: Schirmer, Henry G., Mueller, Walter B.
• Primary Examiner(s): Herbert, Thomas J.
• Application Number:
  US07/098,116
• Time in Patent Office: 558 Days
• Field of Search: 428/35, 428/480, 428/216, 428/349, 428/483, 428/520, 428/522, 428/523, 156/244.11, 156/244.23, 264/211.23, 264/211, 560/3
• US Class Current: 428/480
• CPC Class Codes: A61J 1/10 Bag-type containers
• CPC Class Codes: B32B 27/36 comprising polyesters
• CPC Class Codes: Y10T 428/31786 Of polyester [e.g., alkyd, etc.]
• CPC Class Codes: Y10T 428/31797 Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31928 Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 428/31935 Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 428/31938 Polymer of monoethylenically unsaturated hydrocarbon

Abstract

In a multilayer flexible film sutable for medical solution packaging, film-derived extractables are controlled by the use of a small amount of a high molecular weight stabilizer in the outer layer of the film. Solution pH can be controlled by the addition of a carbonate of an alkali metal to at least one intermediate adhesive layer and/or the core layer of the film.

Claims

1. In a multilayer flexible film comprising a sealant layer, a core layer of very low density polyethylene, an outer layer of a flexible polyester or copolyester, and a first and a second intermediate adhesive layer, wherein said first adhesive layer bonds the core layer to the sealant layer and wherein said second adhesive layer bonds the core layer to the outer layer, said adhesive layers comprising ethylene ester copolymers or modified ethylene ester copolymers, the improvement comprising the inclusion in at least one intermediate layer of a carbonate of an alkali metal.

2. The improvement according to claim 1 wherein the alkali metal is sodium.

3. The improvement according to claim 1 wherein the carbonate of an alkali metal comprises between about 0.05% and 0.15% by weight of at least one of the first and second intermediate adhesive layers.

4. The improvement according to claim 3 wherein the carbonate of an alkali metal comprises about 0.10% by weight of at least one of the first and second intermediate adhesive layers.

5. In a multilayer flexible film comprising a sealant layer, a core layer of very low density polyethylene, an outer layer of a flexible polyester or copolyester, and a first and a second intermediate adhesive layer, wherein said first adhesive layer bonds the core layer to the sealant layer and wherein said second adhesive layer bonds the core layer to the outer layer, said adhesive layers comprising ethylene ester copolymers or modified ethylene ester copolymers, the improvement comprising inclusion in the core layer of a carbonate of an alkali metal.

6. The improvement according to claim 5 wherein the alkali metal is sodium.

7. The improvement according to claim 5 wherein the carbonate of an alkali metal comprises between about 0.005% and 0.015% by weight of the core layer.

8. The improvement according to claim 7 wherein the carbonate of an alkali metal comprises about 0.1% by weight of the core layer.