Electrochemical cell aqueous electrolyte and method

• US 4,816,352 A
• Filed: 06/21/1984
• Issued: 03/28/1989
• Est. Priority Date: 06/21/1984
• Status: Expired due to Fees

• Current Assignee: Gordon, Arnold Z.
• Original Assignee: Gordon, Arnold Z.
• Inventors: Gordon, Arnold Z.
• Primary Examiner(s): Skapars, Anthony
• Application Number:
  US06/622,785
• Time in Patent Office: 1,741 Days
• Field of Search: 429/13, 429/26, 429/27, 429/29, 429/50, 429/46, 429/120, 429/188, 429/206, 429/218
• US Class Current: 429/405
• CPC Class Codes: H01M 12/06 with one metallic and one gaseous electrode
• CPC Class Codes: H01M 6/04 Cells with aqueous electrolyte
• CPC Class Codes: H01M 6/26 Cells without oxidising active material, e.g. Volta cells

Abstract

An electrochemical cell and a method of controllably generating electricity with the cell wherein the cell comprises an anode of a metal which is highly reactive with water, a cathode of a nonreactive, electrically conductive material spaced from the anode, and an electrolyte which is an aqueous solution of a negatively charged electrolytic ionic specie and which is saturated with respect to the electrochemical reaction product between the anodic metal and the electrolytic ionic specie.

The cell advantageously operates at elevated temperatures, is stable and safe, generates high current densities, provides a readily manageable electrolyte system and is controllable by control of the operating temperature alone.

Claims

1. An electrochemical cell, comprising:

(a) an anode of an anodic metal which is reactive with water; and

,

(b) a non-reactive electrically conductive cathode spaced from said anode, each of said anode and said cathode being at least partially immersed during operation in a liquid electrolyte comprising an aqueous solution of a negatively charged electrolytic ionic specie, said electrolyte being saturated at the interface region between the electrolyte and the anode with respect to the product formed between said ionic specie and said anodic metal as a result of the electrochemical reaction at said anode, said cell being adapted to operate at an elevated temperature sufficiently high to produce useful electrical current at a preselected rate.

2. The cell of claim 1 wherein said anode comprises said anodic metal in compound, alloy or amalgam form.

3. The cell of claim 1 wherein said anode comprises said anodic metal in elemental form.

4. The cell of claim 1 wherein said anodic metal comprises an alkali metal.

5. The cell of claim 4 wherein said metal is sodium.

6. The cell of claim 4 wherein said metal is lithium.

7. The cell of claim 4 wherein said metal is potassium.

8. The cell of claim 1 wherein said cathode comprises a metal.

9. The cell of claim 1 wherein said cathode is a gas diffusion cathode.

10. The cell of claim 9 wherein said cathode is an air cathode.

11. The cell of claim 1 wherein said ionic specie is selected from the group consisting of hydroxide, halide, phosphate and carbonate ions.

12. The cell of claim 1 wherein said ionic specie comprises hydroxide ions.

13. The cell of claim 12 wherein said anodic metal comprises lithium.

14. The cell of claim 1 wherein said electrolyte further comprises a dissolved salt providing said ionic specie and a cation other than the cationic form of said anodic metal.

15. The cell of claim 1 wherein saturation of said electrolyte is effected by the presence of excess solid anode reaction product.

16. The cell of claim 15 further comprising means for physically separating excess solid reaction product from said electrolyte.

17. The cell of claim 16 wherein said separating means comprises a filter.

18. The cell of claim 16 wherein said separating means comprises a centrifuge.

19. The cell of claim 1 wherein said electrolyte temperature is less than the boiling point of said electrolyte at the pressure of operation of said cell.

20. The cell of claim 19 wherein said temperature is greater than the melting point of said anodic metal.

21. The cell of claim 19 wherein said anode comprises elemental lithium and said temperature is greater than about 55°

C.

22. The cell of claim 21 wherein said temperature is greater than about 90°

C.

23. The cell of claim 19 further including associated heat exchange means for maintaining said electrolyte temperature at a desired level.

24. An electrochemical cell, comprising:

(a) a lithium anode; and

,

(b) a non-reactive electrically conductive cathode spaced from said anode, each of said anode and said cathode being at least partially immersed during operation in a liquid electrolyte comprising an aqueous solution of lithium hydroxide, said electrolyte being saturated at the interface region between the electrolyte and the anode with respect to said lithium hydroxide, said cell being adapted to operate at an elevated temperature sufficiently high to produce useful electrical current at a preselected rate.

25. The cell of claim 24 wherein said anode comprises said lithium in compound, alloy or amalgam form.

26. The cell of claim 24 wherein said anode comprises said lithium in elemental form.

27. The cell of claim 24 wherein said cathode comprises a metal.

28. The cell of claim 24 wherein said cathode is a gas diffusion cathode.

29. The cell of claim 24 wherein said cathode is an air cathode.

30. The cell of claim 24 wherein said electrolyte further comprises a dissolved salt providing hydroxide ions and a metal cation other than lithium cation.

31. The cell of claim 30 wherein said electrolyte comprises dissolved sodium hydroxide or potassium hydroxide in addition to said lithium hydroxide.

32. The cell of claim 24 wherein saturation of said electrolyte is effected by the presence of excess solid lithium hydroxide.

33. The cell of claim 32 further comprising means for physically separating excess solid lithium hydroxide from said electrolyte.

34. The cell of claim 33 wherein said separating means comprises a filter.

35. The cell of claim 33 wherein said separating means comprises a centrifuge.

36. The cell of claim 24 wherein said electrolyte temperature is less than the boiling point of said electrolyte at the pressure of operation of said cell.

37. The cell of claim 36 wherein said temperature is greater than the melting point of said lithium anode.

38. The cell of claim 36 wherein said anode comprises elemental lithium and said temperature is greater than about 55°

C.

39. The cell of claim 38 wherein said temperature is greater than about 90°

C.

40. The cell of claim 36 further including associated heat exchange means for maintaining said electrolyte temperature at a desired level.

41. A method of generating electricity in an electrochemical cell, said method comprising the steps of:

(a) providing an anode of an anodic metal which is reactive with water, and a cathode of a nonreactive, electrically conductive material;

(b) at least partially immersing each of said anode and said cathode in an aqueous liquid electrolyte comprising an aqueous solution of a negatively charged electrolytic ionic specie, said electrolyte being saturated with respect to the product formed between said ionic specie and said anodic metal as a result of the electrochemical reaction at said anode;

(c) maintaining said cell at an elevated temperature sufficiently high to produce a useful electrical current at a preselected rate; and

(d) withdrawing electrical current from a circuit connecting said anode and said cathode.

42. The method of claim 41 wherein said anode comprises said anodic metal in compound, alloy or amalgam form.

43. The method of claim 41 wherein said anode comprises said anodic metal in elemental form.

44. The method of claim 41 wherein said anodic metal comprises an alkali metal.

45. The method of claim 44 wherein said metal is sodium.

46. The method of claim 44 wherein said metal is lithium.

47. The method of claim 44 wherein said metal is potassium.

48. The method of claim 41 wherein said cathode comprises a metal.

49. The method of claim 41 wherein said cathode is a gas diffusion cathode.

50. The method of claim 49 wherein said cathode is an air cathode.

51. The method of claim 41 wherein said ionic specie is selected from the group consisting of hydroxide, halide, phosphate and carbonate ions.

52. The method of claim 41 wherein said ionic specie comprises hydroxide ions.

53. The method of claim 52 wherein said anodic metal comprises lithium.

54. The method of claim 41 wherein said electrolyte further comprises a dissolved salt providing said ionic specie and a cation other than the cationic form of said anodic metal.

55. The method of claim 41 wherein saturation of said electrolyte is effected by the presence of excess solid anode reaction product.

56. The method of claim 55 wherein excess solid reaction product formed by said reaction is separated from said electrolyte by physical separating means.

57. The method of claim 56 wherein said separating means comprises a filter.

58. The method of claim 56 wherein said separating means comprises a centrifuge.

59. The method of claim 41 wherein said electrolyte temperature is maintained at less than the boiling point of said electrolyte at the pressure of operation of said cell.

60. The method of claim 59 wherein said temperature is greater than the melting point of said anodic metal.

61. The method of claim 59 wherein said anode comprises elemental lithium and said temperature is greater than 55°

C.

62. The method of claim 61 wherein said temperature is greater than about 90°

C.

63. The method of claim 59 wherein said electrolyte temperature is maintained by heat exchange means associated with said cell.

64. A method of generating electricity in an electrochemical cell, said method comprising the steps of:

(a) providing a lithium anode and a cathode of a nonreactive, electrically conductive material;

(b) at least partially immersing each of said anode and said cathode in an aqueous liquid electrolyte comprising an aqueous solution of lithium hydroxide, said electrolyte being saturated with respect to said lithium hydroxide;

(c) maintaining said cell at an elevated temperature sufficiently high to produce a useful electrical current at a preselected rate; and

(d) withdrawing electrical current from a circuit connecting said anode and said cathode.

65. The method of claim 64 wherein said anode comprises said lithium in compound, alloy or amalgam form.

66. The method of claim 64 wherein said anode comprises said lithium in elemental form.

67. The method of claim 64 wherein said cathode comprises a metal.

68. The method of claim 64 wherein said cathode is a gas diffusion cathode.

69. The method of claim 68 wherein said cathode is an air cathode.

70. The method of claim 64 wherein said electrolyte further comprises a dissolved salt providing hydroxide ions and a metal cation other than lithium cation.

71. The method of claim 70 wherein said electrolyte comprises dissolved sodium hydroxide or potassium hydroxide in addition to said lithium hydroxide.

72. The method of claim 64 wherein saturation of said electrolyte is effected by the presence of excess solid lithium hydroxide.

73. The method of claim 72 wherein excess solid lithium hydroxide is separated from said electrolyte by physical separating means.

74. The method of claim 73 wherein said separating means comprises a filter.

75. The method of claim 73 wherein said separating means comprises a centrifuge.

76. The method of claim 64 wherein said electrolyte temperature is maintained at less than the boiling point of said electrolyte at the pressure of operation of said cell.

77. The method of claim 76 wherein said temperature is greater than the melting point of said anode.

78. The method of claim 76 wherein said anode comprises elemental lithium and said temperature is greater than about 55°

C.

79. The method of claim 78 wherein said temperature is greater than about 90°

C.

80. The method of claim 76 wherein said electrolyte temperature is maintained by heat exchange means associated with said cell.