Heat development process and color photographic recording material suitable for this process

• US 4,816,372 A
• Filed: 09/14/1987
• Issued: 03/28/1989
• Est. Priority Date: 09/26/1986
• Status: Expired due to Fees

• Current Assignee: Agfa-Gevaert AG (Agfa-Gevaert N.V.)
• Original Assignee: Agfa-Gevaert AG (Agfa-Gevaert N.V.)
• Inventors: Peters, Manfred, Schenk, Gunther
• Primary Examiner(s): Schilling, Richard L.
• Application Number:
  US07/095,904
• Time in Patent Office: 561 Days
• Field of Search: 430/203, 430/218, 430/617, 430/619, 430/559
• US Class Current: 430/203
• CPC Class Codes: G03C 8/246 Non-macromolecular agents inhibiting image regression or formation of ghost images
• CPC Class Codes: G03C 8/408 Additives or processing agents not provided for in groups G03C8/402 - G03C8/4046

Abstract

Compounds of the formula I are suitable as thermal development and diffusion promoting agents for the heat development process. With the aid of said compounds higher color transfer densities can be achieved and/or the development time can be shortened. ##STR1## wherein X₁ denotes --SO₂ -- or--CO--;

R¹ to R⁴ denote alkyl, cycloalkyl, aralkyl or aryl;

R⁵ and R⁶ denote acyl or a group as defined for R¹ to R⁴ ; and R¹ together with R⁵, R² together with R⁶, R³ together with R⁴ and/or R¹ together with R² may in each case form a heterocyclic ring containing at least one nitrogen atom.

Claims

1. Heat development process for the production of colour images in which an imagewise exposed colour photographic recording material having at least one layer of binder arranged on a layer support and containing light-sensitive silver halide, optionally in combination with a substantially light-insensitive silver salt, and at least one non-diffusible, colour providing compound which is capable of releasing a diffusible dye as a result of development is developed by heat treatment in the presence of a thermal development and diffusion promoting agent, the dye released imagewise from the non-diffusible, colour providing compound being transferred to an image receptor layer capable of absorbing diffusible dyes, characterised in that the thermal development and diffusion-promoting agent corresponds to the following formula I ##STR7## wherein X denotes SO₂ ;

R¹ to R⁴ denote alkyl, cycloalkyl, aralkyl or aryl;

R⁵ and R⁶ denote acyl or a group as defined for R¹ to R⁴ ; and

R¹ together with R⁵ ;

R² together with R⁶ ;

R³ together with R⁴ ; and

/or R¹ together with R² may in each case form a heterocyclic ring containing at least one nitrogen atom.

2. Process according to claim 1, characterised in that in formula I, the two substituents in each pair R¹ and R² ;

R³ and R⁴ ;

R⁵ and R⁶ are identical.

3. Process according to claim 1, characterised in that in formula I the substituents R¹ to R⁶ are alkyl groups with up to 4 carbon atoms.

4. Process according to one of the claims 1, 2 or 3, characterised in that the thermal development and diffusion-promoting agent is contained in the colour photographic recording material and/or in a separate image receptor material which is in contact with the colour photographic recording material during the heat treatment.

5. Colour photographic recording material developable by heat treatment, having at least one layer of binder which is arranged on a layer support and contains light-sensitive silver halide, optionally in combination with a substantially light-insensitive silver salt, at least one non-diffusible, colour providing compound which is capable of releasing a diffusible dye as a result of development by heat treatment, and at least one thermal development and diffusion promoting agent, characterised in that the thermal development and diffusion promoting agent corresponds to the following formula I:

##STR8## wherein X denotes SO₂ ;

R¹ -R⁴ denote alkyl, cycloalkyl, aralkyl or aryl;

R⁵ and R⁶ denote acyl or a group as defined for R¹ -R⁴ ; and

R¹ together with R⁵ ;

R² together with R⁶ ;

R³ together with R⁴ ; and

/or R¹ together with R² may in each case form a heterocyclic ring containing at least one nitrogen atom.

6. Recording material according to claim 5, characterised in that in formula I, the two members in each pair of substituents R¹ and R² ;

R³ and R⁴ ; and

R⁵ and R⁶ are identical.

7. Recording material according to claim 5, characterised in that in formula I, the substituents R¹ to R⁶ are alkyl groups with up to 4 carbon atoms.