PTC compositions containing low molecular weight polymer molecules for reduced annealing

• US 4,818,439 A
• Filed: 01/30/1986
• Issued: 04/04/1989
• Est. Priority Date: 01/30/1986
• Status: Expired due to Term

• Current Assignee: Sunbeam Products, Inc. d/b/a Jarden Consumer Solutions (Newell Brands Inc.)
• Original Assignee: Sunbeam Corp. (Newell Brands Inc.)
• Inventors: Rowe, William M. Jr., Blackledge, Brian D.
• Primary Examiner(s): Barr, Josephine
• Application Number:
  US06/824,193
• Time in Patent Office: 1,160 Days
• Field of Search: 252/511, 252/512, 252/518, 524/495, 524/496, 264/105, 264/235, 264/236, 264/346, 264/347
• US Class Current: 252/511
• CPC Class Codes: H01C 7/027 consisting of conducting or semi-conducting material dispersed in a non-conductive organic material
• CPC Class Codes: H05B 3/56 Heating cables

Abstract

A revolutionary new semiconductive material having a sharp rise in electrical resistance at a predetermined maximum temperature with substantially no annealing necessary after extrusion to achieve an essentially constant resistance at room temperature. The PTC composition includes a finely divided conductive material, such as carbon black; a suitable semicrystalline polymer having a molecular weight distribution containing a sufficient number of relatively low molecular weight molecules to substantially eliminate annealing; and a suitable polymeric material providing a sufficient number of polar molecules for electrical conductivity. At least 9% by weight of the polymer molecules should be in the molecular weight range of 1,000 to 30,000, and particularly in the 5,000 to 23,000 range and the entire polymeric portion of the composite composition should have a number average molecular weight of 30,000 or less. Generally, the relatively low molecular weight molecules of the semicrystalline polymer (1,000 to 30,000 and particularly 5,000 to 23,000 M.S.) are included in an amount of 9% to 15% based on the total weight of polymer molecules in the composition.

Claims

1. An electrically conductive composite polymer material comprising a suitable finely divided electrically conductive carbon black in an amount of 4 to 25% by weight dispersed within an olefinic polymer wherein the polymer has a number average molecular weight in the range of about 15,000 to 40,000 to reduce the annealing time necessary to achieve an electrically conductive material exhibiting PTC behavior to less than one minute.

2. The composite polymer material of claim 1 wherein the carbon black comprises a carbon black having a pH of at least 4.0.

3. The material of claim 2 wherein the carbon black has a pH in the range of 5.0 to 8.5.

4. The material of claim 3 wherein the carbon black has a pH in the range of 5.5 to 8.0.

5. The composite polymer material of claim 2 wherein the carbon black has a dry volatile content, when heated to 950°

C. of less than or equal to 3.0% by weight.

6. The composite polymer material of claim 1 wherein the carbon black has a N₂ surface area A in m² /gram and a DBP absorption x in cc/100 grams such that A≧

1.75x+e^x/37.

7. The composite polymer material of claim 6 wherein the polymer has a number average molecular weight of 15,000 to 40,000 and a sufficient number of molecules in the molecular weight range of 1,000 to 30,000, as measured by gel permeation chromatographic analysis, to essentially eliminate the need for annealing after extrusion.

8. The composite polymer material of claim 7 wherein the polymer includes a sufficient number of low molecular weight molecules to require annealing for less than 1 second before achieving an essentially constant room temperature conductivity.

9. The composite polymer material of claim 1 wherein the polymer has a number average molecular weight in the range of 15,000 to 30,000.

10. The composite polymer material of claim 1 wherein the polymer has a number average molecular weight in the range of 20,000 to 25,000.

11. The composite polymer material of claim 9 wherein the carbon black comprises a carbon black having a pH of at least 4.0.

12. The composite polymer material of claim 11 wherein the carbon black has a N₂ surface area A in m² /gram and a DBP absorption x in cc/100 grams such that A≧

1.75x+e^x/37.

13. The composite polymer material of claim 1 wherein the olefinic polymer has a weight average molecular weight of about 200,000 or less;

a number average molecular weight of about 15,000 to 30,000; and

9 to 15% of the polymer molecules having a molecular weight of less than 23,000.

14. An electrically conductive composite polymer material comprising a suitable finely divided electrically conductive carbon black in an amount of 4 to 25% by weight dispersed within an olefinic polymer wherein the polymer has a number average molecular weight in the range of about 15,000 to about 40,000 to reduce the annealing time necessary to achieve an electrically conductive material exhibiting PTC behavior to less than one minute.

15. An electrically conductive composite polymer material comprising a suitable finely divided electrically conductive carbon black in an amount of 4 to 25% by weight dispersed within a first, semicrystalline, olefinic polymer wherein the polymer has a number average molecular weight in the range of about 15,000 to 40,000;

and a second polymer material having one or more polar groups in an amount of at least 2% by weight of the electrically conductive material to reduce the annealing time necessary to achieve an electrically conductive material exhibiting PTC behavior.