Process for removing or separating pollutants from waste gases

• US 4,818,505 A
• Filed: 03/28/1986
• Issued: 04/04/1989
• Est. Priority Date: 04/26/1983
• Status: Expired due to Fees

• Current Assignee: Dietrich Muller
• Original Assignee: Dietrich Muller
• Inventors: Muller, Dietrich
• Primary Examiner(s): Doll, John
• Assistant Examiner(s): Russel, Jeffrey E.
• Application Number:
  US06/832,150
• Time in Patent Office: 1,103 Days
• Field of Search: 423/220, 423/225, 423/242 A, 423/242 R, 423/243, 423/244 A, 423/244 R, 423/210, 55/72, 55/73, 210/711, 71/13, 44/10 A, 44/589, 44/590
• US Class Current: 423/210
• CPC Class Codes: B01D 53/34 Chemical or biological purification of waste gases
• CPC Class Codes: B01D 53/501 by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
• CPC Class Codes: B01D 53/64 Heavy metals or compounds thereof, e.g. mercury

Abstract

The invention relates to a process for the removal or separation of pollutants, such as sulphur or metal compounds from waste gases, by contacting the waste gases with aqueous binder suspensions, comprising using a sewage sludge as the binder suspension. The binder suspension is preferably constituted by a sewage sludge mixed with comminuted, dried autumn leaves or an extraction residue thereof and to which are added further additives, particularly alkaline substances. Apart from the excellent manner in which sewage sludge binds pollutants, roasting is made more economic due to the high carbon content of the sewage sludge.

Claims

1. A process for removing or separating pollutants including heavy metal pollutants and SO₂ from flue gas comprising the following step:

contacting the flue gas having said heavy metal pollutants and less than or equal to 1.0% by weight of SO₂, with a binder suspension consisting essentially of sludge in an aqueous suspension having 2 to 10% sludge solids consisting of digested sewage sludge.

2. A process according to claim 1, wherein the binder suspension consists of digested sewage sludge mixed with comminuted, dried autumn leaves or with the solvent extraction residue of comminuted, dried autumn leaves, the comminuted dried autumn leaves being 30-40% of the carbon content on a dry basis of the binder suspension.

3. A process according to claim 1 comprising adding an alkaline substance to the digested sewage sludge suspension.

4. A process according to claim 3 comprising passing the flue gas through the digested sewage sludge suspension.

5. A process according to claim 1 comprising passing the flue gas through the digested sewage sludge suspension.

6. A process according to claim 3 comprising spraying the digested sewage sludge suspension into the flue gas.

7. A process according to claim 1 comprising spraying the digested sewage sludge suspension into the flue gas.

8. A process according to claim 1 comprising passing the digested sewage sludge suspension through the flue gas in counterflow in a binding zone such a way that the digested sewage sludge is partially dried and in one part of the binding zone is present in liquid form and in a further part of the binding zone is present in solid form and absorbing the pollutants in two stages in different aggregate states of the binder.

9. A process according to claim 3 comprising passing the digested sewage sludge suspension through the flue gas in counterflow in a binding zone in such a way that the digested sewage sludge is partially dried and in one part of the binding zone is present in liquid form and in a further part of the binding zone is present in solid form and absorbing the pollutants in two stages in different aggregate states of the binder.

10. A process according to claim 4 comprising passing the digested sewage sludge suspension through the flue gas in counterflow in a binding zone such a way that the digested sewage sludge is partially dried and in one part of the binding zone is present in liquid form and in a further part of the binding zone is present in solid form and absorbing the pollutants in two stages in different aggregate states of the binder.

11. A process according to claim 6 comprising passing the digested sewage sludge suspension through the flue gas in counterflow in a binding zone such a way that the digested sewage sludge is partially dried and in one part of the binding zone is present in liquid form and in a further part of the binding zone is present in solid form and absorbing the pollutants in two stages in different aggregate states of the binder.

12. A process according to claim 1 comprising carrying out the flue gas cleaning in a cleaning absorber simultaneously acting as a stack.

13. A process according to claim 1 comprising processing the pollutant-charged digested sewage sludge with a carbon-containing material waste to form fuel briquets.

14. A process according to claim 13 wherein the carbon-containing material waste is dried autumn leaves or the solvent extraction residue of dried autumn leaves.

15. A process according to claim 13 wherein the carbon-containing material waste is straw or garbage.

16. A process according to claim 9 comprising adding to a new digested sewage sludge suspension the ash obtained after burning the fuel briquettes produced from a digested sewage sludge previously employed for cleaning SO₂ -containing flue gas and using the new digested sewage sludge suspension to remove or separate pollutants from a further batch of SO₂ -containing flue gas.

17. A process according to claim 1 wherein said flue gas is contacted with said digested sewage sludge for a period of time less than or equal to 40 minutes.

18. A process for removing or separating pollutants including heavy metal pollutants and SO₂ from flue gas comprising the following step:

contacting the flue gas having said heavy metal pollutants and less than or equal to 1.0% by weight of SO₂, with a binder suspension consisting essentially of sludge in an aqueous suspension having 2 to 10% sludge solids consisting of a member of the group consisting of digested sewage sludge, excavator sludge and dredger sludge.

19. A process for removing or separating pollutants including heavy metal pollutants and SO₂ from flue gas consisting of the following step:

contacting the flue gas having said heavy metal pollutants and less than or equal to 1.0% by weight of SO₂, with a binder suspension consisting essentially of sludge in an aqueous suspension having 2 to 10% sludge solids consisting of digested sewage sludge.