Method for the recovery of sterilants

• US 4,822,563 A
• Filed: 10/26/1987
• Issued: 04/18/1989
• Est. Priority Date: 10/26/1987
• Status: Expired due to Term

• Current Assignee: Joslyn Valve Corporation
• Original Assignee: Joslyn Valve Corporation
• Inventors: Joslyn, Larry
• Primary Examiner(s): Richman, Barry S.
• Assistant Examiner(s): ALEXANDER, LYLE
• Application Number:
  US07/112,333
• Time in Patent Office: 540 Days
• Field of Search: 422/2, 422/31, 422/33, 422/34, 55/279
• US Class Current: 422/31
• CPC Class Codes: A61L 2/20 Gaseous substances, e.g. vapours
• CPC Class Codes: A61L 2/206 Ethylene oxide
• CPC Class Codes: C07D 301/32 Separation; Purification

Abstract

For safe removal and collection of chemical sterilants such as ethylene oxide from a sterilization process, steam or other substantially condesable, inert dilutent gas is used to extract and to transport sterilant from the inside of sterilized materials and the sterilizing chamber into a collection tank. The sterilant and the condensable dilutent are separated when the mixture is discharged from the sterilizing chamber such that virtually all of the sterilant can be collected as a liquid by compression and/or refrigeration at practical pressures and temperatures.

Claims

1. A method for safely recovering a flammable chemical sterilant gas from a sterilizing chamber following the treatment of material within the chamber with said gas at an elevated pressure which comprises:

(a) reducing the pressure in said chamber,

(b) flushing the chamber at the reduced pressure with a stream of substantially condensable, inert dilutant gas,

(c) recovering from the chamber a discharge stream comprising said sterilant and said condensable dilutant,

(d) subjecting said stream to conditions of temperature and pressure for causing said dilutant to condense but not the sterilant gas, thereby separating the dilutant from the sterilant gas, and thereafter

(e) recovering the sterilant gas.

2. A method according to claim 1 wherein said elevated pressure is a superatmospheric pressure and the flushing of the chamber in step (b) is at subatmospheric pressure.

3. A method according to claim 1 wherein the sterilant gas is ethylene oxide and the condensable dilutent is steam.

4. A method according to claim 3 wherein steam is flowed through the chamber for a period of time sufficient to remove substantially all of the ethylene oxide from the chamber.

5. A method according to claim 4 wherein the elevated Pressure is above about 19 psia and the chamber is flushed with steam at a pressure from about 1 to 2 psia.

6. A method according to claim 3 wherein after flushing the chamber with steam, (a) the pressure in the chamber is raised to a level sufficient to condense steam on the load being sterilized and for a time sufficient to extract ethylene oxide from the load, (b) thereafter, steam is flowed through the chamber at a reduced pressure which is sufficiently low to vaporize the condensed steam and ethylene oxide and flush them from the chamber, and (c) the sequence of steps (a) and (b) is repeated until substantially all of the ethylene oxide is removed from the chamber.

7. A method according the claim 6 wherein the ethylene oxide gas after separation from the steam condensate is subjected to conditions of temperature and pressure causing it to liquefy.

8. A method of recovering a chemical sterilant gas from a sterilizing chamber which comprises flushing the chamber with a substantially condensable, insert dilutent gas and selectively condensing the effluent dilutent gas to separate the sterilant gas from the dilutent.

9. A method according to claim 8 wherein the sterilant gas is a flammable gas and the dilutent gas is steam.

10. A method according to claim 8 wherein the sterilant gas is ethylene oxide.