Flame resistant electrical insulating material

• US 4,824,723 A
• Filed: 06/02/1986
• Issued: 04/25/1989
• Est. Priority Date: 06/02/1986
• Status: Expired due to Fees

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Campbell, Richard W., Kimbel, Kirk L.
• Primary Examiner(s): KENDELL, LORRAINE
• Application Number:
  US06/833,707
• Time in Patent Office: 1,058 Days
• Field of Search: 428/412, 428/480, 428/336, 428/500, 428/522, 428/337, 428/332, 428/921, 428/483, 428/423.1, 428/423.7, 428/475.2, 428/334, 174/120 SR
• US Class Current: 428/332
• CPC Class Codes: H01B 3/421 Polyesters
• CPC Class Codes: H01B 7/295 using material resistant to flame
• CPC Class Codes: Y10S 428/921 Fire or flameproofing
• CPC Class Codes: Y10T 428/26 Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
• CPC Class Codes: Y10T 428/263 Coating layer not in excess of 5 mils thick or equivalent
• CPC Class Codes: Y10T 428/265 1 mil or less
• CPC Class Codes: Y10T 428/266 of base or substrate
• CPC Class Codes: Y10T 428/31507 Of polycarbonate
• CPC Class Codes: Y10T 428/31551 Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
• CPC Class Codes: Y10T 428/31565 Next to polyester [polyethylene terephthalate, etc.]
• CPC Class Codes: Y10T 428/31736 Next to polyester
• CPC Class Codes: Y10T 428/31786 Of polyester [e.g., alkyd, etc.]
• CPC Class Codes: Y10T 428/31797 Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31855 Of addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31935 Ester, halide or nitrile of addition polymer

Abstract

A flame resistant electrically insulating multilayer material is described herein, in which a flame resistant core which may be comprised of coextrudable, thermoformable thermoplastic materials has at least one electrically insulating outer layer attached thereto. Preferred polymeric materials forming the core include blends of polycarbonates with halogen-containing polycarbonates. Each outer layer typically may be formed from polycarbonates and linear polyesters. The multilayer material may be shaped to surround and shield any sensitive device requiring protection from high voltage arcing or fire.

Claims

1. A coextruded flame resistant electrically insulating multilayer material comprising a flame resistant core, said core comprised of a thermoplastic polymer selected from the group comprising polyolefins, poly(aryl ethers), polyetherimides, polyamides, poly(aryl sulfones), thermoplastic polyurethanes, alkenyl aromatic polymers, acrylic-based polymers, polycarbonates, nitrile barrier resins, thermoplastic polyester, and blends of said polymers blended with a flame retardant and an electrically insulating first thermoplastic outer layer wherein said thermoplastic core is the only flame resistant polymer in said multilayer material and wherein said flame retardant is the only flame retardant in said multilayer material.

2. The material of claim 1 further comprising an electrically insulating second thermoplastic outer layer attached to a second surface of the core opposite the first surface.

3. The material of claim 2 wherein the first and second outer layers are formed from polymers or copolymers selected from the group consisting of polyesters and polycarbonates.

4. The material of claim 2 wherein the core and first and second outer layers are extruded simultaneously.

5. The material of claim 2 wherein the core is formed from at least one thermoformable material.

6. The material of claim 2 wherein the thermoplastic polymer core is a polycarbonate.

7. The material of claim 6 wherein the halogen-containing organic compound is a copolycarbonate derived from a halogenated bisphenol-A and a dihydric phenol.

8. A coextruded flame resistant electrically insulating multilayer material comprising a flame resistant core, said core comprised of a thermoplastic polycarbonate polymer blended with a flame retardant comprised of a copolycarbonate derived from a halogenated bisphenol -A and a dihydric phenol, and electrically insulating first and second thermoplastic outer layers attached to a first and second surface of the core, respectively, said second surface of the core opposite to said first surface and wherein the first and second thermoplastic outer layers are polyesters and wherein said thermoplastic core is the only flame resistant polymer in said multilayer material and wherein said flame retardant is the only flame retardant in said multilayer material.

9. The material of claim 8 wherein the polyester forming the first and second outer layers is poly(ethylene terephthalate).

10. The material of claim 8 wherein the polyester forming the first and second outer layers is a blend of a polymer derived from cyclohexanedimethanol and a mixture of iso- and terephthalic acids with an aromatic polycarbonate.

11. A coextrudable and thermoformable multilayer material exhibiting flame resistance and electrical insulative capability, comprising

a flame resistant core formed from an aromatic

polycarbonate blended with a copolycarbonate derived

from a halogenated bisphenol-A and a dihydric phenol,

and first and second outer layers attached to

first and second surfaces of the core, respectively,

said outer layers formed from polymers or copolymers

selected from the group consisting of polyesters and

polycarbonates.

12. The multilayer material of claim 11 wherein the polymer forming the first and second outer layers is poly(ethylene terephthalate).

13. The multilayer material of claim 11 wherein the polymer forming the first and second outer layers comprises:

(a) a polyester derived from

cyclohexanedimethanol and a mixture of iso- and terephthalic acids; and

(b) an aromatic carbonate polymer.

21. A multilayer material according to claim 11 wherein each of said outer layers has a thickness of greater than about 1 mil.

22. A multilayer material according to claim 11 wherein each of said outer layers has a thickness of from about 1 to about 10 mils.

23. A multilayer material according to claim 11 wherein each of said outer layers has a thickness of from about 1 to about 7 mils.

24. A multilayer material according to claim 11 wherein said core has a thickness of greater than about 4 mils.

25. A multilayer material according to claim 11 wherein said core has a thickness of from about 4 to about 240 mils.

26. A multilayer material according to claim 11 wherein said core has a thickness of from about 12 to about 22 mils.

27. A multilayer material according to claim 11 wherein each of said outer layers are substantially equal in thickness.

28. A multilayer material according to claim 11 wherein the total thickness of the core and said outer layers is from about 20 to about 30 mils.

14. A coextruded flame retardant electrically insulating multilayer material comprising a flame retardant core, said core comprised of a polycarbonate blended with a halogenated copolycarbonate, and an electrically insulating first thermoplastic outer layer comprised of polymers or copolymers selected from the group consisting of polyesters and polycarbonates, wherein said core is the only flame resistant polymer in said multilayer material and wherein said halogenated copolycarbonate is the only flame retardant in said multilayer material.

15. A multilayer material according to claim 14 wherein said outer layer has a thickness of greater than about 1 mil.

16. A multilayer material according to claim 14 wherein said outer layer has a thickness of from about 1 to about 10 mils.

17. A multilayer material according to claim 14 wherein said outer layer has a thickness of from about 1 to about 7 mils.

18. A multilayer material according to claim 14 wherein said core has a thickness of greater than about 4 mils.

19. A multilayer material according to claim 14 wherein said core has a thickness of from about 4 to about 240 mils.

20. A multilayer material according to claim 14 wherein said core has a thickness of from about 12 to about 22 mils.

29. A coextruded flame resistant electrically insulating multilayer material comprising a flame resistant core, said core comprised of a thermoplastic polymer selected from the group consisting of polyolefins, poly(aryl ethers), polyether imides, polyamides, poly(aryl sulfones), polyurethanes, alkenyl aromatic polymers, acrylic-based polymers, polycarbonates, nitrile barrier resins, and copolymers, mixtures and blends of the foregoing, blended with a flame retardant, and an electrically insulating first thermoplastic outer layer selected from the group consisting of polyesters, polycarbonates, polyphthalate carbonates, copolyestercarbonates and copolymers, mixtures and blends of the foregoing, wherein said thermoplastic core is the only flame resistant polymer in said multilayer material and wherein said flame retardant is the only flame retardant in said multilayer material.

30. A multilayer material according to claim 29 wherein said flame retardant is selected from the group consisting of chlorinated hydrocarbons, brominated hydrocarbons, halogenated organo phosphorous compounds, non-halogenated organo phosphorous compounds, zinc salts, antimony salts, aluminum salts, molybdenum salts, brominated aromatics, brominated aliphatic polyols, phosphorous-containing polyols, an admixture of an aromatic polycarbonate and a polytetrafluoro ethylene (PTFE), and mixtures of any of the foregoing.