Tungsten carbide-cobalt coatings for various articles

• US 4,826,734 A
• Filed: 03/03/1988
• Issued: 05/02/1989
• Est. Priority Date: 03/03/1988
• Status: Expired due to Fees

• Current Assignee: Praxair S.T. Technology, Inc. (Linde Plc)
• Original Assignee: Union Carbide Corporation (Dow, Inc.)
• Inventors: Jackson, John E., Quets, Jean M., Price, Marianne O., Meyerhoff, Robert W.
• Primary Examiner(s): Swisher, Nancy A. B.
• Application Number:
  US07/163,945
• Time in Patent Office: 425 Days
• Field of Search: 428/698, 428/699, 428/469, 428/472
• US Class Current: 428/472
• CPC Class Codes: C23C 4/06 Metallic material

Abstract

The invention relates to a coated article comprising a substrate coated with a tungsten carbide-cobalt layer having a strain-to-fracture greater than 4.3×10^-3 inch per inch and a Vickers hardness of greater than about 875 HV₀.3.

Claims

1. A coated article comprising a substrate coated with a tungsten carbide-cobalt layer having a strain-to-fracture greater than 4.3×

10^-3 inch per inch and a Vickers hardness of greater than about 875 HV₀.3.

2. The coated article of claim 1 wherein the tungsten carbide-cobalt layer has a strain-to-fracture from about 4.5×

10^-3 to 10×

10^-3 inch per inch and a Vickers hardness of greater than about 900 HV₀.3.

3. The coated article of claim 1 wherein the tungsten carbide cobalt layer has a strain-to fracture greater than 5.3×

10^-3 inch and a Vickers hardness of greater than about 1000 HV₀.3.

4. The coated article of claim 1, 2 or 3 wherein the tungsten carbide-cobalt layer is from about 0.0005 to about 0.1 inch thick.

5. The coated article of claim 4 wherein the tungsten carbide cobalt layer is from about 0.001 to about 0.02 inch thick.

6. The coated article of claim 1, 2 or 3 wherein the tungsten carbide-cobalt layer has a cobalt content of from about 7 to about 20 weight percent, a carbon content from about 0.5 to about 5 weight percent and tungsten content of from about 75 to 92.5 weight percent.

7. The coated article of claim 6 wherein said layer contains up to 6 weight percent chromium.

8. The coated article of claim 7 wherein said layer contains from about 3 to about 5 weight percent chromium.

9. The coated article of claim 8 wherein said layer contains about 4 weight percent chromium.

10. The coated article of claim 6 wherein the cobalt content is from about 8 to about 18 weight percent, the carbon content is from about 2.0 to about 4.0 weight percent and the tungsten content is from about 78 to about 90 weight percent.

11. The coated article of claim 6 wherein said substrate is selected from the group consisting of titatium, steel, aluminum, nickel, cobalt and alloys thereof.

12. The coated article of claim 6 wherein the cobalt content is about 9 to about 15 weight percent, the carbon content is about 2.5 to about 4.0 weight percent and the tungsten content is about 81 to about 88.5 weight percent, and wherein the substrate is a titanium based alloy.

13. The coated article of claim 6 wherein said layer contains up to 6 weight percent chromium and wherein said substrate is selected from the group consisting of titanium, steel, aluminum, nickel, cobalt and alloys thereof.

14. The coated article of claim 6 wherein said layer contains up to 6 weight percent chromium and wherein said substrate is a titanium based alloy.

15. The coated article of claim 1, 2 or 3 wherein said substrate is selected from the group consisting of titanium, steel, aluminum, nickel, cobalt and alloys thereof.