Dual sample cell gas analyzer

• US 4,829,183 A
• Filed: 09/11/1987
• Issued: 05/09/1989
• Est. Priority Date: 09/11/1987
• Status: Expired due to Term

• Current Assignee: AC Limited (Emirate of Dubai (United Arab Emirates))
• Original Assignee: Andros Anlayzers Incorporated
• Inventors: McClatchie, Edward A., Williams, Kevin G.
• Primary Examiner(s): Fields, Carolyn E.
• Application Number:
  US07/096,169
• Time in Patent Office: 606 Days
• Field of Search: 250/345, 250/343, 250/344, 250/346, 250/339, 250/352
• US Class Current: 250/346
• CPC Class Codes: G01N 2021/3137 with selection of wavelengths after the sample
• CPC Class Codes: G01N 2021/3166 using separate detectors and filters
• CPC Class Codes: G01N 21/3504 for analysing gases, e.g. multi-gas analysis
• CPC Class Codes: G01N 2201/1215 for interfering gases

Abstract

A non-dispersive infrared gas analyzer is disclosed that accurately measures the concentration levels of a plurality of gases within a gas mixture. The analyzer includes first and second sample cells and is utilized advantageously for the measurement of NO_x and hydrocarbon gas present in the exhaust of an automobile engine. The gas mixture of the exhaust is chilled before entering the first sample cell to remove a substantial amount of the water vapor from that sample cell to facilitate measurement of the NO_x gas. The second sample cell receives the gas mixtue in an unchilled state to allow for accurate measurement of the hydrocarbon gas. The analyzer includes processors which are utilized to further correct the NO_x measurement and which also interact with each other to provide an output data stream that is representative of the concentration levels of the gases that are being analyzed.

Claims

1. A non-dispersive gas analyzer comprising:

a first sample cell for containing a sample gas mixture to be analyzed for the presence of NO_x gas;

a second sample cell for containing said gas mixture to be analyzed for the presence of hydrocarbon gas;

means for directing infrared energy through said first and second sample cells;

means for modulating the amplitude of said infrared energy;

means for dehumidifying said gas mixture entering said first sample cell;

first detector means for detecting the infrared energy passing through the dehumidified gas mixture in said first sample cell at a characteristic absorption wavelength of said NO_x gas and producing a first signal representative thereof;

second detector means for detecting the infrared energy passing through said second sample cell at a characteristic absorption wavelength of hydrocarbon gas and producing a second signal representative thereof;

processor means for processing said first signal of said first detector means to provide an indication of the concentration level of NO_x gas in said gas mixture and for processing said second signal of said second detector means to provide an indication of the concentration level of hydrocarbon gas in said gas mixture; and

means for measuring a residual amount of water vapor within the dehumidified gas mixture in said first sample cell and for providing a correction signal representative thereof, wherein said processor means utilizes said correction signal to provide a more accurate indication of the concentration level of NO_x gas.

2. The gas analyzer of claim 1 which further comprises;

means for detecting the infrared energy passing through said second sample cell at the characteristic wavelength of CO₂ gas and producing a signal representative thereof;

wherein said processor means is responsive to said CO₂ gas signal to correct said signal from said first detector means to provide a more accurate indication of the concentration level of NO_x gas.

3. The gas analyzer of claim 2 in which said modulating means comprises;

a rotary chopper blade; and

a stepper motor for rotating said chopper blade through a plurality of position steps, each position step being of a predetermined duration.

4. The gas analyzer of claim 3 in which said processor means controls said stepper motor so as to cause said chopper blade to alternately block the infrared energy entering said first and second sample cells.

5. The gas analyzer of claim 2 in which said processor means further comprises;

a first processor for receiving and processing said first signal representative of NO_x gas and said water vapor correction signal; and

a second processor for receiving and processing said second signal and said CO₂ gas signal;

wherein said first processor receives said CO₂ gas signal from said second processor and processes said CO₂ gas signal, said water vapor correction signal and said NO_x gas signal to provide an output signal indicative of the concentration level of NO_x gas, and wherein said second processor receives said output signal from said first processor and provides an output data stream representative of NO_x and hydrocarbon concentrations.

6. A non-dispersive gas analyzer comprising:

a sample cell for containing a first sample gas mixture to be analyzed for the presence of a predetermined gas;

means for directing infrared energy through said sample cell;

means for modulating the amplitude of said infrared energy;

means for dehumidifying the gas mixture entering said sample cell, said sample cell containing a residual amount of water vapor;

means for measuring said residual amount of water vapor and for producing a correction signal representative thereof;

means for detecting the infrared energy passing through said sample cell at the characteristic wavelength of said predetermined gas and producing an output signal representative thereof; and

,

processor means for processing said correction signal with said output signal to provide a corrected output signal representative of the characteristic absorption wavelength of said predetermined gas.

7. A non-dispersive gas analyzer comprising:

a first sample cell for containing a sample gas mixture to be analyzed for the presence of a first predetermined gas;

a second sample cell for containing the sample gas mixture to be analyzed for the presence of a second predetermined gas;

means for directing infrared energy through said first nd second sample cells;

means for modulating the amplitude of said infrared energy;

first detector means for detecting the infrared energy passing through said first sample cell at a first characteristic absorption wavelength of said first predetermined gas and producing a first signal representative thereof;

second detector means for detecting the infrared energy passing through said second sample cell at a second characteristic absorption wavelength of said second redetermined gas and producing a second signal representative thereof;

processor means for processing said second signal of said second detector means to provide an indication of the concentration level of said second predetermined gas in said gas mixture, said processing means being responsive to said indication of the concentration level of said second predetermined gas and providing a correction signal representative of the interference of said second predetermined gas with said first predetermined gas;

said processing means processing said first signal of said first detector means and said correction signal to provide an indication of the concentration level of said first predetermined gas in said gas mixture.

means for dehumidifying said gas mixture entering said first sample cell, said first sample cell containing a residual mount of water vapor; and

means for measuring the residual amount of water vapor and providing a measurement signal representative thereof;

wherein said processor means utilizes said measurement

signal to provide a more accurate indication of the concentration level of said second predetermined gas.