Conversion of aluminum-mercury amalgam and incidental mercury in contact with aluminum alloy surfaces to harmless compounds

• US 4,830,829 A
• Filed: 09/04/1987
• Issued: 05/16/1989
• Est. Priority Date: 09/04/1987
• Status: Expired due to Fees

• Current Assignee: Exxonmobil Oil Corporation (Exxon Mobil Corporation)
• Original Assignee: Mobil Oil Corporation (Exxon Mobil Corporation)
• Inventors: Craig, Howard L. Jr.
• Primary Examiner(s): Marcus, Michael S.
• Assistant Examiner(s): Santiago, Amalia L.
• Application Number:
  US07/093,277
• Time in Patent Office: 620 Days
• Field of Search: 422/7, 148/6.27, 148/6.3, 427/255.1, 427/255.2, 427/255.3, 427/142, 423/569
• US Class Current: 422/7
• CPC Class Codes: B01J 19/002 Avoiding undesirable reactions or side-effects, e.g. avoiding explosions, or improving the yield by suppressing side-reactions
• CPC Class Codes: C23C 22/02 using non-aqueous solutions

Abstract

A method for treating mercury-contaminated aluminum surfaces to render aluminum-mercury amalgam and liquid mercury harmless to aluminum is provided. The method involves converting the mercury to a compound which is inert to aluminum, such as mercuric sulfide, at temperatures below the freezing point of water. This is accomplished by contacting the aluminum surface with a condensable solvent such as carbon disulfide, carbonyl sulfide, or tetrahydrofuran having gaseous hydrogen sulfide dissolved therein, and then dissolving a reactive gas such as sulfur dioxide within the solvent. The reaction of the two dissolved gases within the solvent generates the sulfur which reacts with the mercury to form mercuric sulfide.

Claims

1. A method for treating a mercury-contaminated aluminum surface, comprising:

(a) providing a liquid solvent which is substantially nonreactive with aluminum or mercury but capable of dissolving a sulfur-bearing component;

(b) contacting said mercury-contaminated aluminum surface with said liquid solvent;

(c) dissolving a sulfur-bearing component into said liquid solvent;

(d) dissolving a gas reactive with said sulfur-bearing component into said solvent, said sulfur-bearing component and said gas reacting in such a manner that sulfur from said sulfur-bearing component reacts with the mercury upon said mercury-contaminated aluminum surface to render it inert to aluminum.

2. The method of claim 1 wherein the liquid solvent of (a) is carbon disulfide.

3. The method of claim 1 wherein the liquid solvent of (a) is carbonyl sulfide.

4. The method of claim 1 wherein the liquid solvent of (a) is tetrahydrofuran.

5. The method of claim 1 wherein the sulfur-bearing component of (c) is gaseous hydrogen sulfide.

6. The method of claim 1 wherein said gas is sulfur dioxide.

7. The method of claim 1 wherein said gas is ammonia.

8. The method of claim 1 including the step of maintaining the temperature of said aluminum surface below about 0°

C.

9. A method for rendering mercury and mercury amalgam present on an aluminum surface inert to aluminum, comprising:

(a) depositing on said aluminum surface a liquid solvent capable of dissolving hydrogen sulfide;

(b) contacting the resulting liquid solvent-wet surface with gaseous hydrogen sulfide;

(c) contacting said solvent-wet aluminum surface with a reactant for releasing sulfur from hydrogen sulfide present in said liquid solvent, whereby said sulfur reacts with said mercury to form a compound inert to aluminum.

10. The method of claim 9 wherein said reactant comprises sulfur dioxide.

11. The method of claim 9 wherein said reactant comprises ammonia gas.

12. A method for rendering mercury and mercury amalgam present on an aluminum surface inert to aluminum, comprising:

(a) providing a vaporized solvent having hydrogen sulfide dissolved therein;

(b) condensing said vaporized solvent mixed with said dissolved hydrogen sulfide onto said aluminum surface;

(c) contacting said solvent-wet aluminum surface with a gas capable of reacting with hydrogen sulfide and releasing sulfur therefrom, whereby said sulfur reacts with said mercury to form a compound inert to aluminum.

13. The method of claim 12 wherein the solvent of (a) is carbon disulfide.

14. The method of claim 12 wherein the solvent of (a) is carbonyl sulfide.

15. The method of claim 12 wherein the solvent of (a) is tetrahydrofuran.

16. The method of claim 12 wherein the gas of (c) is selected from the group consisting of sulfur dioxide and ammonia.

17. The method of claim 12 wherein the gas of (c) is sulfur dioxide.

18. The method of claim 12 wherein the gas of (c) is ammonia.

19. The method of claim 12 including the step of maintaining the temperature of said aluminum surface below about 0°

C.

20. A method for treating a mercury-contaminated aluminum surface comprising:

maintaining the temperature of said surface below about zero degrees Centigrade;

providing a solvent capable of dissolving a sulfur-bearing component;

contacting said surface with said solvent;

dissolving a sulfur-bearing component within said solvent; and

dissolving a substance reactive with said sulfur-bearing component in said solvent, said substance being capable of causing the release of sulfur from said sulfur-bearing component,

whereby said sulfur reacts with said mercury to form mercuric sulfide.

21. A method as defined in claim 20 wherein said solvent is condensed upon said mercury-contaminated aluminum surface.

22. A method as defined in claim 20 wherein said sulfur-bearing component is hydrogen sulfide.

23. A method as defined in claim 20 wherein said substance is sulfur dioxide.