Alloy powder mixture for treating alloys

• US 4,830,934 A
• Filed: 06/01/1987
• Issued: 05/16/1989
• Est. Priority Date: 06/01/1987
• Status: Expired due to Term

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Somerville, Mark, Young, William R., Ferrigno, Stephen J.
• Primary Examiner(s): Zimmerman, John J.
• Application Number:
  US07/056,175
• Time in Patent Office: 715 Days
• Field of Search: 228/119, 228/194, 29/402.18, 419/6, 75/255, 75/251, 75/246, 428/678, 428/680, 428/668, 148/127
• US Class Current: 428/678
• CPC Class Codes: B23K 35/30 with the principal constituent melting at less than 1550 degrees C
• CPC Class Codes: B23K 35/304 with Cr as the next major constituent
• CPC Class Codes: Y10T 29/49746 by applying fluent material, e.g., coating, casting
• CPC Class Codes: Y10T 428/12861 Group VIII or IB metal-base component
• CPC Class Codes: Y10T 428/12931 Co-, Fe-, or Ni-base components, alternative to each other
• CPC Class Codes: Y10T 428/12944 Ni-base component

Abstract

An improved mixture of alloy powders is provied for use in treating a preselected article alloy, for example, to repair or join multiple components of the article. The mixture has at least three distinct groups of alloy powders which together define a mixture composition range, with each alloy powder of the groups characterized by a composition and melting range different from the others and from the article alloy. In a preferred form, the mixture composition range comprises, by weight, 15-30% Cr, 1.5-6% W, 0.4-4% Al, 1-11% Ti, 1-6% Ta, up to 1.5% B, up to 0.5% Si, up to 0.2% Zr, up to 3% Mo, up to 0.3% Hf, up to 6% Cb, up to 2% Re, with the balance selected from Co and Ni along with incidental impurities.

Claims

1. An improved mixture of alloy powders for use in treating a preselected article alloy of predetermined composition range and based on an element selected from the group consisting of Ni and Co, at a temperature less than the incipient melting temperature of the article alloy;

the mixture having at least three distinct groups of alloy powders together defining a mixture composition range;

each alloy powder of the groups characterized by a composition and melting range different from the others and from the article alloy;

a first of the groups having at least one alloy each with a melting range higher than the melting ranges of the alloys in other groups and further characterized by;

(a) substantially all of elements selected from the group consisting of W and Mo, and

(b) substantially all of any C included in the mixture composition;

the second of the groups having at least one alloy each with a melting range lower than alloys in the first group, and further characterized by;

(a) the substantial absence of elements selected from the group consisting of W and Mo, and

(b) the substantial absence of C;

the alloys of the second group comprising Cr, Al, and at least one element selected from the group consisting of Ni and Co; and

a third of the groups having at least one eutectic alloy each with a melting range lower than alloys of the second group, the alloys of the third group being characterized by the substantial absence of C;

the mixture composition range characterized by less than 2 wt. % total of elements selected from the group consisting of B and Si, less than 1 wt. % C, and including 15-30 wt. % Cr, 1-7 wt. % W, and 1-6 wt. % Ta.

2. The mixture of claim 1 in which the mixture composition range comprises, by weight, 15-30% Cr, 1.5-6.5% W, 0.4-4% Al, 1-11% Ti, 1-6 Ta, up to 1.5% B, up to 0.5% Si, up to 0.2% Zr, up to 3% Mo, up to 0.3% Hf, up to 6% Cb, up to 3% Re, with the balance selected from the group consisting of Ni and Co, along with incidental impurities.

3. The mixture of claim 2 wherein:

the first of the groups is characterized by the lower total weight percent of melting point depressants selected from the group consisting of B and Si when compared with powders in the second of the groups of the mixture; and

the mixture composition range consists essentially of, by weight, 15-30% Cr, 2-7% W, 0.4-1.5% Al, 1-4% Ti, 2-6% Ta, 0.5-2% B, up to 0.5% Si, up to 0.2% Zr, 9-15% Ni, with the balance Co and incidental impurities.

4. The mixture of claim 3 which consists nominally by weight, of 19-20% Cr, 3-4% W, 14-15% Ni, 0.4-0.6% Al, 1-2% Ti, 1-3% Ta, 1-1.5% B, with the balance Co and incidental impurities.

5. The mixture of claim 3 which consists nominally, by weight, of 15-≠

% Cr, 6-7% W, 9-10% Ni, 0.3-0.5% Al, 1-2% Ti, 4-5% Ta, 1-1.2% B, with the balance Co and incidental impurities.

6. The mixture of claim 3 which consists nominally, by weight, of 25-30% Cr, 4-5% W, 9-10% Ni, 0.9-1.1% Al, 1-2% Ti, 5-6% Ta, 0.7-1% B, 0.2-0.4% Si, 0.1-0.2% Zr, with the balance Co and incidental impurities.

7. The mixture of claim 3 which consists nominally, by weight, of 20-23% Cr, 2-3% W, 9-10% Ni, 1-1.2% Al, 3-4% Ti, 2-4% Ta, 1.1-1.5% B, 0.2-0.3% Si, 0.1-0.2% Zr, with the balance Co and incidental impurities.

8. The mixture of claim 1 in which the mixture composition range consists essentially of, by weight, 15-25% Cr, 1.5-4% W, 0.5-4% Al, 2-11% Ti, 1-4% Ta, up to about 1% B, 2-30% Co, 1-3% Mo, 0.1-0.3 Hf, 0.5-6% Cb, up to 3% Re, with the balance Ni and incidental impurities.

9. The mixture of claim 1 which consists nominally, by weight, of 16-18% Cr, 3-5% W, 0.6-0.8% Al, 2-3% Ti, 3-4% Ta, 0.9-1.1% B, 25-30% Co, 1-1.5% Mo, 0.2-0.3% Hf, 0.5-1% Cb, with the balance Ni, and incidental impurities.

10. The mixture of claim 1 which consists nominally, by weight, of 18-20% Cr, 2-3% W, 3-4% Al, 2-3% Ti, 1-2% Ta, 0.2-0.3% B, 3-4% Co, 2-3% Mo, 0.2-0.3% Hf, 5-6% Cb, 1-2% Re, with the balance Ni and incidental impurities.

11. The mixture of claim 1 which consists nominally, by weight, of 16-18% Cr, 2-3% W, 3-4% Al, 6-7% Ti, 1-2% Ta, up to 0.2% B, 2-3% Co, 2-3% Mo, 0.2-0.3% Hf, 5-6% Cb, 1-2% Re, with the balance Ni and incidental impurities.

12. The mixture of claim 1 which consists nominally by weight, of 21-23% Cr, 1-2% W, 2-4% Al, 9-11% Ti, 1-2% Ta, 3-4% Co, 1-2% Mo, 0.1-0.2% Hf, 1-2% Cb, 1-2% Re, with the balance Ni and incidental impurities.

13. The mixture of claim 1 which consists nominally, by weight, of 16-18% Cr, 2-4% W, 3-4% Al, 7-8% Ti, 1-3% Ta, 0.05-0.15% B, 3-5% Co, 2-4% Mo, 0.2-0.4% Hf, 1-2% Cb, 1-3% Re, with the balance Ni and incidental impurities.

14. In a method of repairing a repair area of an article of an alloy of predetermined composition range and based on an element selected from the group consisting of Ni and Co, the steps of:

A. disposing at the repair area an improved mixture of alloy powders which can be used in treating the alloy of the article at a temperature less than the incipient melting temperature of the alloy;

(1) the mixture having at least three distinct groups of alloy powders together defining a mixture composition range;

(2) each alloy powder of the groups characterized by a composition and melting range different from the others and from the article alloy;

(3) a first of the groups having at least one alloy each with a melting range higher than the melting ranges of the alloys in other groups and further characterized by;

(a) substantially all of elements selected from the group consisting of W and Mo, and

(b) substantially all of any C included in the mixture composition;

(4) the second of the groups having at least one alloy each with a melting range lower than alloys in the first group, and further characterized by;

(a) the substantial absence of elements selected from the group consisting of W and Mo, and

(b) the substantial absence of C;

(c) the alloys of the second group comprising Cr, Al, and at least one element selected from the group consisting of Ni and Co; and

(5) a third of the groups having at least one eutectic alloy each with a melting range lower than alloys of the second group, the alloys of the third group being characterized by the substantial absence of C;

(6) the mixture composition range characterized by less than 2 wt. % total of elements selected from the group consisting of B and Si, less than 1 wt. % C, and including 15-30 wt. % Cr, 1-7 wt. % W, and 1-6 wt. % Ta;

B. heating the area below the incipient melting temperature of the alloy and in a first temperature range of about 2125°

-2275°

F. for a time sufficient to flow at least a portion of the powder mixture at the repair area; and

thereafter,

C. heating the repair area in a second temperature range below the first temperature range for at least about 8 hours to diffuse at least a portion of the powder mixture with the alloy of the article and to provide the repair area microstructure with a fine dispersion of second phase borides or carbides or both.

15. The method of claim 14, for repair of a nickel base superalloy, in which, after heating at the second temperature, the repair area is aged for gamma prime strengthening.

16. The method of claim 15 in which the aging is conducted in a temperature range of about 1550°

-1600°

F. for about 4-8 hours.

17. The method of claim 14 in which:

the first temperature range is about 2145°

-2225°

F.;

the second temperature range is about 2000°

-2125°

F.; and

the repair area is held in the second temperature range for at least about 8 hours.

18. The method of claim 17 in which the repair area is held at the second temperature for about 8-15 hours.

19. A repaired article of a nickel base or cobalt base superalloy including a repair area treated in accordance with the method of claim 14, the repair area being characterized by a microstructure of a fine, discrete dispersion of second phase borides or carbides or both, and strength properties at least approaching the strength of the superalloy.

20. The article of claim 19 in which the repair area includes a repaired gap up to about 0.02 inch.