Non-agueous lithium battery

• US 4,830,940 A
• Filed: 01/14/1986
• Issued: 05/16/1989
• Est. Priority Date: 01/14/1986
• Status: Expired due to Term

• Current Assignee: Greatbatch Limited (Greatbatch Incorporated)
• Original Assignee: Wilson Greatbatch Technologies, Inc.
• Inventors: Takeuchi, Ester S., Muffoletto, Barry C., Mead, Ralph T., Greenwood, John M., Ebel, Steven J., Zelinsky, Michael A., Keister, Pamela P.
• Primary Examiner(s): Kalafut, Stephen J.
• Application Number:
  US06/818,879
• Time in Patent Office: 1,218 Days
• Field of Search: 429/194, 429/219, 429/128, 429/94
• US Class Current: 429/94
• CPC Class Codes: A61N 1/3758 Packaging of the components within the casing
• CPC Class Codes: A61N 1/378 Electrical supply
• CPC Class Codes: H01M 10/0413 Large-sized flat cells or batteries for motive or stationary systems with plate-like electrodes
• CPC Class Codes: H01M 10/0454 Cells or batteries with electrodes of only one polarity folded
• CPC Class Codes: H01M 4/12 of consumable metal or alloy electrodes use of alloy compositions as active materials H01M4/38
• CPC Class Codes: H01M 4/483 for non-aqueous cells H01M4/485 takes precedence
• CPC Class Codes: H01M 4/54 of silver
• CPC Class Codes: H01M 50/103 prismatic or rectangular H01M50/109, H01M50/11 take precedence
• CPC Class Codes: H01M 50/176 for prismatic or rectangular cells H01M50/181 takes precedence
• CPC Class Codes: H01M 50/30 Arrangements for facilitating escape of gases
• CPC Class Codes: H01M 50/538 Connection of several leads or tabs of wound or folded electrode stacks
• CPC Class Codes: H01M 50/54 Connection of several leads or tabs of plate-like electrode stacks, e.g. electrode pole straps or bridges
• CPC Class Codes: H01M 6/10 with wound or folded electrodes
• CPC Class Codes: H01M 6/103 Cells with electrode of only one polarity being folded or wound
• CPC Class Codes: H01M 6/16 with organic electrolyte H01M6/18 takes precedence

Abstract

A solid cathode liquid organic electrolyte lithium cell for delivering high current pulses comprising a casing, a cathode structure inthe casing comprising a plurality of plates in spaced apart relation, a lithium anond comprising a plurality of anode sections interposed between the cathode plates, a non-aqueous liquid organic electrolyte comprising the combination of a lithum dalt and an organic solvent in the casing operatively contacting the anode and the cathode an electrical connection provided to the anode and an electrical connection provided to the cathode. In accordance with one aspect of the invention the cathode includes as active material Ag_x V₂ O_y where x is in the range from about 0.5 to about 2.0 and y is in the range from about 4.5 to about 6.0 which advantageously has high volumetric capacity and high rate capability with the result that the cell of the present invention delivers high capacity, shows good current pulsing behavior at various levels of discharge, and has a sloping discharge cause enabling end of life to be predicted. In accordance with another aspect of the present invention, the anode comprises a continuous elongated lithium element enclosed within a separator and folded into a plurality of sections interposed between the cathode plates, each of which individually is enclosed within separator material thereby enhancing the reliability of the cell. The cell of the present invention finds advantageous use as a power source for an implantable cardiac defibrillator.

Claims

1. A solid cathode liquid organic electrolyte alkali metal primary cell for delivering high current pulses comprising:

(a) a casing;

(b) cathode means in said casing comprising a plurality of plates in spaced apart relation, said cathode means including as active material Ag_x V₂ O_y where x is in the range from about 0.5 to about 2.0 and y is in the range from about 4.5 to about 6.0 so as to have high volumetric capacity and high rate capability;

(c) alkali metal anode means comprising a plurality of anode sections interposed between said cathode plates;

(d) a non-aqueous electrolyte in said casing operatively contacting said anode means and said cathode means;

(e) means for providing electrical connection to said anode means; and

(f) means for providing electrical connection to said cathode means;

(g) said cathode means, anode means and electrolyte co-operating to enable said cell to deliver high current pulses and rapidly recover the cell open circuit voltage and to enable said cell to have high capacity and low self discharge.

2. A cell according to claim 1, wherein said cathode means includes as active material Ag_x V₂ O_y where x is in the range from about 0.95 to about 1.1 and y is in the range from about 5.0 to about 6.0.

3. A cell according to claim 1, wherein said anode means is of lithium.

4. A cell according to claim 1, wherein each of said cathode plates comprises a cathode conductor including a body portion and a lead portion extending therefrom, a cathode mixture pressed onto said conductor body portion in the form of a pellet and including said cathode active material.

5. A cell according to claim 4, where said cathode pellet further comprises a binder and conductors including graphite powder and acetylene black power.

6. A cell according to claim 4, wherein said cathode mixture includes an additive selected from the group consisting of lithium salts, lithium ion conducting electrolyte and solid surfactant.

7. A cell according to claim 4, wherein said pellet is enclosed in an envelope of separator material.

8. A cell according to claim 1, wherein said anode means comprises a continuous elongated lithium element enclosed within separator material and folded into said plurality of sections.

9. A cell according to claim 1, wherein said anode means comprises:

(a) an enlongated ribbon-like anode conductor element.

(b) a pair of elongated ribbon-like lithium elements pressed together against opposite sides of said conductor element to form an anode structure;

(c) separator material encapsulating said anode structure; and

(d) said anode structure being folded at spaced intervals along the length thereof to form a sepentine-like structure to receive between the folds thereof said plurality of cathode plates.

10. A cell according to claim 9, wherein said anode conductor element includes at least one terminal tab extending therefrom.

11. A cell according to claim 10, wherein said casing is of electrically conductive material and wherein said terminal tab is electrically connected to said casing.

12. A cell according to claim 1, wherein said electrolyte is an organic liquid.

13. A cell according to claim 1, wherein said electroyte is a combination of a lithium salt and an organic solvent.

14. A cell according to claim 1, wherein said casing means is of electrically conductive material and said anode means is electrically connected to said casing.

15. A cell according to claim 14, wherein said means for providing electrical connection to said cathode means comprises conductor means electrically connnected to said cathode means extending through said casing and electrically insulated therefrom.

16. A cell according to claim 1, wherein said casing is of electrically conductive material and said cathode means is electrically connected to said casing.

17. A cell according to claim 15 wherein said means for providing electrical connection to said anode means comprises conductor means electrically connected to said anode means extending through said casing and electrically insulated therefrom.

18. A cell according to claim 1, in combination with an implantable cardiac defibrillator.

19. A cell according to claim 1, wherein said anode means comprises a plurality of plates defining said anode sections interposed between said cathode plates.

20. A solid cathode liquid electrolyte alkali metal primary cell for delivering high current pulses comprising:

(a) a casing of electrically conductive material;

(b) cathode means in said casing comprising a plurality of plates of cathode active material in spaced apart relation, each of said plates including conductor means extending therefrom;

(c) anode means comprising a continuous elongated alkali metal element enclosed within a separator and folded into a plurality of sections interposed between said cathode plates, said anode means comprising anode conductor means extending therefrom;

(d) a non-aqueous electrolyte in said casing operatively contacting said anode means and said cathode means;

(e) means for connecting said anode conductor means to said casing;

(f) conductor means electrically connected to said cathode means extending through said casing; and

(g) means for electrically insulating said conductor means from said casing.

21. A cell according to claim 20, wherein each of said cathode plates is enclosed in an envelope of separator material.

22. A cell according to claim 20, wherein said cathode means includes as active material Ag_x V₂ O_y where x is in the range from about 0.5 to about 2.0 and y is in the range from about 4.5 to about 6.0.

23. A cell according to claim 22, wherein each of said cathode conductor means comprises a body portion and a lead portion and wherein each of said cathode plates comprises a cathode mixture pressed onto said conductor body portion in the form of a pellet and including said cathode active material.

24. A cell according to claim 23, wherein said cathode pellet further comprises a binder and conductors including graphite powder and acetylene black powder.

25. A cell according to claim 23, wherein said pellet is enclosed in an envelope of separator material.

26. A cell according to claim 20, wherein said lithium anode means comprises:

(a) an elongated ribbon-like anode conductor element;

(b) a pair of elongated ribbon-like lithium elements pressed together against opposite sides of said conductor element to form an anode structure;

(c) separator material encapsulating said anode structure; and

(d) said anode structure being folded at spaced intervals along the length thereof to form a serpentine-like structure to receive between the folds thereof said plurality of cathode plates.

27. A cell according to claim 26, wherein anode conductor means includes at least one terminal tab extending therefrom and electrically connected to said casing.

28. A cell according to claim 20, wherein said electrolyte is an organic liquid.

29. A cell according to claim 28, wherein said electrolyte is a combination of lithuim salt and an organic solvent.

30. A cathode for an alkali metal non-aqueous silver vanadium oxide primary cell for delivering successive high current pulses and rapidly recovering the cell open circuit voltage and including a plurality of cathode components in spaced relation and adapted to be interposed between a plurality of anode sections, each of said cathode components comprising a cathode conductor including a body portion and a lead portion extending therefrom, a cathode mixture pressed onto said conductor body portion in the form of a pellet and including cathode active material, said cathode active material comprising Ag_x V₂ O_y where x is in the range from about 0.5 to about 2.0 and y is in the range from about 4.5 to about 6.0, said material having high volumetric capacity and high rate capability.

31. A cathode according to claim 30, wherein x is in the range from about 0.95 to about 1.1 and y is in the range from about 5.0 to about 6.0.

32. A cathode according to claim 30, wherein said cathode mixture further includes binder and conductors including graphite powder and acetylene black powder.

33. A cathode according to claim 30, wherein said cathode mixture contains an additive selected from the group consisting of lithium salts, solid lithium ion conducting electrolyte and surfactant.

34. A cathode according to claim 30, wherein said pellet is enclosed in an envelope of separator material.

35. An anode for a solid cathode non-aqueous liquid electrolyte alkali metal primary cell for delivering successive high current pulses and rapidly recovering the cell open circuit voltage, said anode comprising:

(a) an alongated ribbon-like anode conductor element;

(b) a pair of elongated ribbon-like alkali metal elements pressed together against opposite sides of said conductor element to form an anode structure;

(c) separator material encapsulating said anode structure, said separator material being in the form of a sheet pressed on said anode structure and heat sealed around the edges thereof; and

(d) said anode structure being folded at spaced intervals along the length thereof to form a serpentine-like structure to receive between the folds thereof a plurality of cathode elements of the cell.

36. An anode according to claim 35, wherein said alkali metal elements are of lithium.

37. An anode according to claim 35, further including at least on terminal tab extending therefrom.

38. A solid cathode liquid electrolyte alkali metal primary cell for delivering high current pulses comprising:

(a) a casing;

(b) cathode means in said casing comprising a plurality of plates in spaced apart relation, each of said plates comprising cathode active material enclosed within separator material and each of said plates including conductor means extending therefrom, said separator material being in the form of a sheet pressed on said plate and heat sealed around the edges thereof;

(c) anode means comprising a continuous elongated alkali metal element enclosed with separator material and folded into a plurality of sections interposed between said cathode plates, said separator material being in the form of a sheet pressed on said element and heat sealed around the edges thereof, said anode means comprising anode conductor means extending therefrom;

(d) a non-aqueous electrolyte in said casing operatively contacting said anode means and said cathode means;

(e) means for providing electrical connection to each of said cathode conductor means; and

(f) means for providing electrical connection to said anode conductor means.

39. A cell according to claim 38, wherein anode means is of lithium.

40. A cell according to claim 38, wherein said casing is of electrically conductive material and said anode means is electrically connected to said casing.

41. A cell according to claim 40, wherein said means for providing electrical connection to said cathode conductor means comprises conductor means electrically connected to said cathode conductor means extending through said casing and electrically insulated therefrom.

42. A cell according to claim 38, wherein said casing is of electrically conductive material and said cathode conductor means is electrically connected to said casing.

43. A cell according to claim 42, wherein said means for providing electrical connection to said anode conductor means comprises conductor means electrically connected to said anode conductor means extending through said casing and electrically insulated therefrom.

44. A solide state cathode liquid electrolyte alkali metal primary cell for delivering high current pulses comprising:

(a) a casing

(b) cathode means in said casing comprising a plurality of interconnected cathode sections in a chain-like arrangement;

(c) alkali metal anode means comprising a continuous elongated structure foldable into a plurality of sections;

(d) said cathode means and anode means being folded together in a manner providing an arrangement whereby said anode means is folded into a plurality of sections interposed between said cathode sections;

(e) a non-aqueous electrolyte in said casing operatively contacting said anode means and said cathode means;

(f) means for providing electrical connection to said anode means; and

(g) means for providing electrical connection to said cathode means.

45. A cathode for a solid cathode non-aqueous liquid electrolyte alkali metal primary cell comprising:

(a) a conductor comprising a plurality of individual sections joined to end-to-end relation; and

(b) a corresponding plurality of individual pellets of cathode active material pressed onto said conductor sections.

46. A cathode according to claim 45, further including separator material encapsulating said pellets.

47. A solid cathode non-aqueous liquid electrolyte alkali metal primary cell for delivering high current pulses comprising:

(a) a casing

(b) cathode means in said casing comprising a continuous elongated body comprising cathode active material and a conductor therein, said body folded into a plurality of sections;

(c) alkali metal anode means comprising a plurality of anode sections interposed between said cathode sections;

(d) a non-queous electrolyte in said casing operatively contacting said anode means and said cathode means;

(e) means for providing electrical connection to said anode means; and

(f) means for providing electrical connection to said cathode means.

48. A cell according to claim 47, wherein said anode means is of lithium.

49. A cell according to claim 47, wherein said anode means comprises a plurality of plates defining said anode sections interposed between said cathode sections.

50. A cell according to claim 47, wherein said anode means comprises a continuous elongated body folded into a plurality of sections interposed between said cathode sections.

51. A cell according to claim 47, wherein each of said anode means and cathode means is individually enclosed in separator material.