Thin film ion conducting coating
First Claim
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1. An electronic device comprising:
- a transparent substrate;
a first transparent electronically conductive layer on said substrate;
an electrochromic layer on said first transparent electrically conductive layer;
an ion conductive-electron resistive layer on said electrochromic layer, said ion conductive-electron resistive layer capable of transporting positive metal ions into said electrochromic layer to transform said electrochromic layer into said optically reflective state;
a counter-electrode layer on said ion conductive-electron resistive layer, said counter-electrode layer capable of storing and delivering electrons and ions to be transported into said electrochromic layer to transform said electrochromic layer into said optically reflective state; and
a second transparent electronically conductive layer on said counter-electrode layer, said first and second electrically conductive layers being adapted for connection with an external voltage source, whereby when voltage of a first polarity is applied across said first and second conductive layers said positive metal ions and said electrons are driven into said electrochromatic layer and when voltage of a second opposite polarity is applied across said first and second electrically conductive layers said positive metal ions and said electrons are removed from said electrochromic layer, said ion conductive-electron resistive layer comprising mixed metal oxides said mixed metal oxides layer including lithium oxide and at least one additional oxide selected from the group consisting of, tantalum oxide, and niobium oxide.
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Abstract
Durable thin film ion conducting coatings are formed on a transparent glass substrate by the controlled deposition of the mixed oxides of lithium:tantalum or lithium:niobium. The coatings provide durable ion transport sources for thin film solid state storage batteries and electrochromic energy conservation devices.
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Citations
13 Claims
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1. An electronic device comprising:
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a transparent substrate; a first transparent electronically conductive layer on said substrate; an electrochromic layer on said first transparent electrically conductive layer; an ion conductive-electron resistive layer on said electrochromic layer, said ion conductive-electron resistive layer capable of transporting positive metal ions into said electrochromic layer to transform said electrochromic layer into said optically reflective state; a counter-electrode layer on said ion conductive-electron resistive layer, said counter-electrode layer capable of storing and delivering electrons and ions to be transported into said electrochromic layer to transform said electrochromic layer into said optically reflective state; and a second transparent electronically conductive layer on said counter-electrode layer, said first and second electrically conductive layers being adapted for connection with an external voltage source, whereby when voltage of a first polarity is applied across said first and second conductive layers said positive metal ions and said electrons are driven into said electrochromatic layer and when voltage of a second opposite polarity is applied across said first and second electrically conductive layers said positive metal ions and said electrons are removed from said electrochromic layer, said ion conductive-electron resistive layer comprising mixed metal oxides said mixed metal oxides layer including lithium oxide and at least one additional oxide selected from the group consisting of, tantalum oxide, and niobium oxide. - View Dependent Claims (4, 5, 6, 7)
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2. An electrochromic device comprising:
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a transparent substrate; a first transparent electronically conductive layer on said substrate; an electrochromic layer on said first transparent electrically conductive layer; an ion conductive-electron resistive layer on said electrochromic layer, said ion conductive-electron resistive layer capable of transporting positive metal ions into said electrochromic layer to transform said electrochromic layer into said optically reflective state; a counter-electrode layer on said ion conductive-electron resistive layer, said counter-electrode layer capable of storing and delivering electrons and ions to be transported into said electrochromic layer to transform said electrochromic layer into said optically reflective state; and a second transparent electronically conductive layer on said counter-electrode layer, said first and second electrically conductive layers being adapted for connection with an external voltage source, whereby when voltage of a first polarity is applied across said first and second conductive layers said positive metal ions and said electrons are driven into said electrochromic layer and when voltage of a second opposite polarity is applied across said first and second electrically conductive layers said positive metal ions and said electrons are removed from said electrochromic layer, said ion conductive-electron resistive layer comprising mixed metal oxides said mixed metal oxides layer including lithium oxide and at least one additional oxide selected from the group consisting of, boron oxide, magnesium oxide, calcium oxide, manganese oxide and zinc oxide.
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3. An electrochromic device comprising:
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a transparent substrate; a first transparent electronically conductive layer on said substrate; an electrochromic layer on said first transparent electrically conductive layer; an ion conductive-electron resistive layer on said electrochromic layer, said ion conductive-electron resistive layer capable of transporting positive metal ions into said electrochromic layer to transform said electrochromic layer into said optically reflective state; a counter-electrode layer on said ion conductive-electron resistive layer, said counter-electrode layer capable of storing and delivering electrons and ions to be transported into said electrochromic layer to transform said electrochromic layer into said optically reflective state; and a second transparent electronically conductive layer on said counter-electrode layer, said first and second electrically conductive layers being adapted for connection with an external voltage source, whereby when voltage of a first polarity is applied across said first and second conductive layers said positive metal ions and said electrons are driven into said electrochromic layer and when voltage of a second opposite polarity is applied across said first and second electrically conductive layers said positive metal ions and said electrons are removed from said electrochromic layer, said ion conductive-electron resistive layer comprising mixed metal oxides said mixed metal oxides layer including lithium oxide and at least one additional oxide selected from the group consisting of, gallium oxide, tungsten oxide, molydbenum oxide, germanium oxide, strontium oxide, yttrium oxide and barium oxide.
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8. A method of forming durable thin film electrical coatings comprising the steps of:
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providing a transparent substrate within a deposition chamber; depositing a layer of a transparent conductive coating on said transparent substrate; depositing a layer of electrochromic material on said first conductive layer; depositing a layer of ion conductive-electron resistive mixed-oxides on said electrochromic layer; depositing a counter-electrode layer of electron conductive ion resistive material on said ion conductive-electron resistive layer; depositing a layer of a transparent conductive coating on said electron conductive ion resistive layer said step of depositing a mixed-oxides layer comprising depositing a composition which includes lithium oxide in excess of stoichiometry. - View Dependent Claims (9, 10, 11)
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12. A method of forming durable thin film electrical coatings comprising the steps of:
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providing a transparent substrate within a deposition chamber; depositing a layer of a transparent conductive coating on said transparent substrate; depositing a layer of electrochromic material on said first conductive layer; preparing mixed-oxides of lithium oxide and tantalum oxide in excess of stoichiometry depositing said mixed-oxides simultaneously on said electrochromic layer to form an ion conductive-electron resistive layer; depositing a counter-electrode layer of electron conductive ion resistive material on said ion conductive-electron resistive layer; and depositing a layer of a transparent conductive coating on said electron conductive ion resistive layer.
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13. A method of forming durable thin film electrical coatings comprising the steps of:
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providing a transparent substrate within a deposition chamber; depositing a layer of a transparent conductive coating on said transparent substrate; depositing a layer of electrochromic material on said first conductive layer; preparing mixed-oxides of lithium oxide and niobium oxide in excess of stoichiometry; depositing said mixed-oxides simultaneously on said electrochromic layer; depositing a counter-electrode layer of electron conductive ion resistive material on said ion conductive-electron resistive layer; and depositing a layer of a transparent conductive coating on said electron conductive ion resistive layer.
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Specification