Electrochromic variable color tone nonglaring mirror

• US 4,832,467 A
• Filed: 08/10/1987
• Issued: 05/23/1989
• Est. Priority Date: 08/11/1986
• Status: Expired due to Fees

• Current Assignee: Nissan Motor Co., Ltd.
• Original Assignee: Nissan Motor Co., Ltd.
• Inventors: Ishikawa, Masazumi, Miyagi, Harutoshi
• Primary Examiner(s): LaRoche, Eugene R.
• Assistant Examiner(s): McCutcheon, Nathan W.
• Application Number:
  US07/083,486
• Time in Patent Office: 652 Days
• Field of Search: 350/357
• US Class Current: 359/273
• CPC Class Codes: B60R 1/088 using a cell of electrically changeable optical characteristic, e.g. liquid-crystal or electrochromic mirrors
• CPC Class Codes: G02F 1/15165 Polymers
• CPC Class Codes: G02F 1/1524 Transition metal compounds

Abstract

The invention relates to a nonglaring mirror which is an electrochromic (EC) device in principle. The mirror comprises a transparent front substrate provided with a transparent first electrode layer, a back substrate provided with a second electrode layer opposite to the first electrode layer, first and second EC layers formed on the first and second electrode layers, respectively, an electrolyte liquid which fills up the space between the two substrates and reflecting means for providing a reflective surface to the second substrate. The material of the first EC layer is an organic polymer which is colorless or very pale in color in its electrochemically reduced state and undergoes electrochemical oxidation in two stages to assume a characteristic color in the first-stage oxidized state and another color in the second-stage oxidized state, and intermediate colors in intermediately oxidized states. It is very favorable to use a polymer made up of repeating structural units of N,N,N'"'"',N'"'"'-tetraphenyl-p-phenylenediamine. The second EC layer is usually formed of a transition metal oxide, e.g. WO₃, which takes on color in its electrochemically reduced state.

Claims

1. An electrochromic nonglaring mirror, comprising:

a transparent first substrate of which the inside surface is laid with a transparent first electrode layer;

a first electrochromic layer laid on said first electrode layer and formed of an organic polymer which undergoes electrochemical oxidation and reduction in at least two states and assumes different colors at its respective stages of electrochemical oxidation and becomes pale or colorless in its electrochemically fully reduced state wherein said organic polymer is made up of repeating units represented by the following general formula;

##STR2## wherein X and X'"'"' each represent a hydrogen atom, a halogen atom, an alkyl group having not more than 4 carbon atoms or an alkoxyl group having not more than 4 carbon atoms;

a second substrate comprising a second electrode layer arranged opposite to said first electrode layer;

a second electrochromic layer laid on said second electrode layer;

means for holding said first and second substrates spaced from each other and defining a closed space between the two substrates;

an electrolyte liquid which occupies said closed space; and

reflecting means for providing a reflective surface to said second substrate.

2. A mirror according to claim 1, wherein said second electrochromic layer is formed of a transition metal oxide which takes on color in its electrochemically reduced state.

3. A mirror according to claim 2, wherein said transition metal oxide is selected from the group consisting of WO₃, MoO₃, Nb₂ O₅, Cr₂ O₃, Ta₂ O₅, TiO₂, Fe₂ O₃ and AgO.

4. A mirror according to claim 1, wherein aid electrolyte liquid is a solution of a supporting electrolyte in an organic solvent.

5. A mirror according to claim 4, further comprising drive means for applying a DC voltage not higher than 0.8 V across said first and second electrode layers.

6. A mirror according to claim 1, wherein both said second substrate and said second electrode layer are transparent, said reflecting means comprising a reflective metal film coated on the rear surface of said second substrate.

7. A mirror according to claim 1, wherein said second electrode layer is a reflecting metal layer, whereby said reflecting means is incorporated in said second electrode layer.